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ChemicalBook >> CAS DataBase List >>1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo-

1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo-

CAS No.
356058-42-9
Chemical Name:
1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo-
Synonyms
1-(CarboxyMethyl)-2-(4-fluorobenzylthio)-5,6-triMethylenepyriMidin-4-one;2-[(4-Fluorobenzyl)thio]-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidine-1-acetic Acid;2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid;1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo-;2-[2-[(4-fluorophenyl)methylsulfanyl]-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-1-yl]acetic acid
CBNumber:
CB12563364
Molecular Formula:
C16H15FN2O3S
Molecular Weight:
334.37
MDL Number:
MFCD21337366
MOL File:
356058-42-9.mol
MSDS File:
SDS
Last updated:2026-05-27 23:22:38
Product description Number Pack Size Price
2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 304875 250.00mg $38
2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 304875 1.00g $104
2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 304875 5.00g $324
2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 97% F23259 100mg $80
2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 97% F23259 250mg $120

1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo- Properties

storage temp. Keep in dark place,Sealed in dry,Store in freezer, under -20°C

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo- price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Matrix Scientific 304875 2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 356058-42-9 250.00mg $38 2026-05-19 Buy
Matrix Scientific 304875 2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 356058-42-9 1.00g $104 2026-05-19 Buy
Matrix Scientific 304875 2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 356058-42-9 5.00g $324 2026-05-19 Buy
Synthonix F23259 2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 97% 356058-42-9 100mg $80 2026-05-06 Buy
Synthonix F23259 2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 97% 356058-42-9 250mg $120 2026-05-06 Buy
Product number Packaging Price Buy
304875 250.00mg $38 Buy
304875 1.00g $104 Buy
304875 5.00g $324 Buy
F23259 100mg $80 Buy
F23259 250mg $120 Buy

1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo- Chemical Properties,Uses,Production

Synthesis

2,3,4,5,6,7-hexahydro-4-oxo-2-thioxo-1H-CyclopentapyriMidine-1-acetic acid

1349902-20-0

4-Fluorobenzyl chloride

352-11-4

1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo-

356058-42-9

Preparation of 2-(2-((4-fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid from 2,3,4,5,6,7-hexahydro-4-oxo-2-thioxo-1H-cyclopenta[d]pyrimidin-1-yl) as raw material and 4-fluorobenzylchloride (13.4 g, 1.05 eq) The general procedure was as follows: 2,3,4,5,6,7-hexahydro-4-oxo-2-thio-1H-cyclopentadienopyrimidin-1-yl-acetic acid was slurried in a mixture of water (112 mL) and isopropanol (20 mL). A 50.9% aqueous NaOH solution (13.82 g, 1.99 eq.) was added, followed by washing with water (10 mL) to obtain a solution. Next, Na2CO3 (1.50 g, 0.16 eq.) was added and the solution was heated to 40 ± 3°C. 4-fluorobenzyl chloride was then added and subsequently washed with isopropanol (12 mL). The reaction mixture was stirred at 40 ± 3°C until the reaction was complete (about 2.5 h). After cooling to 20 ± 3°C, formic acid (2.4 g, 0.6 eq.) was added and the product was crystallized within 30 min. a second batch of formic acid (6.9 g, 1.7 eq.) was added within 1 h. The slurry was stirred at 20 ± 3°C for at least 1 h. The reaction mixture was then stirred for at least 1 h. The product was then filtered to separate the product. The slurry was filtered to separate the product, washed twice successively with a mixture of water (32 mL) and isopropanol (8 mL), then with isopropanol (40 mL), and finally dried in vacuo at 50°C to give the title compound as an off-white solid (28.6 g, 97% yield).1H NMR (d6-DMSO) δ: 1.95 (2H, m), 2.57 (2H, t) , 2.85 (2H, t), 4.4 (2H, s), 4.7 (2H, s), 7.15 (2H, dd), 7.45 (2H, dd), ~13.6 (1H, vbrs).

References

[1] Patent: WO2011/146494, 2011, A1. Location in patent: Page/Page column 11
[2] Bioorganic and Medicinal Chemistry Letters, 2013, vol. 23, # 3, p. 839 - 843
[3] Bioorganic and Medicinal Chemistry Letters, 2018, vol. 28, # 4, p. 787 - 792

1349902-20-0
352-11-4
356058-42-9
Synthesis of 1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo- from 2,3,4,5,6,7-hexahydro-4-oxo-2-thioxo-1H-CyclopentapyriMidine-1-acetic acid and 4-Fluorobenzyl chloride

1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo- Preparation Products And Raw materials

1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo- Suppliers

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356058-42-9(1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo-)Related Search:

1H-CyclopentapyriMidine-1-acetic acid, 2-[[(4-fluorophenyl)Methyl]thio]-4,5,6,7-tetrahydro-4-oxo- 1-(CarboxyMethyl)-2-(4-fluorobenzylthio)-5,6-triMethylenepyriMidin-4-one 2-(2-((4-Fluorobenzyl)thio)-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidin-1-yl)acetic acid 2-[2-[(4-fluorophenyl)methylsulfanyl]-4-oxo-6,7-dihydro-5H-cyclopenta[d]pyrimidin-1-yl]acetic acid 2-[(4-Fluorobenzyl)thio]-4-oxo-4,5,6,7-tetrahydro-1H-cyclopenta[d]pyrimidine-1-acetic Acid 356058-42-9
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