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(R)-(β-D-Glucopyranosyloxy)phenylacetonitril

PRUNASIN Struktur
99-18-3
CAS-Nr.
99-18-3
Bezeichnung:
(R)-(β-D-Glucopyranosyloxy)phenylacetonitril
Englisch Name:
PRUNASIN
Synonyma:
(r)-prunasin;Prunacin;PRUNASIN;d-prunasin;Noguro Sakura;Wild cherry glycoside;(r)-benzeneacetonitril;Prunasin (6CI, 7CI, 8CI);D-MANDELONITRILE B-D-GLUCOSIDE;D-Mandelonitrile β-D-glucoside
CBNumber:
CB9677133
Summenformel:
C14H17NO6
Molgewicht:
295.29
MOL-Datei:
99-18-3.mol

(R)-(β-D-Glucopyranosyloxy)phenylacetonitril Eigenschaften

Schmelzpunkt:
138-148°C
Siedepunkt:
527.0±50.0 °C(Predicted)
Dichte
1.45±0.1 g/cm3(Predicted)
storage temp. 
Hygroscopic, -20°C Freezer, Under Inert Atmosphere
L?slichkeit
Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
Aggregatzustand
Powder
pka
12.71±0.70(Predicted)
Farbe
White to off-white
Stabilit?t:
Hygroscopic
Major Application
metabolomics
vitamins, nutraceuticals, and natural products
Kosmetik-Inhaltsstoffe Funktionen
SKIN CONDITIONING
InChI
InChI=1/C14H17NO6/c15-6-9(8-4-2-1-3-5-8)20-14-13(19)12(18)11(17)10(7-16)21-14/h1-5,9-14,16-19H,7H2/t9-,10+,11+,12-,13+,14+/s3
InChIKey
ZKSZEJFBGODIJW-OAWZEMCWNA-N
SMILES
O([C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@H](C1C=CC=CC=1)C#N |&1:1,2,3,5,7,12,r|
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher T
R-S?tze: 36/37/38-25-60
S-S?tze: 26-36/37/39-61-45
RIDADR  UN 2811 6.1 / PGIII
WGK Germany  3
RTECS-Nr. UL3420000
Speicherklasse 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Repr. 1B
Bildanzeige (GHS) Skull and Crossbones (GHS06)Health Hazard (GHS08)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H301 Giftig bei Verschlucken. Akute Toxizit?t oral Kategorie 3 Achtung P264, P270, P301+P310, P321, P330,P405, P501
H360 Kann die Fruchtbarkeit beeintr?chtigen oder das Kind im Mutterleib sch?digen. Fertility (Fruchtbarkeit) Kategorie 1 Achtung
Sicherheit
P201 Vor Gebrauch besondere Anweisungen einholen.

(R)-(β-D-Glucopyranosyloxy)phenylacetonitril Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

Beschreibung

(R)-Prunasin is a cyanogenic glucoside that is the precursor to amygdalin, a bitter component found in species of the genera Prunus and Olinia. It can be degraded to hydrogen cyanide, glucose, and benzaldehyde by the action of prunasin hydrolase and mandelonitrile lyase and possesses inhibitory effects on plant growth. (R)-Prunasin reportedly inhibits rat DNA polymerase β, which performs base excision repair required for DNA maintenance and replication, with an IC50 value of 98 μM.

Chemische Eigenschaften

White Solid

Verwenden

Used in the synthesis of cyanogen glycoside. A component of antiperspirants, deodorants, body soaps, shampoos, hair rinses, and hair

Enzyminhibitor

This cyanogenic glucoside (FW = 295.29 g/mol; CAS 99-18-3), also known as D(R)-mandelonitrile-b-D-glucoside, is readily obtained from amygdalin and is found in the pits of Prunus serotina. Prunasin is soluble in water and will give rise to prulaurasin (i.e., the diastereoisomeric mixture of DL(RS)- mandelonitrile-b-D-glucoside [i.e., prunasin and sambunigrin]). Target(s): DNA-directed DNA polymerase; DNA polymerase b; and a,a trehalase.

(R)-(β-D-Glucopyranosyloxy)phenylacetonitril Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(R)-(β-D-Glucopyranosyloxy)phenylacetonitril Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 124)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Shaanxi Dideu Medichem Co. Ltd
+8617392709771
1097@dideu.com China 3992 58
Chengdu GLP biotechnology Co Ltd
028-87075086 13350802083
scglp@glp-china.com CHINA 1824 58
Chengdu Biopurify Phytochemicals Ltd.
+86-28-82633860; +8618080483897
sales@biopurify.com China 4616 58
career henan chemical co
+86-0371-86658258 +8613203830695
factory@coreychem.com China 29792 58
Hubei Ipure Biology Co., Ltd
+8613367258412
ada@ipurechemical.com China 10236 58
HONG KONG IPURE BIOLOGY CO.,LIMITED
86 18062405514 18062405514
ada@ipurechemical.com CHINA 3461 58
Finetech Industry Limited
+86-27-8746-5837 +8619945049750
info@finetechnology-ind.com China 9539 58
TargetMol Chemicals Inc.
+1-781-999-5354;
support@targetmol.com United States 39039 58
HANGZHOU LEAP CHEM CO., LTD.
+86-571-87711850
market18@leapchem.com China 43333 58
R&D Scientific Inc.
+1-2266000236
sales@rdscientific.com Canada 1939 58

99-18-3((R)-(β-D-Glucopyranosyloxy)phenylacetonitril)Verwandte Suche:


  • D-Mandelonitrile β-D-glucoside
  • (R)-α-(β-D-Glucopyranosyloxy)benzeneacetonitrile
  • (αR)-α-(β-D-Glucopyranosyloxy)-α-phenylacetonitrile
  • [(αR)-α-Cyanobenzyl]β-D-glucopyranoside
  • Prunacin
  • (2R)-2-phenyl-2-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyacetonitrile
  • (2R)-2-phenyl-2-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-ethanenitrile
  • (2R)-2-phenyl-2-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-methylol-tetrahydropyran-2-yl]oxy-acetonitrile
  • PENTAMETHYL-6-HYDROXYCHROMAN, 2,2,5,7,8-(RG)
  • Benzeneacetonitrile, a-(b-D-glucopyranosyloxy)-, (aR)-
  • D-MANDELONITRILE-BETA-D-GLUCOSIDE
  • PRUNASIN
  • (R)-(beta-D-glucopyranosyloxy)phenylacetonitrile
  • D-MANDELONITRILE B-D-GLUCOSIDE
  • (r)-alpha-(beta-d-glucopyranosyloxy)benzene-acetonitrile
  • (r)-benzeneacetonitril
  • d-prunasin
  • Noguro Sakura
  • Benzeneacetonitrile, α-(β-D-glucopyranosyloxy)-, (αR)-
  • Wild cherry glycoside
  • Prunasin (6CI, 7CI, 8CI)
  • D-Mandelonitrile β-D-glucoside
  • (R)-2-Phenyl-2-(((2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)acetonitrile
  • (r)-prunasin
  • 99-18-3
  • Chiral Reagents
  • Miscellaneous Natural Products
  • Aromatics
  • Carbohydrates & Derivatives
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