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ChemicalBook >> CAS DataBase List >>Thiacloprid

Thiacloprid

CAS No.
111988-49-9
Chemical Name:
Thiacloprid
Synonyms
Bariard;Biscaya;Calypso;ntn33894;yrc 2894;hiaclopri;THIACLOPRID;Thiaclopyrid;Calypso 70WG;Bay YRC 2894
CBNumber:
CB0260844
Molecular Formula:
C10H9ClN4S
Molecular Weight:
252.72
MDL Number:
MFCD02101042
MOL File:
111988-49-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-31 15:25:14
Product description Number Pack Size Price
Thiacloprid PESTANAL?, analytical standard 37905 100mg $145
Thiacloprid certified reference material, TraceCERT? 14783 50mg $239
Thiacloprid ≥98% 25824 25mg $28
Thiacloprid ≥98% 25824 50mg $53
Thiacloprid ≥98% 25824 100mg $99
More product size

Thiacloprid Properties

Melting point 128-129°
Boiling point 423.1±55.0 °C(Predicted)
Density 1.42±0.1 g/cm3(Predicted)
vapor pressure 0-0Pa at 20-25℃
storage temp. -20°C
solubility Chloroform: Slightly Soluble,Methanol: Slightly Soluble
form Solid
pka 0.01±0.10(Predicted)
color White to off-white
Henry's Law Constant 9.0×108 mol/(m3Pa) at 25℃, HSDB (2015)
Major Application agriculture
environmental
InChI InChI=1S/C10H9ClN4S/c11-9-2-1-8(5-13-9)6-15-3-4-16-10(15)14-7-12/h1-2,5H,3-4,6H2/b14-10+
InChIKey HOKKPVIRMVDYPB-GXDHUFHOSA-N
SMILES N1(CCS/C/1=N/C#N)CC1=CN=C(Cl)C=C1
LogP 1.3-1.4 at 24℃ and pH4-9
Surface tension 72mN/m at 150mg/L and 20℃
CAS DataBase Reference 111988-49-9(CAS DataBase Reference)
FDA UNII DSV3A944A4
Pesticides Freedom of Information Act (FOIA) Thiacloprid
EPA Substance Registry System Thiacloprid (111988-49-9)
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H332-H336-H351-H360FD-H410
Precautionary statements  P201-P273-P301+P310+P330-P304+P340+P312
target organs Central nervous system
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xn
Risk Statements  20/22-52/53
Safety Statements  60
RIDADR  2588
WGK Germany  2
RTECS  GS6093749
HazardClass  6.1(b)
PackingGroup  III
HS Code  29349990
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Acute Tox. 4 Inhalation
Aquatic Acute 1
Aquatic Chronic 1
Carc. 2
Repr. 1B
STOT SE 3
Hazardous Substances Data 111988-49-9(Hazardous Substances Data)
Toxicity LD50 in male, female rats (mg/kg): 836, 444 orally; >2000, >2000 dermally; LC50 (4 hr) in male, female rats (mg/m3): >2535, 1223; LC50 (96 hr) in rainbow trout (mg/l): 30.5 (Elbert)
REACH Registrations Active
NFPA 704
0
3 0

Thiacloprid price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 37905 Thiacloprid PESTANAL?, analytical standard 111988-49-9 100mg $145 2026-04-30 Buy
Sigma-Aldrich 14783 Thiacloprid certified reference material, TraceCERT? 111988-49-9 50mg $239 2026-04-30 Buy
Cayman Chemical 25824 Thiacloprid ≥98% 111988-49-9 25mg $28 2026-04-30 Buy
Cayman Chemical 25824 Thiacloprid ≥98% 111988-49-9 50mg $53 2026-04-30 Buy
Cayman Chemical 25824 Thiacloprid ≥98% 111988-49-9 100mg $99 2026-04-30 Buy
Product number Packaging Price Buy
37905 100mg $145 Buy
14783 50mg $239 Buy
25824 25mg $28 Buy
25824 50mg $53 Buy
25824 100mg $99 Buy

Thiacloprid Chemical Properties,Uses,Production

Uses

Insecticide.

Production Methods

The production of thiacloprid involves a multi-step synthesis based around coupling two key intermediates. First, 2-cyanoimino-1,3-thiazolidine is synthesized from precursors like cyanamide, carbon disulfide, and cysteamine hydrochloride through cyclization reactions. Separately, 2-chloro-5-chloromethylpyridine is prepared from 2-chloro-5-methylpyridine via chlorination. These two intermediates are then reacted in a suitable solvent, such as methanol or n-butanol, in the presence of a base like guanidine, which facilitates nucleophilic substitution to form the final product.

Definition

ChEBI: Thiacloprid is a nitrile that is cyanamide in which the hydrogens are replaced by a 1,3-thiazolidin-2-ylidene group which in turn is substituted by a (6-chloropyridin-3-yl)methyl group at the ring nitrogen. It has a role as a xenobiotic, an environmental contaminant and a neonicotinoid insectide. It is a member of thiazolidines, a nitrile and a monochloropyridine. It is functionally related to a 2-chloropyridine and a cyanamide.

General Description

Thiacloprid is a chloronicotinyl insecticide, which can be commonly used in agriculture in order to control various sucking insects like aphids, whiteflies and some jassids. It can also be actively used against weevils, leaf miners and various species of beetles.

