4-Thiacyclohexanon
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- CAS-Nr.
- 1072-72-6
- Bezeichnung:
- 4-Thiacyclohexanon
- Englisch Name:
- Tetrahydrothiopyran-4-one
- Synonyma:
- TETRAHYDRO-4H-THIOPYRAN-4-ONE;dihydro-2H-thiopyran-4(3H)-one;THIAN-4-ONE;4H-Thiopyran-4-one, tetrahydro-;Penthianone;4-OXOTHIANE;4-Oxothiane>THIAN-3-ONEOXIME;4-Thiacyclohexanon;4-thiacyclohexanone
- CBNumber:
- CB8202200
- Summenformel:
- C5H8OS
- Molgewicht:
- 116.18
- MOL-Datei:
- 1072-72-6.mol
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4-Thiacyclohexanon Eigenschaften
- Schmelzpunkt:
- 60-64 °C (lit.)
- Siedepunkt:
- 140.82°C (estimate)
- Dichte
- 1.050 (estimate)
- Brechungsindex
- 1.5100 (estimate)
- storage temp.
- Inert atmosphere,Room Temperature
- L?slichkeit
- Acetonitrile (Slightly), Chloroform (Slightly)
- Aggregatzustand
- Crystalline Solid
- Farbe
- White to pale yellow
- BRN
- 106464
- InChI
- InChI=1S/C5H8OS/c6-5-1-3-7-4-2-5/h1-4H2
- InChIKey
- OVRJVKCZJCNSOW-UHFFFAOYSA-N
- SMILES
- C1SCCC(=O)C1
- LogP
- 0.490 (est)
- CAS Datenbank
- 1072-72-6(CAS DataBase Reference)
- NIST chemische Informationen
- 4H-Thiopyran-4-one, tetrahydro-(1072-72-6)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
Xi |
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| R-S?tze: |
36/37/38 |
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| S-S?tze: |
22-24/25 |
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| WGK Germany |
3 |
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| HazardClass |
IRRITANT |
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| HS Code |
29349990 |
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| Speicherklasse |
11 - Combustible Solids |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
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P264, P280, P305+P351+P338,P337+P313P |
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| Sicherheit |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
| P337+P313 |
Bei anhaltender Augenreizung: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
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4-Thiacyclohexanon Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
WHITE TO PALE YELLOW CRYSTALLINE SOLID
Verwenden
Tetrahydro-4H-thiopyran-4-one is a cyclic carbonyl compound used as a reactant in the stereoselective preparation of [aryl(nitro)ethyl] carbonyl compounds via asymmetric Michael addition to nitroolefins catalyzed by chiral pyrrolidine-pyridine conjugate bases.
Allgemeine Beschreibung
The diastereoselectivity of the aldol reaction of tetrahydro-4H-thiopyran-4-one has been studied.
l?uterung methode
Purify it by recrystallisation from diisopropyl ether or pet ether and dry it in air. If too impure, then dissolve it in Et2O, wash with aqueous NaHCO3, then H2O, dry (MgSO4), filter, evaporate and the residue is recrystallised as before. [Cardwell J Chem Soc 715 1949.] The oxime can be recrystallised from CHCl3/pet ether (at -20o) and has m 84-85o [Barkenbus et al. J Org Chem 20 871 1955]. The 2,4-dinitrophenylhydrazone has m 186o (from EtOAc) [Barkenbus et al. J Org Chem 16 232 1951]. The S-dioxide is recrystallised from AcOH, m 173-174o [Fehnel & Carmack J Am Chem Soc 70 1813 1948, Beilstein 17 II 287, 17 III/IV 4172, 17/1 V 21].
4-Thiacyclohexanon Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Propanoic acid, 3,3'-thiobis-, di-2-propenyl ester (9CI)
4H-Thiopyran-4-one, 2,3-dihydro-
2H-Thiopyran, 3,6-dihydro-4-[(trimethylsilyl)oxy]-
1,4-dioxa-8-thiaspiro<4.5>decane-6-carboxaldehyde
Thian-4-one S-oxide
METHYL TETRAHYDRO-4-OXO-2H-THIOPYRAN-3-CARBOXYLATE
TETRAHYDROTHIOPYRAN-4-OL 97
Dimethyl-3,3'-thiobispropionat
1,5-DIBROMO-PENTAN-3-ONE
diethyl 3,3'-thiobispropionate
PIPERIDINIUM, 1,1-DIMETHYL-4-OXO-, IODIDE
3,3'-Thiodipropionsure
Downstream Produkte
4-Thiacyclohexanon Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 307)Lieferanten
1072-72-6(4-Thiacyclohexanon)Verwandte Suche:
- 1-Thiacyclohexan-4-one
- 2,3,5,6-Tetrahydro-4-thiopyranone
- 4H-tetrahydrothiopyran-4-one
- 4-Oxotetrahydrothiopyran
- Penthianone
- Tetrahydro-1,4-thiapyrone
- Tetrahydro-1-thio-4-pyrone
- Tetrahydro-1-thio-gamma-pyrone
- Tetrahydro-4H-thiapyran-4-one
- Tetrahydro-4-thiopyrone
- Tetrahydrothia-4-pyranone
- Tetrahydrothiopyranone
- TETRAHYDROTHIOPYRAN-4-ONE
- TETRAHYDRO-2H-THIOPYRAN-4-ONE
- 4-thiacyclohexanone
- 4-OXOTHIANE
- THIAN-3-ONEOXIME
- 2,3,5,6-Tetrahydro-4H-thiopyran-4-one
- Tetrahydrothiopyran-4-one,99%
- Tetrahydrothiopyran-4-one ,98%
- Tetrahydro-4H-thiopyran-4...
- Tetrahydrothiapyran-4-one
- Tetrahydrothiopyran-4-one, 99% 5GR
- Thian-4-one, 4-Oxotetrahydro-2H-thiopyran
- Tetrahydro-4H-thiopyran-4-one 99%
- Tetrahydro-4H-thiopyran-4-one, 99%, 99%
- 4-tetrahydrothiopyranone
- 4H-Thiopyran-4-one, tetrahydro- (8CI)(9CI)
- Tetrahydrothian-4-one
- 4-Thiacyclohexanon
- 4-Oxothiane>
- Tetrahydrothiopyran-4-one ISO 9001：2015 REACH
- 4H-Thiopyran-4-one, tetrahydro-
- dihydro-2H-thiopyran-4(3H)-one
- Tetrahydrothiophene-4-one
- Tetrahydrothiopyran-4-one 98%
- TETRAHYDRO-4H-THIOPYRAN-4-ONE
- THIAN-4-ONE
- 1072-72-6
- C5H8OS
- C5H14OS
- Building Blocks
- S-Containing
- Others
- Heterocyclic Building Blocks
- Building Blocks
- Chemical Synthesis
- Heterocyclic Building Blocks
- Ring Systems
- Heterocyclic Building Blocks
- Others
- S-Containing
