Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
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- CAS-Nr.
- 373650-12-5
- Englisch Name:
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
- Synonyma:
- (S)-Ru(OAc)2(SEGPHOS);RU(OAC)2[(S)-SEGPHOS];(S)-Ru(OAc)2(SEGPHOS(R));(S)-Ru(OAc)2(SEGPHOS?);Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II);Diacetato[(S)-(–)-5,5′-bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole]ruthenium(II), CAS 373650-12-5;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II),Ru(OAc)2[(S)-segphos;Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos];Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane
- CBNumber:
- CB71181064
- Summenformel:
- C38H28O4P2.C4H6O4Ru
- Molgewicht:
- 829.741
- MOL-Datei:
- 373650-12-5.mol
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Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Eigenschaften
- Schmelzpunkt:
- >100°C
- Flammpunkt:
- 100.00°C
- storage temp.
- 2-8°C
- Aggregatzustand
- solid
- Farbe
- yellow to black
- Sensitive
- air sensitive
- InChIKey
- BHGLLIGZFQVMBJ-UHFFFAOYSA-L
- SMILES
- C1(P(C2=CC=CC=C2)C2C=CC=CC=2)C=CC2OCOC=2C=1C1=C(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC2OCOC1=2.O(C(=O)C)[Ru]OC(=O)C
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
(
S)-Ru(OAc)
2(SEGPHOS
) can be used as a catalyst:
- To prepare highly chemo, enantio, and diastereoselective primary β-amino lactams by asymmetric reductive amination of racemic β-keto lactams.
- To synthesize chiral primary diarylmethylamines and sterically bulky benzylamines from diaryl and sterically hindered ketones via asymmetric reductive amination reaction.
- For the conversion of levulinic acid to optically active γ-valerolactone via asymmetric hydrogenation reaction.
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 83)Lieferanten
373650-12-5()Verwandte Suche:
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II)
- (S)-Ru(OAc)2(SEGPHOS(R))
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos]
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II) Ru(OAc)2[(S)-segphos(R)]
- Diacetoxyruthenium, [4-(5-diphenylphosphanyl-1,3-benzodioxol-4-yl )-1,3-benzodioxol-5-yl]-diphenyl-phosphane
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-be...
- Diacetato[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]ruthenium(II),Ru(OAc)2[(S)-segphos
- (S)-Ru(OAc)2(SEGPHOS?)
- Diacetato[(S)-(–)-5,5′-bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole]ruthenium(II), CAS 373650-12-5
- (S)-Ru(OAc)2(SEGPHOS)
- RU(OAC)2[(S)-SEGPHOS]
- 373650-12-5
- C42H34O8P2Ru
- Ru
