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SENKIRKIN

SENKIRKIN Struktur
2318-18-5
CAS-Nr.
2318-18-5
Englisch Name:
SENKIRKIN
Synonyma:
Kushenin;SENKIKIN;renardin;SENKIRKIN;nsc-89945;RENARIDINE;Senkarkane;senkirkine;renardine[neutral];Renardine (neutral)
CBNumber:
CB9427741
Summenformel:
C19H27NO6
Molgewicht:
365.42
MOL-Datei:
2318-18-5.mol

SENKIRKIN Eigenschaften

Schmelzpunkt:
197°C
Siedepunkt:
497.19°C (rough estimate)
Dichte
1.2439 (rough estimate)
Brechungsindex
1.5180 (estimate)
storage temp. 
-20°C
Aggregatzustand
Solid
pka
12.67±0.40(Predicted)
Farbe
White to off-white
LogP
0.690 (est)
IARC
3 (Vol. 31, Sup 7) 1987
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 22
RIDADR  1544
WGK Germany  3
HazardClass  6.1(b)
PackingGroup  III
Giftige Stoffe Daten 2318-18-5(Hazardous Substances Data)
Bildanzeige (GHS) Skull and Crossbones (GHS06)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H301 Giftig bei Verschlucken. Akute Toxizit?t oral Kategorie 3 Achtung P264, P270, P301+P310, P321, P330,P405, P501
Sicherheit
P301+P310 BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.

SENKIRKIN Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A further hepatotoxiC alkaloid present in Senecio kirkii Hook, S. renardi and Nardosrnia laevigata. The base has [α]25D - 16° (c 1.89, MeOH) or[α]15D - 6.2° (c 1.91, CHCI3). It forms colourless plates when crystallized from either Me2CO or AcOEt and yields a picrate, m.p. 225.5-226°C and a picrolonate, m.p. 109- 110°C. The ultraviolet spectrum shows a single absorption maximum at 219 mp.. Several crystalline salts and derivatives are known, e.g. the aurichloride, m.p. 182.5-183.5°C; platinichloride, m.p. 196-7°C (dec.); bitartrate, m.p. 201°C; reineckate, m.p. 169-171°C; picrate, m.p. 225- 225.5°C; picrolonate, m.p. 138°C and the methiodide, m.p. 194-6°C (dec.). The O-acetate occurs naturally (q.v.) in Senecio kirkii.

Sicherheitsprofil

Poison by ingestion and intraperitoneal routes. Questionable carcinogen with experimental neoplastigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of Nox

Einzelnachweise

Briggs, Mangan, Russell., J. Chern. Soc., 1891 (1948)
Massagetov, Kuzovkov.,J. Gen. Chern., USSR, 23, 158 (1953)
Danilova, Konovalova., ibid, 30, 1921 (1961)
Danilova, Koretskaya, Utkin., ibid, 31, 3815 (1961)
Wunderlich., Chern. Ind., 2089 (1962)
Briggs et al., J. Chern. Soc., 2492 (1965)

SENKIRKIN Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


SENKIRKIN Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 79)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shanghai Zheyan Biotech Co., Ltd.
18017610038
zheyansh@163.com CHINA 3619 58
Chengdu Biopurify Phytochemicals Ltd.
+86-28-82633860; +8618080483897
sales@biopurify.com China 4616 58
TargetMol Chemicals Inc.
+1-781-999-5354; +17819995354
marketing@targetmol.com United States 32467 58
Career Henan Chemica Co
+86-0371-86658258 +8613203830695
laboratory@coreychem.com China 30224 58
Finetech Industry Limited
+86-27-8746-5837 +8619945049750
info@finetechnology-ind.com China 9539 58
Chengdu Youngshe Chemical Co., Ltd.
+8618108235634
Cecilia@youngshechem.com China 2345 58
Shaanxi Didu New Materials Co. Ltd
+86-86-17392712697 +8617792793228
1069@dideu.com China 8662 58
Shanghai Acmec Biochemical Technology Co., Ltd.
+86-18621343501; +undefined18621343501
product@acmec-e.com China 33324 58
SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580
cooperation@kean-chem.com China 40066 58
J & K SCIENTIFIC LTD. 18210857532; 18210857532
jkinfo@jkchemical.com China 96815 76

2318-18-5()Verwandte Suche:


  • RENARIDINE
  • SENKIKIN
  • SENKIRKIN
  • (4Z)-4-Ethylidene-7-hydroxy-6,7,14-trimethyl-2,9-dioxa-14-azabicyclo[9.5.1]heptadec-11-ene-3,8,17-trione
  • 11,16-trione,12-hydroxy-4-methyl-8-secosenecionan-8
  • 2,12-Dihydroxy-4-methyl-11,16-dioxosenecionanium
  • 4,8-Secosenecionan-8,11,16-trione, 12-hydroxy-4-methyl-
  • 8,12-dihydroxy-4-methyl-11,16-dioxo-senecionaniu
  • trans-15-ethylidene-12-beta-hydroxy-4,12-alpha,13-beta-trimethyl8-oxo-4,8se
  • 12-Hydroxy-4-methyl-4,8-secosenecionan-8,11,16-trione
  • SENKIRKIN(RENARDINE)(SH)
  • nsc-89945
  • renardin
  • Renardine (neutral)
  • renardine[neutral]
  • Senecionanium, 8,12-dihydroxy-4-methyl-11,16-dioxo-
  • Senkarkane
  • senkirkine
  • Senkirkine (neutral)
  • senkirkine(neutral)
  • senkirkine[neutral]
  • trans-15-Ethylidene-12-beta-hydroxy-4,12-alpha,13-beta-trimethyl 8-oxo-4,8 secosenec-1-enine
  • 2,9-Dioxa-14-azabicyclo[9.5.1]heptadec-11-ene-3,8,17-trione, 4-ethylidene-7-hydroxy-6,7,14-trimethyl-, (1R,4Z,6R,7R)-
  • SENKIRKIN(RENARDINE)
  • Senkirkine 100 μg/mL in Water
  • Pyrrolizidine alkaloids Mixture 661 100 μg/mL in Methanol
  • Senkirkin (Standard)
  • Kushenin
  • 2318-18-5
  • C19H28NO6
  • Heterocycles
  • Mutagenesis Research Chemicals
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