6-Bromo-2-methylquinoline
- CAS No.
- 877-42-9
- Chemical Name:
- 6-Bromo-2-methylquinoline
- Synonyms
- 6-BROMOQUINALDINE;6-Bromo-2-methyL;6-BROMOQUINAIDINE;6-Bromoquildine, 98%;6-BROMO-2-METHYLQUINOLINE;Quinoline, 6-bromo-2-methyl-;6-Bromo-2-methylquinoline >6-BroMo-2-Methylquinoline, 97+%;6-Bromo-2-methylquinoline, 97%, OS-2039;6-Bromo-2-methylquinoline ISO 9001：2015 REACH
- CBNumber:
- CB0156824
- Molecular Formula:
- C10H8BrN
- Molecular Weight:
- 222.08
- MDL Number:
- MFCD00079724
- MOL File:
- 877-42-9.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 6-Bromo-2-methylquinoline 97% | 649279 | 5g | $40.9 |
| 6-Bromo-2-methylquinoline 97% | 649279 | 25g | $148 |
| 6-Bromo-2-methylquinoline >98.0%(GC)(T) | B3039 | 5g | $90 |
| 6-Bromo-2-methylquinoline >98.0%(GC)(T) | B3039 | 25g | $293 |
| 6-Bromo-2-methylquinoline 98% | AS40529 | 5g | $36 |
| More product size | |||
| Melting point | 101-105 °C (lit.) |
|---|---|
| Boiling point | 299.7±20.0 °C(Predicted) |
| Density | 1.488±0.06 g/cm3(Predicted) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | soluble in Methanol |
| form | solid |
| pka | 5.02±0.43(Predicted) |
| color | Grey |
| InChI | 1S/C10H8BrN/c1-7-2-3-8-6-9(11)4-5-10(8)12-7/h2-6H,1H3 |
| InChIKey | SQRYQSKJZVQJAY-UHFFFAOYSA-N |
| SMILES | Cc1ccc2cc(Br)ccc2n1 |
| CAS DataBase Reference | 877-42-9(CAS DataBase Reference) |
| NIST Chemistry Reference | 6-Bromoquinaldine(877-42-9) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H315-H317-H318-H334-H335 | |||||||||
| Precautionary statements | P261-P280-P305+P351+P338-P342+P311 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Faceshields, Gloves | |||||||||
| Hazard Codes | Xn,Xi | |||||||||
| Risk Statements | 22-37/38-42-36/37/38-20/21/22 | |||||||||
| Safety Statements | 26-39-36/37/39-24/25-22 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 29339900 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Eye Dam. 1 Resp. Sens. 1 Skin Irrit. 2 Skin Sens. 1 STOT SE 3 |
|||||||||
| NFPA 704 |
|
6-Bromo-2-methylquinoline price More Price(60)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 649279 | 6-Bromo-2-methylquinoline 97% | 877-42-9 | 5g | $40.9 | 2026-04-30 | Buy |
| Sigma-Aldrich | 649279 | 6-Bromo-2-methylquinoline 97% | 877-42-9 | 25g | $148 | 2024-03-01 | Buy |
| TCI Chemical | B3039 | 6-Bromo-2-methylquinoline >98.0%(GC)(T) | 877-42-9 | 5g | $90 | 2026-04-30 | Buy |
| TCI Chemical | B3039 | 6-Bromo-2-methylquinoline >98.0%(GC)(T) | 877-42-9 | 25g | $293 | 2026-04-30 | Buy |
| Activate Scientific | AS40529 | 6-Bromo-2-methylquinoline 98% | 877-42-9 | 5g | $36 | 2026-06-04 | Buy |
6-Bromo-2-methylquinoline Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powder
Synthesis
106-40-1
123-73-9
877-42-9
GENERAL METHOD: 4-Bromoaniline (1.50 mmol) and trans-2-butenal (1.00 mmol) were dissolved in 1.5 mL of ether (Et2O) in a reaction flask fitted with a magnetic stir bar, followed by the addition of silver(I)-exchanged montmorillonite K10 (0.50 g). After stirring for 5 min, the solvent was removed under vacuum to obtain a dry powder. The reaction mixture was heated at 120 °C for 3 hours. After the reaction mixture was cooled to room temperature, it was filtered through a short silica gel plug and the solid residue was washed well with dichloromethane (CH2Cl2). After removal of the solvent under vacuum, the crude product was purified by silica gel column chromatography, eluting using a solvent mixture of hexane/ethyl acetate (EtOAc) to give the final 6-bromo-2-methylquinoline (3a-3k). Note: For recycling/reuse studies, the crude product is separated by gravity filtration and the clay material is washed several times with dichloromethane (CH2Cl2), air-dried and weighed. The process is repeated for successive recycling/reuse reactions.
References
[1] Advanced Functional Materials, 2012, vol. 22, # 2, p. 345 - 352
[2] Heterocycles, 2016, vol. 92, # 12, p. 2213 - 2224
[3] Tetrahedron Letters, 2011, vol. 52, # 22, p. 2840 - 2843
[4] Chemical Communications, 2012, vol. 48, # 35, p. 4196 - 4198
[5] Dalton Transactions, 2012, vol. 41, # 20, p. 6189 - 6194
6-Bromo-2-methylquinoline Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan Bao Enluo International TradeCo.，LTD | +86-17331933971 | deasea125996@gmail.com | China | 2472 | 58 |
| Chembon Pharmaceutical Co., Ltd. | +86-28-8425-2981 | CHINA | 722 | 55 | |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
| HaBo Hong Kong Co., Limited. | +86-25-18512596065 | info@habotech.com | CHINA | 933 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29792 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Hebei Zhanyao Biotechnology Co. Ltd | 15369953316 +8615369953316 | admin@zhanyaobio.com | China | 2123 | 58 |
View Lastest Price from 6-Bromo-2-methylquinoline manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-11-18 | 6-Bromo-2-methylquinoline
877-42-9
|
$1.10 | 1g | 99.00% | 100 Tons | Dideu Industries Group Limited | |
 |
2024-02-19 | 6-Bromo-2-methylquinoline
877-42-9
|
$1250.00 | 1g | 98 | 500 Kg | R&D Scientific Inc. | |
 |
2023-08-18 | 6-Bromo-2-methylquinoline
877-42-9
|
$10.00 | 1kg | 99% | 500t/month | Henan Bao Enluo International TradeCo.，LTD |
-
- 6-Bromo-2-methylquinoline
877-42-9
- $1.10
- 99.00%
- Dideu Industries Group Limited
-
- 6-Bromo-2-methylquinoline
877-42-9
- $1250.00
- 98
- R&D Scientific Inc.
-
- 6-Bromo-2-methylquinoline
877-42-9
- $10.00
- 99%
- Henan Bao Enluo International TradeCo.，LTD
