ChemicalBook >> CAS DataBase List >>BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
- CAS No.
- 13007-90-4
- Chemical Name:
- BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
- Synonyms
- phosphine)dicarbonyL;BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL;BIS(TRIPHENYLPHOSPHINE)NICKEL &;DICARBONYL-BIS(TRIPHENYLPHOSPHINE)NICKEL;BIS(TRIPHENYLPHOSPHINE)NICKEL DICARBONYL;NICKEL-BIS(TRIPHENYLPHOSPHINE) DICARBONYL;Bis-(triphenylphosphino)-nickel dicarbonyl;dicarbonylbis(triphenylphosphine)nickel(0);Bis(triphenylphosphine)nickel(0)dicarbonyl;Bis(triphenylphosphine)nickeldicarbonyl,98%
- CBNumber:
- CB0687047
- Molecular Formula:
- C38H30NiO2P2
- Molecular Weight:
- 639.28
- MDL Number:
- MFCD00009591
- MOL File:
- 13007-90-4.mol
- MSDS File:
- SDS
Last updated:2026-05-27 22:51:29
| Product description | Number | Pack Size | Price |
| Bis(triphenylphosphine)dicarbonylnickel | 213934 | 10g | $143 |
| Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 28-0100 | 5g | $46 |
| Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 28-0100 | 25g | $173 |
| Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 28-0100 | 100g | $513 |
| Bis(triphenylphosphine)nickel dicarbonyl, 98% | 28-0100 | 5g | $43 |
| Melting point | 206-209 °C (lit.) |
|---|---|
| storage temp. | 2-8°C |
| solubility | Soluble in HMPA, THF, diglyme, triglyme, benzene, acetonitrile, ethanol, and cyclohexane. |
| form | crystal |
| color | light yellow |
| Sensitive | air sensitive |
| Merck | 14,1304 |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
| InChI | 1S/2C18H15P.2CO.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2*1-2;/h2*1-15H;;; |
| InChIKey | SLFKPACCQUVAPG-UHFFFAOYSA-N |
| SMILES | [Ni].[C-]#[O+].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6 |
| CAS DataBase Reference | 13007-90-4 |
| REACH Annex XVII Substances List | Dicarbonylbis(triphenylphosphine)nickel (13007-90-4) |
| FDA UNII | 1QB0TWF7LY |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H317-H350 | |||||||||
| Precautionary statements | P201-P280-P302+P352-P308+P313 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | T | |||||||||
| Risk Statements | 45-42/43 | |||||||||
| Safety Statements | 53-22-36/37-45 | |||||||||
| RIDADR | 3281 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
|||||||||
| Hazard Classifications | Carc. 1B Skin Sens. 1 |
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| NFPA 704 |
|
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 213934 | Bis(triphenylphosphine)dicarbonylnickel | 13007-90-4 | 10g | $143 | 2026-04-30 | Buy |
| Strem Chemicals | 28-0100 | Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 13007-90-4 | 5g | $46 | 2026-04-30 | Buy |
| Strem Chemicals | 28-0100 | Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 13007-90-4 | 25g | $173 | 2026-04-30 | Buy |
| Strem Chemicals | 28-0100 | Bis(triphenylphosphine)nickel dicarbonyl, 98% 98% | 13007-90-4 | 100g | $513 | 2026-04-30 | Buy |
| Strem Chemicals | 28-0100 | Bis(triphenylphosphine)nickel dicarbonyl, 98% | 13007-90-4 | 5g | $43 | 2024-03-01 | Buy |
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Chemical Properties,Uses,Production
Chemical Properties
light yellow crystals or crystalline powder
Uses
Catalyst for:
- Cyclotrimerization reactions
- Cyclooligomerization reactions
Uses
Catalyst in polymerization of acetylene to benzene and styrene, trimerization of ethynyl Compounds, cyclization of butadiene.
reaction suitability
core: nickel
reagent type: catalyst
Synthesis
The preparative method of Bis(triphenylphosphine)dicarbonylnickel: by treating Tetracarbonylnickel with 2 equiv of Triphenylphosphine or by dissolving Dichlorobis(triphenylphosphine)nickel(II) in ethanol and treating it with CO in the presence of MeSNa. Purification: recrystallize from benzene.
Precautions
Catalytic activity decreases with storage. It is likely to be toxic, similar to nickel carbonyl, but its low volatility makes it easy to avoid ingestion. Use in a fume hood.
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Preparation Products And Raw materials
Raw materials
Preparation Products
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Suppliers
Global( 50)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Hunan russell chemicals technology co ltd | 731-88557738 +8613739093081 | sales01@russellchem.com | CHINA | 291 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 9996 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +86-18621343501; +undefined18621343501 | product@acmec-e.com | China | 33324 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40066 | 58 |
| XIAMEN AMITY INDUSTRY AND TRADE CO., LTD. | +8618950047208 | ellena@amitychem.com | China | 43414 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39927 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532; 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40228 | 62 |
13007-90-4(BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL)Related Search:
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Bis(triphenylphosphine)nickel(0)dicarbonyl
Bis(triphenylphosphine)nickeldicarbonyl,98%
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dicarbonylbis(triphenylphosphine)nickel(0)
Bis-(triphenylphosphino)-nickel dicarbonyl
Dicarbonylbis(triphenylphosphine)nickel(0), Nickel(0)bis(triphenylphosphine) dicarbonyl
Bis(triphenylphosphine)nickel(0)dicarbonyl, Dicarbonylbis(triphenylphosphine)nickel(0), Nickel(0)bis(triphenylphosphine) dicarbonyl
Bis(triphenylphosphine)dicarbonylnickel,98%
Nickel(0)bis(triphenylphosphine) dicarbonyl
phosphine)dicarbonyL
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL ISO 9001：2015 REACH
13007-90-4
C6H53P2NiCO2
C38H30NiO2P2
Catalysis and Inorganic Chemistry
metal carbonyl complexes
