3-(3-AMINOPHENOXY)ANILINE
- CAS No.
- 15268-07-2
- Chemical Name:
- 3-(3-AMINOPHENOXY)ANILINE
- Synonyms
- 3,3'-Oxydianiline;3,3-Oxybisbenzolamine;3,3'-oxydibenzeneamine;Bis(3-aminophenyl) Ether;BenzenaMine, 3,3'-oxybis-;3-(3-AMINOPHENOXY)ANILINE;3,3'-Diaminodiphenyl ether;3,3- DIAMINODIPHENYL ETHER(33ODA)
- CBNumber:
- CB11010207
- Molecular Formula:
- C12H12N2O
- Molecular Weight:
- 200.24
- MDL Number:
- MFCD09834067
- MOL File:
- 15268-07-2.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 3,3'-Oxydianiline min. 98.0 % | O0568 | 1G | $275 |
| 3,3'-Diamino diphenyl ether Asreported | 273433 | 50mg | $489 |
| 3,3'-Diamino diphenyl ether Asreported | 273433 | 100mg | $704 |
| 3,3'-Diamino diphenyl ether Asreported | 273433 | 250mg | $1005 |
| 3,3'-Diamino diphenyl ether Asreported | 273433 | 500mg | $1444 |
| Melting point | 37 °C(Solv: benzene (71-43-2); ligroine (8032-32-4)) |
|---|---|
| Boiling point | 315 °C |
| Density | 1.216±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Acetonitrile (Slightly), Chloroform(Slightly) |
| form | Solid |
| pka | 4.37±0.10(Predicted) |
| color | Light Brown |
| InChI | InChI=1S/C12H12N2O/c13-9-3-1-5-11(7-9)15-12-6-2-4-10(14)8-12/h1-8H,13-14H2 |
| InChIKey | LXJLFVRAWOOQDR-UHFFFAOYSA-N |
| SMILES | O(C1C=CC=C(N)C=1)C1C=CC=C(N)C=1 |
| EWG's Food Scores | 1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H319-H315 |
| Precautionary statements | P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P |
3-(3-AMINOPHENOXY)ANILINE price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | O0568 | 3,3'-Oxydianiline min. 98.0 % | 15268-07-2 | 1G | $275 | 2026-04-30 | Buy |
| Usbiological | 273433 | 3,3'-Diamino diphenyl ether Asreported | 15268-07-2 | 50mg | $489 | 2026-06-03 | Buy |
| Usbiological | 273433 | 3,3'-Diamino diphenyl ether Asreported | 15268-07-2 | 100mg | $704 | 2026-06-03 | Buy |
| Usbiological | 273433 | 3,3'-Diamino diphenyl ether Asreported | 15268-07-2 | 250mg | $1005 | 2026-06-03 | Buy |
| Usbiological | 273433 | 3,3'-Diamino diphenyl ether Asreported | 15268-07-2 | 500mg | $1444 | 2026-06-03 | Buy |
3-(3-AMINOPHENOXY)ANILINE Chemical Properties,Uses,Production
Uses
3,3''-Oxydianiline was used as a reactant in the synthesis of a deep blue electrophosphorescent Pt(II) emitter.
Synthesis
626-01-7
591-27-5
15268-07-2
The general procedure for the synthesis of 3,3'-oxydiphenylamine from 3-iodoaniline and 3-aminophenol was as follows: 3-aminophenol (6.0 g, 54.8 mmol), 3-iodoaniline (10.0 g, 45.7 mmol), pyridine carboxylic acid (0.56 g, 4.6 mmol), cuprous iodide (I) and potassium phosphate (19.4 g, 91 mmol). DMSO (100 mL) was added as solvent and the reaction mixture was degassed by blowing in nitrogen for 1 hour. Subsequently, the reaction flask was placed in a preheated 80 °C oil bath and the reaction was stirred for 15 hours. After completion of the reaction, the mixture was cooled to room temperature. The reaction mixture was poured into 150 mL of water and extracted with ethyl acetate (3 x 50 mL). The organic phases were combined and washed sequentially with 50 mL of water and 50 mL of brine, dried and the solvent evaporated. The crude product was purified by silica gel column chromatography, eluting first with 80/20 (v/v) hexane/ethyl acetate solvent mixture and then with 50/50 (v/v) hexane/ethyl acetate solvent mixture to give 7.2 g (79% yield) of 3,3'-oxydiphenylamine as a white solid. The structure of the product was confirmed by GC/MS and NMR.
References
[1] Angewandte Chemie - International Edition, 2013, vol. 52, # 2, p. 650 - 654
[2] Angew. Chem., 2013, vol. 125, # 2, p. 678 - 682,5
[3] Patent: US9461254, 2016, B2. Location in patent: Page/Page column 195-196
[4] Journal of the American Chemical Society, 2009, vol. 131, # 47, p. 17423 - 17429
3-(3-AMINOPHENOXY)ANILINE Preparation Products And Raw materials
Raw materials
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Preparation Products
3-(3-AMINOPHENOXY)ANILINE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Synchem Pharma Co., Ltd | +86-61984905-1 +86-18016477331 | synchempharma@aliyun.com | China | 92 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30224 | 58 |
| Finetech Industry Limited | +86-27-8746-5837 +8619945049750 | info@finetechnology-ind.com | China | 9539 | 58 |
| Henan Alfa Chemical Co., Ltd | +8615838112936 | sale03@alfachem.cn | China | 9796 | 58 |
| Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49734 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +86-18621343501; +undefined18621343501 | product@acmec-e.com | China | 33324 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40066 | 58 |
| Guangzhou CATO Research Chemicals Inc. | +86-020-81960175-617 +8615602392859 | Intermediate@cato-chem.com | China | 3858 | 58 |
| NANJING YINGWEN BIOTECHNOLOGY CO LTD | +8613382787392 | sales@aeechem.com | China | 10002 | 58 |
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