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AZIDOMETHYL PHENYL SULFIDE

AZIDOMETHYL PHENYL SULFIDE Struktur
77422-70-9
CAS-Nr.
77422-70-9
Englisch Name:
AZIDOMETHYL PHENYL SULFIDE
Synonyma:
PHENYLTHIOMETHYL AZIDE;[(AZIDOMETHYL)THIO]BENZENE;AZIDOMETHYL PHENYL SULFIDE;azidomethylsulfanylbenzene;(azidomethyl)(phenyl)sulfane;Azidomethyl phenyl sulfide 95%;[(Azidomethyl)thio]benzene Phenylthiomethyl Azide
CBNumber:
CB9399545
Summenformel:
C7H7N3S
Molgewicht:
165.22
MOL-Datei:
77422-70-9.mol

AZIDOMETHYL PHENYL SULFIDE Eigenschaften

Siedepunkt:
104-105 °C/5 mmHg (lit.)
Dichte
1.168 g/mL at 25 °C (lit.)
Brechungsindex
n20/D 1.5904(lit.)
Flammpunkt:
226 °F
storage temp. 
2-8°C
Aggregatzustand
liquid
Farbe
colorless to light-gold
InChI
1S/C7H7N3S/c8-10-9-6-11-7-4-2-1-3-5-7/h1-5H,6H2
InChIKey
KIQGRMGPIMCXSC-UHFFFAOYSA-N
SMILES
[N-]=[N+]=NCSc1ccccc1

Sicherheit

R-S?tze: 44
S-S?tze: 36
WGK Germany  3
Speicherklasse 10 - Combustible liquids

AZIDOMETHYL PHENYL SULFIDE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R44:Explosionsgefahr bei Erhitzen unter Einschluss.

S-S?tze Betriebsanweisung:

S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.

Verwenden

Azidomethyl Phenyl Sulfide is a reagent for amination of organomagnesium compounds; allows amination and oxidation of α,α- disubstituted ester enolates via 1,2,3-triazol-5-ones; a synthetic equivalent of methyl azide for the synthesis of methylaziridines; substituted α-azido sulfides undergo Beckmann-type rearrangements to provide lactams and imino thioethers.

Einzelnachweise

1. Trost, B. M.; Pearson, W. H. JACS 1981, 103, 2483.

AZIDOMETHYL PHENYL SULFIDE Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


AZIDOMETHYL PHENYL SULFIDE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 38)Lieferanten
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Aladdin Scientific

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Shandong Xiya Chemical Co., Ltd 13355009207 13355009207
3007715519@qq.com China 18728 57

77422-70-9()Verwandte Suche:


  • AZIDOMETHYL PHENYL SULFIDE
  • [(AZIDOMETHYL)THIO]BENZENE
  • PHENYLTHIOMETHYL AZIDE
  • [(Azidomethyl)thio]benzene Phenylthiomethyl Azide
  • Azidomethyl phenyl sulfide 95%
  • azidomethylsulfanylbenzene
  • (azidomethyl)(phenyl)sulfane
  • 77422-70-9
  • C6H5SCH2N3
  • Organic Building Blocks
  • Nitrogen Compounds
  • Building Blocks
  • Azides
  • Amination
  • Sulfur Compounds (for Synthesis)
  • Sulfur Compounds (for Synthesis)
  • Amination
  • Synthetic Organic Chemistry
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