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ChemicalBook >> CAS DataBase List >>3-(Dimethylamino)benzoic acid

3-(Dimethylamino)benzoic acid

CAS No.
99-64-9
Chemical Name:
3-(Dimethylamino)benzoic acid
Synonyms
3-(Dimethylamino)ben;3-Dimethylaminobenzoic;M-dimetylaminobenzoic acid;DiMethyl aMinobenzoic acid;3-DIMETHYLAMINOBENZOIC ACID;3-Diaminomethylbenzoic acid;M-DIMETHYLAMINOBENZOIC ACID;TwoMethyl aMinobenzoic acid;3-DIMETHYLAMINO-BENZOESAEURE;3-(N,N-Dimethylamino)benzoic
CBNumber:
CB0739540
Molecular Formula:
C9H11NO2
Molecular Weight:
165.19
MDL Number:
MFCD00002497
MOL File:
99-64-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-27 22:51:59
Product description Number Pack Size Price
3-(Dimethylamino)benzoic acid ≥97% (HPLC) D0787 10g $114
3-(Dimethylamino)benzoic acid ≥97% (HPLC) D0787 25g $251
3-Dimethylaminobenzoic acid for synthesis 8.14112 25G $70.8
3-Dimethylaminobenzoic Acid >98.0%(GC)(T) D0646 25g $55
3-Dimethylaminobenzoic Acid >98.0%(GC)(T) D0646 500g $444
More product size

3-(Dimethylamino)benzoic acid Properties

Melting point 148-150 °C(lit.)
Boiling point 293.03°C (rough estimate)
Density 1.1603 (rough estimate)
refractive index 1.5200 (estimate)
storage temp. Store below +30°C.
solubility methanol: 50mg/mL, clear to very slightly hazy, yellow to brown
form Crystalline Powder
pka 3.36±0.10(Predicted)
color Light yellow to yellow-beige
Water Solubility Soluble in methanol (50 mg/ml). Insoluble in water.
BRN 2208586
InChI InChI=1S/C9H11NO2/c1-10(2)8-5-3-4-7(6-8)9(11)12/h3-6H,1-2H3,(H,11,12)
InChIKey NEGFNJRAUMCZMY-UHFFFAOYSA-N
SMILES C(O)(=O)C1=CC=CC(N(C)C)=C1
CAS DataBase Reference 99-64-9(CAS DataBase Reference)
FDA UNII M47AQ3FS7E
EPA Substance Registry System Benzoic acid, 3-(dimethylamino)- (99-64-9)
UNSPSC Code 12352204
NACRES NA.83

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-24/25
WGK Germany  3
TSCA  TSCA listed
HS Code  29224995
Storage Class 11 - Combustible Solids
NFPA 704
0
1 0

3-(Dimethylamino)benzoic acid price More Price(57)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich D0787 3-(Dimethylamino)benzoic acid ≥97% (HPLC) 99-64-9 10g $114 2026-04-30 Buy
Sigma-Aldrich D0787 3-(Dimethylamino)benzoic acid ≥97% (HPLC) 99-64-9 25g $251 2026-04-30 Buy
Sigma-Aldrich 8.14112 3-Dimethylaminobenzoic acid for synthesis 99-64-9 25G $70.8 2025-07-31 Buy
TCI Chemical D0646 3-Dimethylaminobenzoic Acid >98.0%(GC)(T) 99-64-9 25g $55 2026-04-30 Buy
TCI Chemical D0646 3-Dimethylaminobenzoic Acid >98.0%(GC)(T) 99-64-9 500g $444 2026-04-30 Buy
Product number Packaging Price Buy
D0787 10g $114 Buy
D0787 25g $251 Buy
8.14112 25G $70.8 Buy
D0646 25g $55 Buy
D0646 500g $444 Buy

3-(Dimethylamino)benzoic acid Chemical Properties,Uses,Production

Chemical Properties

Light yellow to yellow-beige crystalline powder

Uses

3-(Dimethylamino)benzoic acid has been used to analyse glucose content from the extraction of starch and soluble sugars.

