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Diazoacetylbenzene

Diazoacetylbenzene Struktur
3282-32-4
CAS-Nr.
3282-32-4
Englisch Name:
Diazoacetylbenzene
Synonyma:
α-Diazoacetophenone;Nsc25280;Diazoacetylbenzene;2-Diazoacetophenone;Benzoyldiazomethane;a-Diazoacetophenone;Acetophenone, 2-diazo-;2-Diazo-1-phenylethanone;Phenyl diazomethyl ketone;.Omega.-diazoacetophenone
CBNumber:
CB82352178
Summenformel:
C8H6N2O
Molgewicht:
146.15
MOL-Datei:
3282-32-4.mol

Diazoacetylbenzene Eigenschaften

Schmelzpunkt:
49 °C
Siedepunkt:
265.75°C (rough estimate)
Dichte
1.2312 (rough estimate)
Brechungsindex
1.4900 (estimate)
L?slichkeit
sol ether, THF; slightly sol pentane.
Aggregatzustand
rods
Farbe
pale yellow

Sicherheit

Diazoacetylbenzene Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

α-Diazoacetophenone is used as a precursor to carbenes and carbenoids; reagent for preparation of sulfonium, oxonium, and pyridinium ylides; 1,3 dipole for heterocycle synthesis; reagent for Lewis acid or transition metal-mediated insertion reactions; reagent for cyclopropanation of alkenes and for aromatic annulation.

synthetische

Preparative Methods of α-Diazoacetophenone: an improved method of synthesis of diazo ketones has been recently published, via acylation of the lithium enolate of the ketone with 2,2,2-Trifluoroethyl Trifluoroacetate and subsequent reaction with Methanesulfonyl Azide. [1] Alternatively, acylation of diazomethane with aroyl chlorides in the presence of triethylamine provides a general method for the synthesis of aromatic diazo ketones.[2]

Diazoacetylbenzene Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Diazoacetylbenzene Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 3)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Yantai Shengkailun Chemical Technology Co., Ltd. 13356901049
mark@sklnchem.cn China 9924 58
Shanghai Chemilab Biotechnology CO.,Ltd 18116465878 16510382999;
kmlb@kaimilaibo.com China 1883 58

  • 2-Diazo-1-phenylethanone
  • Benzoyldiazomethane
  • Diazoacetylbenzene
  • Diazomethyl(phenyl) ketone
  • .alpha.-Diazoacetophenone
  • .Omega.-diazoacetophenone
  • 2-Diazoacetophenone
  • Acetophenone, 2-diazo-
  • Ethanone, 2-diazo-1-phenyl-
  • Nsc25280
  • Phenyl diazomethyl ketone
  • a-Diazoacetophenone
  • 2-diazonio-1-phenylethenolate
  • 2-Diazo-1-phenylethan-1-one - [DA7316]
  • α-Diazoacetophenone
  • 3282-32-4
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