Trirutheniumdodecacarbonyl
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- CAS-Nr.
- 15243-33-1
- Bezeichnung:
- Trirutheniumdodecacarbonyl
- Englisch Name:
- Ruthenium carbonyl
- Synonyma:
- Ru3(CO)12;TRIRUTHENIUM DODECACARBONYL;DODECACARBONYLTRIRUTHENIUM;pentaoxonium;RUTHENIUM CARBONYL;Rutheniumcarbonyl,99%;Ruthenium carbonyl 99%;carbon monoxide ruthenium;DIRUTHENIUM DODECACARBONYL;Ruthenium,dodecacarbonyltri-
- CBNumber:
- CB9426890
- Summenformel:
- C12O12Ru3
- Molgewicht:
- 639.33
- MOL-Datei:
- 15243-33-1.mol
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Trirutheniumdodecacarbonyl Eigenschaften
- Schmelzpunkt:
- 150 °C
- storage temp.
- Inert atmosphere,Room Temperature
- L?slichkeit
- Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
- Aggregatzustand
- crystal
- Farbe
- orange
- InChI
- InChI=1S/12CO.3Ru/c12*1-2;;;
- InChIKey
- NQZFAUXPNWSLBI-UHFFFAOYSA-N
- SMILES
- [O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[Ru].[Ru].[Ru]
- CAS Datenbank
- 15243-33-1(CAS DataBase Reference)
- EPA chemische Informationen
- Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
F,Xn |
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| R-S?tze: |
11-20-2017/11/20 |
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| S-S?tze: |
24/25 |
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| RIDADR |
1325 |
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| WGK Germany |
3 |
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| Hazard Note |
Flammable/Harmful |
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| TSCA |
TSCA listed |
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| HazardClass |
6.1 |
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| PackingGroup |
II |
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| HS Code |
28439000 |
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| Speicherklasse |
11 - Combustible Solids |
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| Hazard Classifications |
Acute Tox. 4 Inhalation |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H332 |
Gesundheitssch?dlich bei Einatmen. |
Akute Toxizit?t inhalativ |
Kategorie 4 |
Warnung |
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P261, P271, P304+P340, P312 |
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| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P271 |
Nur im Freien oder in gut belüfteten R?umen verwenden. |
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Trirutheniumdodecacarbonyl Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R11:Leichtentzündlich.
R20:Gesundheitssch?dlich beim Einatmen.
S-S?tze Betriebsanweisung:
S24/25:Berührung mit den Augen und der Haut vermeiden.
Beschreibung
Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.
Chemische Eigenschaften
The substance appears as orange plates or powder and is soluble in non-polar organic solvents.
Verwenden
Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).
Reaktionen
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Catalyst for the conversion of enynes to catechol derivatives.
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Catalyst for the intermolecular [2+2+1] cycloaddition of ketones, CO and alkenes or alkynes.
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3-Component couplings.
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Reaction of α,β-unsaturated imines with carbon monoxide and alkenes to form β,γ-unsaturated γ-butyroactams.
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Ester decarboxylation.
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Catalyst for hydroamination and C-H bond activation.
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Used in sp3 C-H bond arylation and carbonylation.
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Ru/halide catalytic system for C-C bond forming reaction between alkynes and unsaturated carbonyl compounds.
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Amination of α-hydroxy amides.
Allgemeine Beschreibung
Atomic number of base material: 44 Ruthenium
Trirutheniumdodecacarbonyl Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Trirutheniumdodecacarbonyl Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 238)Lieferanten
15243-33-1(Trirutheniumdodecacarbonyl)Verwandte Suche:
- dodecacarbonyltri-rutheniutriangulo
- TrirutheniuM dodecacarbonyl 99%
- Ruthenium, dodecacarbonyltri-, triangulo
- Ruthenium,dodecacarbonyltri-
- DODECACARBONYLTRIRUTHENIUM (0)
- RUTHENIUM CARBONYL
- Rutheniumcarbonyl,99%
- Ruthenium carbonyl 99%
- Ruthenium carbonyl, tri-Ruthenium dodecacarbonyl
- Dodecacarbonyltriruthenium(0) Available in laboratory quantities only dec. 150
- Triruthenium dodecacarbonyl,99%
- TrirutheniuM dodecacarbonyl, 99% 1GR
- TrirutheniuM dodecacarbonyl, 99% 5GR
- RutheniuM carbonyl,98% Ru3(CO)12
- Trirutheniumdodecarbonyl(DCR)
- pentaoxonium
- Carbon monooxide - ruthenium (4:1)
- Triruthenium dodecacarbonyl/ Ruthenium carbonyl/Ru3(CO)12
- RUTHENIUM CARBONYL ISO 9001：2015 REACH
- DIRUTHENIUM DODECACARBONYL
- carbon monoxide ruthenium
- Dichloro(1,5-cyclooctadiene)palladium(lI)
- DODECACARBONYLTRIRUTHENIUM
- Ru3(CO)12
- TRIRUTHENIUM DODECACARBONYL
- 15243-33-1
- 15234-33-1
- 15243-33-6
- 12CO3Ru
- C12H12Ru3
- C12O12Ru3
- Ru3C12O12
- Ru Catalysts
- Transition Metal Compounds
- Classes of Metal Compounds
- Ru (Ruthenium) Compounds
- Catalysis and Inorganic Chemistry
- Ru
- Classes of Metal Compounds
- Ru (Ruthenium) Compounds
- Transition Metal Compounds
- metal carbonyl complexes