Uses

3-Dimethylaminobenzoic acid is used as a benzoic acid derivative.

Biochem/physiol Actions

3-(Dimethylamino)benzoic acid can be used to quantity the activity of peroxidase and manganese peroxidase.

Synthesis

Formaldehyde

50-00-0

3-Nitrobenzoic acid

121-92-6

3-(Dimethylamino)benzoic acid

99-64-9

In a 250 mL three-neck flask, 95 mL of methanol and 3 mL of tetrahydrofuran were added, followed by 16.7 g of m-nitrobenzoic acid and 0.2 g of 5% palladium carbon catalyst. A constant pressure dropping funnel was installed and 15.2 mL of 37% formaldehyde aqueous solution was added to it. The air in the reaction system was replaced with hydrogen via an air pump. The reaction system was warmed up to 64 °C and the reaction was stirred at this temperature until hydrogen uptake stopped. Subsequently, the hydrogenation reaction was continued by slowly adding the formaldehyde solution through a dropping funnel until the hydrogen uptake stopped again. After stopping stirring, the reaction mixture was filtered to recover the catalyst. The filtrate was concentrated to precipitate the product m-dimethylaminobenzoic acid. The precipitate was collected by filtration, washed with a small amount of water and dried at 100 °C to give 15.3 g of m-dimethylaminobenzoic acid in 93% yield. The recovered catalyst was washed with reaction solvent and could be reused in subsequent reactions.

References

[1] Patent: CN107056633, 2017, A. Location in patent: Paragraph 0013; 0014; 0015; 0016
[2] Journal of the Chemical Society, 1950, p. 1342,1345

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View Lastest Price from 3-(Dimethylamino)benzoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
m-(Dimethylamino)benzoic acid pictures 2026-06-05 m-(Dimethylamino)benzoic acid
99-64-9
$89.00 1kg 0.98 100kg Shanghai UCHEM Inc.
3-(Dimethylamino)benzoic acid pictures 2026-05-28 3-(Dimethylamino)benzoic acid
99-64-9
$10.00-30.00 10kg 99% 100000kg Hebei Chuanghai Biotechnology Co,.LTD
3-Dimethylaminobenzoic acid pictures 2026-05-21 3-Dimethylaminobenzoic acid
99-64-9
$5.00 1KG 99% 1000mt/year Jinan Finer Chemical Co., Ltd
M-(N,N-DIMETHYLAMINO) BENZOIC ACID 3-DIMETHYLAMINOBENZOIC ACID, CRYSTALLIZE D 3-DIMETHYLAMINO-BENZOESAEURE 3-(DIMETHYLAMINO)BENZOIC ACID 97%. 3-Dimethylaminobenzoic META DIMETHYLAMINOBENZOIC ACID M-dimetylaminobenzoic acid 3-(N,N-Dimethylamino)benzoic 3-Dimethylaminobenzoic acid,99% 3-Diaminomethylbenzoic acid 3-DIMETHYLAMINOBENZOIC ACID M-DIMETHYLAMINOBENZOIC ACID 3-(Dimethylamino)ben 3-DiMethylaMinobenzoic acid, 99% 25GR 3-DIMETHYLAMINOBENZOIC ACID FOR SYNTHESI TwoMethyl aMinobenzoic acid 3-(DiMethylaMino)benzoic acid, 98%+ DiMethyl aMinobenzoic acid 3-(dimethylamino)-benzoicaci Benzoicacid,3-(dimethylamino)- 3-Dimethylaminobenzoic Acid > 3-(Dimethylamino)benzoic acid USP/EP/BP 99-64-9 Unnatural Amino Acid Derivatives Aromatic Amino Acids Specialty Synthesis Peptide Synthesis Industrial/Fine Chemicals Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Organic acids Aromatic Amino Acids Peptide Synthesis Unnatural Amino Acid Derivatives Chromogenic Detection Enzyme Substrates
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