1,1-Dibromo-2-ethoxycyclopropane
- CAS No.
- 55249-20-2
- Chemical Name:
- 1,1-Dibromo-2-ethoxycyclopropane
- Synonyms
- 1,1-Dibromo-2-ethoxycyclopropane;Cyclopropane, 1,1-dibromo-2-ethoxy-
- CBNumber:
- CB02657992
- Molecular Formula:
- C5H8Br2O
- Molecular Weight:
- 243.92
- MDL Number:
- MOL File:
- 55249-20-2.mol
| Product description | Number | Pack Size | Price |
| 1,1-DIBROMO-2-ETHOXYCYCLOPROPANE 95.00% | HCH0122717 | 5MG | $503.8 |
1,1-Dibromo-2-ethoxycyclopropane Chemical Properties,Uses,Production
Uses
1,1-Dibromo-2-ethoxycyclopropane is used as a cyclopropyllithium reagent; cyclopropene precursor.
Synthesis
1,1-Dibromo-2-ethoxycyclopropane's synthesis: to a mixture of ethoxyethylene (1 equiv), n-Bu3N (0.024 equiv), and CHBr3 (1.5 equiv), is added aq. NaOH solution (50%, 6.25 equiv of NaOH) at rt. The reaction mixture is stirred for 48 h and poured into water and extracted with Et2O. The organic phase is washed with water, dried over anhydrous Na2SO4, filtered and concentrated using a rotary evaporator at 25 °C/60 mmHg. The residue is distilled at 25 °C/0.2 mmHg and further purified by silica gel column chromatography (petroleum ether/CH2Cl2 = 4:1) to give pure 1,1-dibromo-2-ethoxycyclopropane (1) (eq 1).1
Purification Methods
1,1-Dibromo-2-ethoxycyclopropane is purified by distillation followed by silica gel column chromatography.
1,1-Dibromo-2-ethoxycyclopropane Preparation Products And Raw materials
Raw materials
Preparation Products
1,1-Dibromo-2-ethoxycyclopropane Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Beijing Taiya Jie Technology Development Co., Ltd. | 021-33690831-8001 13552411790 | postmaster@tyjchem.cn | China | 1542 | 55 |
| Supplier | Advantage |
|---|---|
| Beijing Taiya Jie Technology Development Co., Ltd. | 55 |
