Tris(dibenzylideneacetone)dipalladium
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- CAS-Nr.
- 52409-22-0
- Englisch Name:
- Tris(dibenzylideneacetone)dipalladium
- Synonyma:
- PD(DBA)2;Pd(dba)3;PALLADIUM(0) BIS(DIBENZYLIDENEACETONE);Bis(dibenzylideneacetone)dipalladium;Tris(dibenzylideneacetone)diplalladium(I);tris(dibenzylideneacetone)dipalladium(o)(pd2(dba)3);Tris(dibenzylideneacetone;Tris(dibenzylideneacetone)dipalladium;BIS(DIBENZYLIDENEACETONE) PALLADIUM(0);Tris(dibenzilideneacetone)dipalladium(0)
- CBNumber:
- CB8132457
- Summenformel:
- C51H42O3Pd2
- Molgewicht:
- 915.71738
- MOL-Datei:
- 52409-22-0.mol
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Tris(dibenzylideneacetone)dipalladium Eigenschaften
- Schmelzpunkt:
- 152-155 °C(lit.)
- storage temp.
- Keep in dark place,Inert atmosphere,2-8°C
- InChI
- InChI=1S/2C17H14O.Pd/c2*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;/h2*1-14H;/b2*13-11+,14-12+;
- InChIKey
- UKSZBOKPHAQOMP-SVLSSHOZSA-N
- SMILES
- [Pd].C(=C/C1=CC=CC=C1)\C(/C=C/C1=CC=CC=C1)=O.C(=C/C1=CC=CC=C1)\C(/C=C/C1=CC=CC=C1)=O
- CAS Datenbank
- 52409-22-0(CAS DataBase Reference)
Tris(dibenzylideneacetone)dipalladium Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/38:Reizt die Augen und die Haut.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Verwenden
Tris(dibenzylideneacetone)dipalladium is used as a source of soluble Pd(0), in particular as a catalyst for various coupling reactions. Examples of reactions using this reagent are the Negishi coupling, Suzuki coupling, Carroll rearrangement, and Trost asymmetric allylic alkylation, as well as Buchwald–Hartwig amination
Synthese
A process for the preparation of tris(dibenzylideneacetone)dipalladium (chloroform) comprising the steps of:
(a) reacting a Pd(II) complex with an alkali metal halide in at least one alcohol solvent; and
(b) reacting the product of step (a) with a mixture comprising dibenzylideneacetone, chloroform and an inorganic base to form Pd2(dba)3.CHCl3.
Tris(dibenzylideneacetone)dipalladium Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Tris(dibenzylideneacetone)dipalladium Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 164)Lieferanten
52409-22-0()Verwandte Suche:
- PALLADIUM (0) BIS(DIBENZYLIDENEACETONE) SALT
- BIS(DIBENZYLIDENEACETONE) PALLADIUM(0)
- Tris(dibenzylideneacetone)dipalladium(0) [20% Pd]
- Tris(dibenzilideneacetone)dipalladium(0)
- PALLADIUM(0) BIS(DIBENZYLIDENEACETONE)
- PD(DBA)2
- tris(dibenzylideneacetone)dipalladium(o)(pd2(dba)3)
- Bis(dibenzylideneacetone)dipalladium
- Tris(dibenzylideneacetone)dipalladium
- Tris(dibenzylideneacetone
- Tris(dibenzylidineacetone)-dipalladium(o)
- Pd(dba)3
- Tris(dibenzylideneacetone)diplalladium(I)
- 52409-22-0
- C21H42O3Pd2
- Pd2C17H14O3
- Catalysis and Inorganic Chemistry
- Homogeneous Pd Catalysts
- Homogeneous Catalysts
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Transition Metal Compounds
- Metal Complexes
- Pd (Palladium) Compounds
- Catalysts-Ligands
