Carbonylchlorobis(triphenylphosphin)rhodium
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- CAS-Nr.
- 13938-94-8
- Bezeichnung:
- Carbonylchlorobis(triphenylphosphin)rhodium
- Englisch Name:
- Carbonylbis(triphenylphosphine)rhodium(I) chloride
- Synonyma:
- CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)RHODIUM(I);Carbonylbis(tripheny;Bis(Triphenylphosphine)rhodium(I) carbon;BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I;Carbonylbis(triphenylphosphine)rhodium(I);Carbonychlorobis(triphenylphosphine)rhodium;carbonylchlorobis(triphenylphosphine)rhodium;Carbonyl diphenyl phosphine rhodium chloride;Carbonylbis(triphenylphosphine)rhodium(I)chlo;Chlorocarbonyl bis(triphenylphosphine) rhodium
- CBNumber:
- CB7376852
- Summenformel:
- C37H30ClOP2Rh
- Molgewicht:
- 690.94
- MOL-Datei:
- 13938-94-8.mol
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Carbonylchlorobis(triphenylphosphin)rhodium Eigenschaften
- Schmelzpunkt:
- 224-227 °C (dec.)(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- L?slichkeit
- Soluble in acetone, chloroform, ethanol
- Aggregatzustand
- crystal
- Farbe
- yellow
- BRN
- 4618896
- Expositionsgrenzwerte
- ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
- InChI
- 1S/2C18H15P.CO.ClH.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h2*1-15H;;1H;/q;;;;+1/p-1
- InChIKey
- SGULOPRLUCGLSH-UHFFFAOYSA-M
- SMILES
- Cl[Rh].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
- CAS Datenbank
- 13938-94-8(CAS DataBase Reference)
Carbonylchlorobis(triphenylphosphin)rhodium Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
yellow crystals
Verwenden
Used for cyclometallation.
Application
Used as catalyst for carbonylation，decarbonylation, carbonyl exchange, reduction, hydrometalation, and C-H activation
reactions; reagent for alkylation of acid chlorides.
Synthese
To a solution of RhCl3.3H2O (2 g, 7.6 mmol) in 70 mL of absolute ethanol is slowly added
triphenylphosphine (7.2 g, 2.75 mmol) in 300 mL of boiling absolute ethanol. The solution becomes clear within 5 min, at
which point sufficient (10-20 mL) 37% formaldehyde solution is added, causing the red solution to become pale yellow. After
several minutes, yellow microcrystals precipitate. Upon cooling, the resulting crystals are washed with ethanol and diethyl
ether, dried (4.5 g, 85%) and recrystallized from hot toluene.
Carbonylchlorobis(triphenylphosphin)rhodium Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Carbonylchlorobis(triphenylphosphin)rhodium Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 236)Lieferanten
13938-94-8(Carbonylchlorobis(triphenylphosphin)rhodium)Verwandte Suche:
- RHODIUM-BIS(TRIPHENYLPHOSPHINE) CARBONYL CHLORIDE
- TRANS-BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL CHLORIDE
- CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(1) CHLORIDE
- CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CHLORIDE
- CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM (I)
- BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) CARBONYL CHLORIDE
- BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I) CHLORIDE
- BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(L) CHLORIDE
- Carbonylbis(triphenylphosphine)rhodium(I) chloride~Carbonylchlorobis(triphenylphosphine)rhodium(I)~Chlorocarbonylbis(triphenylphosphine)rhodium(I)
- carbonylchlorobis(triphenylphosphine)rhodium
- CARBONYLCHLORO-BIS-(TRIPHENYLPHOSPHANO)RHODIUM(I)
- Chlorocarbonyl bis(triphenylphosphine) rhodium
- Bis(triphenylphosphine) rhodium carbonyl chloride
- Chlorocarbonylbis(triphenylphosphine)rhodium(I),99%
- Rhodium, carbonylchlorobis(triphenylphosphine)-
- CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I ) CHLORIDE, 99.99%
- carbonyl bis(triphenylphosphine) rhodium chloride
- Carbonylchlorobis(triphenylphosphine)rhodium(I), Rh 14.9% min
- trans-Bis(triphenylphosphine)rhodium(I) carbonyl chloride, 98+%
- rhodium(I)-bis(triphenylphosphine) carbonyl chloride
- Chlorocarbonylbis(triphenylphosphine)rhodium(I), Rhodiumbis(triphenylphosphine) carbonyl chloride
- Carbonylbis(triphenylphosphine)rhodium(I) chloride,99%
- Carconylchlorobis(triphenylphosphine)rhodium(I)
- Bis(Triphenylphosphine)rhodium(I) carbon
- Bis(triphenylphosphine)rhodium(I) carbonyl chloride ,98%
- Chlorocarbonylbis(triphenylphosphine)rhodiuM(I),98%
- Bis(triphenylphosphine)carbonylrhodium(I) Chloride
Carbonylchlorobis(triphenylphosphine)rhodium(I)
- Bis(triphenylphosphine)carbonylrhodiuM chloride
- Carbonylbis(tripheny
- BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I
- Formylbis(triphenylphosphoranyl)-rhodium(IV) chloride
- Carbonychlorobis(triphenylphosphine)rhodium
- Carbonyl diphenyl phosphine rhodium chloride
- Carbonylbis(triphenylphosphine)rhodium(I) chloride ISO 9001：2015 REACH
- Carbonylbis(triphenylphosphine)rhodium(I)chlo
- Triphenylphosphine carbonyl ruthenium chloride
- Carbonylchlorobis(triphenylphosphane)-
rhodium(I)
- Carbonylbis(triphenylphosphine)rhodium(I)
- Bis(triphenylphosphine)carbonylchlororhodium(I)
- CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
- 13938-94-8
- C37H31ClOP2Rh
- RhClCOPC6H532
- RhClCOPPh32
- C6H53P2RhClCO
- C37H30ClOP2Rh
- 2C18H15PCOClRh
- Catalysis and Inorganic Chemistry
- Metal Complexes
- Transition Metal Compounds
- Homogeneous Catalysts
- Catalysts for Organic Synthesis
- Rh (Rhodium) Compounds
- Classes of Metal Compounds
- metal carbonyl complexes
- Rh
- chemical reaction,pharm,electronic,materials
- Catalysts for Organic Synthesis
