Goldtribromid
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- CAS-Nr.
- 10294-28-7
- Bezeichnung:
- Goldtribromid
- Englisch Name:
- GOLD(III) BROMIDE
- Synonyma:
- GOLD TRIBROMIDE;GOLD BROMIDE;Auric bromide;d(III) bromide;GOLD(III) BROMIDE;goldbromide(aubr3);digold hexabroMide;Gold(III) tribromide;GOLD(III) BROMIDE, 99.9%;Gold(III) bromide Hydrate
- CBNumber:
- CB7173020
- Summenformel:
- AuBr3
- Molgewicht:
- 436.68
- MOL-Datei:
- 10294-28-7.mol
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Goldtribromid Eigenschaften
- Schmelzpunkt:
- 160°C (dec.)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- L?slichkeit
- H2O: slightly soluble(lit.)
- Aggregatzustand
- Powder
- Farbe
- orange to brown
- Wasserl?slichkeit
- Slightly soluble in water.
- Sensitive
- moisture sensitive
- InChI
- 1S/Au.3BrH/h;3*1H/q+3;;;/p-3
- InChIKey
- OVWPJGBVJCTEBJ-UHFFFAOYSA-K
- SMILES
- Br[Au](Br)Br
- CAS Datenbank
- 10294-28-7(CAS DataBase Reference)
- EPA chemische Informationen
- Gold bromide (AuBr3) (10294-28-7)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
C |
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| R-S?tze: |
34 |
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| S-S?tze: |
26-36/37/39-45 |
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| RIDADR |
UN 3260 8/PG 3 |
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| WGK Germany |
3 |
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| F |
8-10-23 |
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| TSCA |
TSCA listed |
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| HazardClass |
8 |
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| PackingGroup |
III |
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| Speicherklasse |
8A - Combustible corrosive hazardous materials |
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| Hazard Classifications |
Skin Corr. 1B |
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| Bildanzeige (GHS) |
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| Alarmwort |
Achtung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H314 |
Verursacht schwere Ver?tzungen der Haut und schwere Augensch?den. |
?tzwirkung auf die Haut |
Kategorie 1B |
Achtung |
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P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501 |
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| Sicherheit |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
| P310 |
Sofort GIFTINFORMATIONSZENTRUM/Arzt/ anrufen. |
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Goldtribromid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R34:Verursacht Ver?tzungen.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Yellowish-gray mass. Decomposes at
approximately 165C. Insoluble in water.
Verwenden
Gold(III) bromide is used as a catalyst in a variety of reactions. It catalyzes the reaction between an enynal unit and carbonyl compounds to form a six-membered cyclic compound. Another catalytic use of gold tribromide is in the nucleophilic substitution reaction of propargylic alcohols, with the gold complex acting as an alcohol-activating agent to facilitate the substitution. It can be used as a testing reagent for the presence of ketamine.
Definition
Brownish-black powder. Mp 160C with decomposition. Soluble in water and alcohol.
l?uterung methode
Purify it by adding pure Br2 to the dark powder, securely stopper the container, warm a little and shake while keeping away from light for ca 48hours. Remove the stopper and place it over NaOH until free Br2 is no longer in the apparatus (48-60hours). The bright yellow needles of the tribromide are stable over NaOH in the dark. It is soluble in H2O and in EtOH where it is slowly reduced. Keep it in a cooled, closed container and protect it from light as decomposition causes free gold to be formed. Aurobromic acid can be obtained by adding the calculated amount of conc HBr to AuBr3 (actually Au2Br6) until all dissolves, whereby the acid crystallises out as HAuBr4.5H2O; a deliquescent solid soluble in EtOH with m ca 27o, and store it as above. [Gibson & Colles J Chem Soc 2411 1931, Burawoy & Gibson J Chem Soc 217 1935, Burawoy & Gibson J Chem Soc 219 1935.]
Goldtribromid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Goldtribromid Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 109)Lieferanten
10294-28-7(Goldtribromid)Verwandte Suche:
- goldbromide(aubr3)
- GOLD(III) BROMIDE
- GOLD BROMIDE
- GOLD(III) BROMIDE, 99.9%
- Gold(III) bromide Hydrate
- Gold(III)bromide,anhydrous,99%(99.9+%-Au)
- gold(iii) bromide, premion
- GOLD(III) BROMIDE, ANHYDROUS (99.9%-AU)
- Auric bromide
- Gold(III) bromide, Premion(R), 99.99% (metals basis), Au 44.6% min
- Gold(III) bromide, Premion, 99.99% (metals basis), Au 44.6% min
- Gold(III) tribromide
- Gold(III) bromide, anhydrous
- Gold(III) bromide hydrate,99.9%(metals basis)
- Gold(III) broMide, anhydrous,98% AuBr3
- digold hexabroMide
- Gold(III) bromide, 99.99% trace metals basis
- Gold(III) bromide, anhydrous,AuBr3
- d(III) bromide
- GOLD(III) BROMIDE ISO 9001：2015 REACH
- GOLD TRIBROMIDE
- 10294-28-7
- AuBr3xH2O
- Catalysis and Inorganic Chemistry
- Gold
- Au
- metal halide
- Gold Catalysis
- Gold Catalysts
- Catalysis and Inorganic Chemistry
- Chemical Synthesis
- Gold
- Gold Salts
- Materials Science
- Metal and Ceramic Science
- Salts