Find more information here: Neonicotinoids

Hazard

Moderately toxic by ingestion and inhalation. A reproductive hazard.

Mechanism of action

Contact and stomach action with some systemic properties. Nicotinic acetylcholine receptor (nAChR) channel blocker.

Pesticide Type

Insecticide; Molluscicide

Thiacloprid Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 224)Suppliers
Supplier Tel Email Country ProdList Advantage
Qingdao Trust Agri Chemical Co.,Ltd
+86-008615963231493 +86-008613573296305 trustagri@hotmail.com China 299 58
Henan Bao Enluo International TradeCo.,LTD
+86-17331933971 deasea125996@gmail.com China 2472 58
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29812 58
BOC Sciences
+1-631-485-4226 inquiry@bocsci.com United States 19936 58
CONIER CHEM AND PHARMA LIMITED
sales@conier.com China 49979 58
Zhengzhou Alfa Chemical Co.,Ltd
+86-18530059196 sale04@alfachem.cn China 9612 58
SIMAGCHEM CORP
+86-5922680277 +86-13806087780 sale@simagchem.com China 17346 58
TargetMol Chemicals Inc.
+1-781-999-5354; +1-00000000000 marketing@targetmol.com United States 32468 58
Baoji Guokang Healthchem Co., Ltd.
+86-0917-3909592 +86-13892490616 gksales1@gk-bio.com China 9048 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 17705817739 info@dycnchem.com China 52704 58

View Lastest Price from Thiacloprid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Thiacloprid pictures 2026-07-14 Thiacloprid
111988-49-9
100kg 98 10000 Qingdao Trust Agri Chemical Co.,Ltd
Thiacloprid pictures 2026-07-14 Thiacloprid
111988-49-9
$37.00 99.96% 10g TargetMol Chemicals Inc.
Thiacloprid pictures 2025-05-26 Thiacloprid
111988-49-9
$6.00 1kg 0.99 1000 Hebei Fengjia New Material Co., Ltd
  • Thiacloprid pictures
  • Thiacloprid
    111988-49-9
  • $0.00
  • 98
  • Qingdao Trust Agri Chemical Co.,Ltd
  • Thiacloprid pictures
  • Thiacloprid
    111988-49-9
  • $37.00
  • 99.96%
  • TargetMol Chemicals Inc.
  • Thiacloprid pictures
  • Thiacloprid
    111988-49-9
  • $6.00
  • 0.99
  • Hebei Fengjia New Material Co., Ltd

Thiacloprid Spectrum

THIACLOPRID (3-((6-chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)-cyanamid 3-(2-chlor-5-pyridylmethyl)-2-cyaniminothiazolidin [3-(6-CHLORO-3-PYRIDINYLMETHYL)-2-THIAZOLIDINYLIDENE]CYANAMIDE ntn33894 Cyanamide, 3-(6-chloro-3-pyridinyl)methyl-2-thiazolidinylidene- thiacloprid (bsi, pa iso) yrc 2894 CHLORNICOTINYL Thiaclopyrid (Z)-thiacloprid Thiacloprid 100mg [111988-49-9] {[(2Z)-3-[(6-chloropyridin-3-yl)Methyl]-1,3-thiazolidin-2-ylidene]aMino}carbonitrile [N(Z)]-[3-[(6-Chloro-3-pyridinyl)Methyl]-2-thiazolidinylidene]cyanaMide [N(Z)]-N-[3-[(6-chloro-3-pyridinyl)Methyl]-2-thiazolidinylidene]cyanaMide Bariard Biscaya Calypso (pesticide) Calypso 70WG Calypso Ultra Bay YRC 2894 Calypso [[3-[(6-chloropyridin-3-yl)methyl]thiazolidin-2-ylidene]amino]formonitrile 3-(6-chloro-3-pyridinylmethyl)-1,3-thiazolidin-2-ylidence cyanamida Thiacloprid Solution, 1000ppm Thiacloprid@100 μg/mL in AcCN Thiacloprid@1000 μg/mL in Acetontrile Thiacloprid Reference Material Thiacloprid 24%SC Organic Insecticide 111988-49-9 Cyanamide, N-[3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]-, [N(Z)]- hiaclopri (Z)-N-[3-[(6-Chloropyridin-3-yl)methyl]thiazolidin-2-ylidene]cyanamide Fluoresceinamine mixed isomers Thiacloprid-d4 (thiazolidinylideme-d4) in acetonitrile Thiacloprid in Acetone C17451000 Thiacloprid L17451000ALThiacloprid 10μg/mLin Acetonitril Thiacloprid 10.0 μg/ml Acetonitrile Thiacloprid 100 μg/ml Acetone Thiacloprid in Acetonitrile (Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide (Thiacloprid) [3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene]cyanamide Thiacloprid 95% Thiacloprid in methanol California Pesticide Class 1 Mixture 100 μg/mL in Acetonitrile California Pesticides Class 1 Mixture 100 μg/mL in Acetonitrile Second Source Thiacloprid 10 μg/mL in Acetonitrile 25%Thiacloprid WDG 36%Thiacloprid WDG 48%Thiacloprid EV 111988-49-9 C10H9ClN4S
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