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4-Chloro-2-trimethylstannyl-1-butene

4-Chloro-2-trimethylstannyl-1-butene Struktur
85370-32-7
CAS-Nr.
85370-32-7
Englisch Name:
4-Chloro-2-trimethylstannyl-1-butene
Synonyma:
4-Chloro-2-trimethylstannyl-1-butene;[1-(2-CHLOROETHYL)VINYL](TRIMETHYL)STANNANE;Stannane, (3-chloro-1-methylenepropyl)trimethyl-
CBNumber:
CB73300450
Summenformel:
C7H15ClSn
Molgewicht:
253.357
MOL-Datei:
85370-32-7.mol

4-Chloro-2-trimethylstannyl-1-butene Eigenschaften

Aggregatzustand
liquid
Farbe
colorless
Wasserl?slichkeit
insoluble in H2O; soluble in THF, Et2O, CHCl3, and other common organic solvents

Sicherheit

4-Chloro-2-trimethylstannyl-1-butene Chemische Eigenschaften,Einsatz,Produktion Methoden

Synthese

4-chloro-2-trimethylstannyl-1-butene is readily prepared from the commercially available butynol (1). Regioselective addition of Me3SnCu.Me2S (see Trimethylstannylcopper-Dimethyl Sulfide) to (1) provides 3-trimethylstannyl-3-buten-1-ol (2), which upon reaction with Ph3P-CCl4 in the presence of Et3N affords (3) (eq 1). This preparative sequence can be carried out on a reasonably large scale (0.2 mol) and produces overall yields of about 50%.
4-Chloro-2-trimethylstannyl-1-butene

4-Chloro-2-trimethylstannyl-1-butene Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


4-Chloro-2-trimethylstannyl-1-butene Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 1)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Merck KGaA --
ordercn@merckgroup.com China 6394 58

  • Stannane, (3-chloro-1-methylenepropyl)trimethyl-
  • 4-Chloro-2-trimethylstannyl-1-butene
  • [1-(2-CHLOROETHYL)VINYL](TRIMETHYL)STANNANE
  • 85370-32-7
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