METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE
- CAS No.
- 877624-40-3
- Chemical Name:
- METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE
- Synonyms
- METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE;3-Bromo-5-bromomethyl-benzoic acid methyl ester;Benzoic acid, 3-bromo-5-(bromomethyl)-, methyl ester
- CBNumber:
- CB02455576
- Molecular Formula:
- C9H8Br2O2
- Molecular Weight:
- 307.97
- MDL Number:
- MFCD11044991
- MOL File:
- 877624-40-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Methyl 3-bromo-5-(bromomethyl)benzoate | CKB62440 | 2.5g | $324.5 |
| Methyl 3-bromo-5-(bromomethyl)benzoate 98% | AS42238 | 1g | $108 |
| Methyl 3-bromo-5-(bromomethyl)benzoate 98% | AS42238 | 5g | $316 |
| Methyl 3-bromo-5-(bromomethyl)benzoate 98% | AS42238 | 25g | $1026 |
| Methyl 3-bromo-5-(bromomethyl)benzoate | 102647 | 1.00g | $67 |
| More product size | |||
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS05 |
|---|---|
| Signal word | Danger |
| Hazard statements | H315-H302-H335-H318 |
| Precautionary statements | P280-P305+P351+P338-P310-P264-P280-P302+P352-P321-P332+P313-P362-P264-P270-P301+P312-P330-P501 |
| HS Code | 2916399090 |
METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE price More Price(39)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | CKB62440 | Methyl 3-bromo-5-(bromomethyl)benzoate | 877624-40-3 | 2.5g | $324.5 | 2026-06-04 | Buy |
| Activate Scientific | AS42238 | Methyl 3-bromo-5-(bromomethyl)benzoate 98% | 877624-40-3 | 1g | $108 | 2026-06-04 | Buy |
| Activate Scientific | AS42238 | Methyl 3-bromo-5-(bromomethyl)benzoate 98% | 877624-40-3 | 5g | $316 | 2026-06-04 | Buy |
| Activate Scientific | AS42238 | Methyl 3-bromo-5-(bromomethyl)benzoate 98% | 877624-40-3 | 25g | $1026 | 2026-06-04 | Buy |
| Matrix Scientific | 102647 | Methyl 3-bromo-5-(bromomethyl)benzoate | 877624-40-3 | 1.00g | $67 | 2026-05-18 | Buy |
METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE Chemical Properties,Uses,Production
Synthesis
307353-32-8
877624-40-3
General procedure for the synthesis of methyl 3-bromo-5-(bromomethyl)benzoate from methyl 3-bromo-5-(hydroxymethyl)benzoate: methyl 3-bromo-5-(hydroxymethyl)benzoate (2.0 g, 8.2 mmol) was mixed with triphenylphosphine (4.28 g, 16.3 mmol) in tetrahydrofuran (20 mL) and the mixture was cooled down to 0°C. The reaction was completed by the addition of N-bromosuccinimidamide (3.05 g, 17.1 mmol). Subsequently, N-bromosuccinimide (3.05 g, 17.1 mmol) was added in batches and the reaction mixture was allowed to gradually warm up to room temperature. After 16 h of reaction, the reaction mixture was diluted with ethyl acetate, washed sequentially with saturated sodium bicarbonate solution (2×) and brine (2×), the organic phase was dried with anhydrous sodium sulfate and concentrated under reduced pressure. Purification by silica gel column chromatography (eluent: 10% ethyl acetate/hexane) gave 2.1 g of light brown oily product in 83% yield. The product was identified by 1H-NMR (CDCl3, 300 MHz): δ 8.07 (s, 1H), 7.96 (s, 1H), 7.70 (s, 1H), 4.42 (s, 2H), 3.90 (s, 3H). Mass spectrometry analysis showed a molecular ion peak of 308.93 (MH)+.
References
[1] Patent: US2007/249607, 2007, A1. Location in patent: Page/Page column 85
METHYL 3-BROMO-5-(BROMOMETHYL)BENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30224 | 58 |
| Win-Win chemical CO., Limited | +86-0086-577-64498589 +86-15355981851 | sales@win-winchemical.com | China | 14304 | 58 |
| AFINE CHEMICALS LIMITED | +86-571-85134551 | info@afinechem.com | China | 15079 | 58 |
| Zhejiang J&C Biological Technology Co.,Limited | +1-2135480471 +1-2135480471; | sales@sarms4muscle.com | China | 10457 | 58 |
| Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4327 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +8618949823763 | sales@tnjchem.com | China | 25356 | 58 |
| Aromsyn Co., Ltd. | +86-0571-85585865 +8613336024896 | CB@aromsyn.com | China | 19183 | 58 |
| Aceschem Inc. | +1-817863-6948 +1-（817）863-6948 | sales@aceschem.com | United States | 19632 | 58 |
