ChemicalBook >> CAS DataBase List >>(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
![(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Structure](CAS/20211123/GIF/959395-10-9.gif)
- CAS No.
- 959395-10-9
- Chemical Name:
- (2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
- Synonyms
- Fe(R,R-PDP);Fe(S,S-PDP);White-Chen catalyst;[Fe(S,S-PDP)(CH3CN)2](SbF6)2;[Fe(R,R-PDP)(CH3CN)2](SbF6)2;(2S,2’S)-[N,N’-Bis(2-pyridylmethyl)]-2,2’-bipyrrolidinebis(acetonitrile)iron(II) Hexafluoroantimonate;(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate;(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate;acetonitrile:hexafluoroantimony(1-):iron(2+):2-[[(2R)-2-[(2R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl]methyl]pyridine;(2S,2′S-(?)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
- CBNumber:
- CB22524290
- Molecular Formula:
- C24H32F6FeN6Sb+
- Molecular Weight:
- 696.16
- MDL Number:
- MFCD16038114
- MOL File:
- 959395-10-9.mol
- MSDS File:
- SDS
Last updated:2026-05-28 00:01:38
| Product description | Number | Pack Size | Price |
| (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst | 26-0060 | 100mg | $89 |
| (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst | 26-0060 | 500mg | $393 |
| (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst | 26-0060 | 100mg | $86 |
| (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst | 26-0060 | 500mg | $383 |
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Properties
| Melting point | 215-226 °C |
|---|---|
| storage temp. | 2-8°C, protect from light, stored under nitrogen |
| form | Powder |
| color | purple |
| optical activity | [α]20/D 30.0 to 20.0°, c = 0.2 in acetonitrile |
| Sensitive | air sensitive |
| InChIKey | XUNWHBGEOCZDBX-QSKJABRXSA-B |
| SMILES | [Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4 |
| CAS DataBase Reference | 959395-10-9 |
| UNSPSC Code | 12352300 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| target organs | Respiratory system |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26 |
| WGK Germany | 3 |
| Storage Class | 11 - Combustible Solids |
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Strem Chemicals | 26-0060 | (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst | 959395-10-9 | 100mg | $89 | 2026-04-30 | Buy |
| Strem Chemicals | 26-0060 | (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst | 959395-10-9 | 500mg | $393 | 2026-04-30 | Buy |
| Strem Chemicals | 26-0060 | (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst | 959395-10-9 | 100mg | $86 | 2024-03-01 | Buy |
| Strem Chemicals | 26-0060 | (2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst | 959395-10-9 | 500mg | $383 | 2024-03-01 | Buy |
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Chemical Properties,Uses,Production
Reaction
Metal complex used in the iron-catalyzed, selective oxidation of C-H bonds.
Uses
Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.
Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation
Catalyst for:
- Oxidative radical reactions
- Selective oxidation of alkyl carbon-hydrogen bonds
- Methylene group oxidation
reaction suitability
core: iron
reagent type: catalyst
reaction type: C-H Activation
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Preparation Products And Raw materials
Raw materials
Preparation Products
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Suppliers
Global( 14)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Aladdin Scientific | tp@aladdinsci.com | United States | 52923 | 58 | |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42934 | 64 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51395 | 80 |
| Alfa Chemistry | 1-516-6625404 | support@alfa-chemistry.com | United States | 9171 | 60 |
| Aikon International Limited | 025-58859352 15955137747 | sales01@aikonchem.com | China | 16027 | 58 |
| Shenzhen Polymeri Biochemical Technology Co., Ltd. | +86-400-002-6226 +86-13028896684; | sales@rrkchem.com | China | 57422 | 58 |
| Yangzhou modier Electronic Materials Co., Ltd | 13918702962 13761402923 | market@modeltemol.com | China | 7761 | 58 |
| Energy Chemical | 021-58432009 400-005-6266 | marketing@energy-chemical.com | China | 44918 | 58 |
| Shanghai Yingxin laboratory equipment Co., Ltd | 021-021-59178156 15300768757 | 359382369@qq.com | China | 10674 | 58 |
(2S,2'S)-(-)-[N,N'-Bis(2-pyridylmethyl]-2,2'-bipyrrolidinebis(acetonitrile) iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst
[Fe(S,S-PDP)(CH3CN)2](SbF6)2
Fe(S,S-PDP)
(2S,2′S-()-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
[Fe(R,R-PDP)(CH3CN)2](SbF6)2
Fe(R,R-PDP)
Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate
White-Chen catalyst
acetonitrile:hexafluoroantimony(1-):iron(2+):2-[[(2R)-2-[(2R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl]methyl]pyridine
(2S,2''S)-(-)-[N,N''-Bis(2-pyridylmethyl]-2,2''-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Fe(S,S-PDP) White-Chen Catalyst
(2S,2’S)-[N,N’-Bis(2-pyridylmethyl)]-2,2’-bipyrrolidinebis(acetonitrile)iron(II) Hexafluoroantimonate
(2S,2′S-(?)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
959395-10-9
2C2H3NC20H26N42F6SbFe
