2-hydroxy-5-(methylthio)benzaldehyde
- CAS No.
- 67868-84-2
- Chemical Name:
- 2-hydroxy-5-(methylthio)benzaldehyde
- Synonyms
- 2-hydroxy-5-(methylthio)benzaldehyde;Benzaldehyde, 2-hydroxy-5-(methylthio)-;2-HYDROXY-5-(METHYLSULFANYL)BENZALDEHYDE
- CBNumber:
- CB23041730
- Molecular Formula:
- C8H8O2S
- Molecular Weight:
- 168.21
- MDL Number:
- MFCD03309091
- MOL File:
- 67868-84-2.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-Hydroxy-5-(methylthio)benzaldehyde 97% | AS110906 | 1g | $59 |
| 2-Hydroxy-5-(methylthio)benzaldehyde 97% | AS110906 | 5g | $228 |
| 2-Hydroxy-5-methylsulfanylbenzaldehyde | 181646 | 5.00g | $1568 |
| 2-Hydroxy-5-(methylthio)benzaldehyde 97% | H49089 | 100mg | $36 |
| 2-Hydroxy-5-(methylthio)benzaldehyde 97% | H49089 | 250mg | $40 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
2-hydroxy-5-(methylthio)benzaldehyde price More Price(26)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Activate Scientific | AS110906 | 2-Hydroxy-5-(methylthio)benzaldehyde 97% | 67868-84-2 | 1g | $59 | 2026-06-04 | Buy |
| Activate Scientific | AS110906 | 2-Hydroxy-5-(methylthio)benzaldehyde 97% | 67868-84-2 | 5g | $228 | 2026-06-04 | Buy |
| Matrix Scientific | 181646 | 2-Hydroxy-5-methylsulfanylbenzaldehyde | 67868-84-2 | 5.00g | $1568 | 2026-05-18 | Buy |
| Synthonix | H49089 | 2-Hydroxy-5-(methylthio)benzaldehyde 97% | 67868-84-2 | 100mg | $36 | 2026-05-06 | Buy |
| Synthonix | H49089 | 2-Hydroxy-5-(methylthio)benzaldehyde 97% | 67868-84-2 | 250mg | $40 | 2026-05-06 | Buy |
2-hydroxy-5-(methylthio)benzaldehyde Chemical Properties,Uses,Production
Synthesis
50-00-0
1073-72-9
67868-84-2
To a suspension of 4-(methylthio)phenol (50 g, 357 mmol), paraformaldehyde (72.3 g, 2407 mmol) and anhydrous magnesium chloride (50.9 g, 535 mmol) in acetonitrile (500 mL) was added triethylamine (186 mL, 1337 mmol). The reaction mixture was stirred at room temperature and then warmed to 60 °C and stirred continuously for 5 hours. Upon completion of the reaction, the mixture was cooled to 0 °C and 1N hydrochloric acid was slowly added until the two phases separated (~1.5 L). Methyl tert-butyl ether (MTBE, 700 mL) was then added and the organic layer was separated. The organic layer was washed with saturated brine, dried over anhydrous sodium sulfate, filtered and concentrated under reduced pressure. The crude product was purified by fast column chromatography on silica gel with the eluent being a 1:1 hexane/dichloromethane solvent mixture to afford 2-hydroxy-5-(methylthio)benzaldehyde (50.5 g, 300 mmol, 84% yield) as a semi-solid.
References
[1] Patent: WO2015/35223, 2015, A1. Location in patent: Paragraph 0821
[2] Patent: WO2016/57242, 2016, A1. Location in patent: Paragraph 0197
[3] Journal of the American Chemical Society, 2009, vol. 131, # 40, p. 14190 - 14191
[4] Angewandte Chemie - International Edition, 2011, vol. 50, # 21, p. 4983 - 4987
[5] European Journal of Organic Chemistry, 2014, vol. 2014, # 27, p. 6077 - 6083
2-hydroxy-5-(methylthio)benzaldehyde Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
2-hydroxy-5-(methylthio)benzaldehyde Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5906 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +86-13203830695 | laboratory@coreychem.com | China | 30224 | 58 |
| Labnetwork lnc. | +86-27-50766799 +86-18062016861 | contact@labnetwork.com | China | 19987 | 58 |
| Young Lively PharminBlock Co.,Ltd | 18600731423 | jason_gao@yl-pharminblock.com | China | 1944 | 58 |
| Shanghai Hanhong Scientific Co., Ltd. | +undefined17612118332 | Lucky@hanhonggroup.com | China | 5844 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131956 | 58 |
| Bide Pharmatech Ltd. | 400-164-7117 18317119277 | product02@bidepharm.com | China | 40000 | 60 |
| Cool Pharm, Ltd | 021-60455363 18019463053 | sales@coolpharm.com | China | 8455 | 58 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 13636370518 | shyysw007@163.com | China | 89686 | 60 |
View Lastest Price from 2-hydroxy-5-(methylthio)benzaldehyde manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-01-15 | 2-hydroxy-5-methylsulfanylbenzaldehyde
67868-84-2
|
1KG | 97.3% | 100 tons | Honest Joy Holdings Limited
|
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- 2-hydroxy-5-methylsulfanylbenzaldehyde
67868-84-2
- $0.00
- 97.3%
- Honest Joy Holdings Limited
