METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97
- CAS No.
- 913836-22-3
- Chemical Name:
- METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97
- Synonyms
- 5-Bromo-4-(methoxycarbonyl)-1,3-thiazole;METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97;Methyl 5-bromo-1,3-thiazole-4-carboxylate 97%;4-Thiazolecarboxylic acid, 5-bromo-, methyl ester
- CBNumber:
- CB2501309
- Molecular Formula:
- C5H4BrNO2S
- Molecular Weight:
- 222.06
- MDL Number:
- MFCD08275713
- MOL File:
- 913836-22-3.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Methyl 5-bromothiazole-4-carboxylate | SYX00326 | 1g | $114 |
| METHYL5-BROMO-4-THIAZOLECARBOXYLATE 97% | CL2513 | 1G | $30 |
| METHYL5-BROMO-4-THIAZOLECARBOXYLATE 97% | CL2513 | 5G | $95 |
| METHYL5-BROMO-4-THIAZOLECARBOXYLATE 97% | CL2513 | 25G | $470 |
| Methyl 5-bromothiazole-4-carboxylate 98% | AS50522 | 1g | $27 |
| More product size | |||
| Melting point | 98-101 |
|---|---|
| Boiling point | 276℃ |
| Density | 1.759 |
| Flash point | 121℃ |
| storage temp. | Inert atmosphere,2-8°C |
| form | solid |
| pka | -1.48±0.10(Predicted) |
| color | Light yellow to orange |
| InChI | InChI=1S/C5H4BrNO2S/c1-9-5(8)3-4(6)10-2-7-3/h2H,1H3 |
| InChIKey | AUJMFWXVFMHABB-UHFFFAOYSA-N |
| SMILES | S1C(Br)=C(C(OC)=O)N=C1 |
| UNSPSC Code | 12352200 |
| NACRES | NA.21 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P271-P280 |
| Hazard Codes | Xi |
| WGK Germany | WGK 3 |
| Hazard Note | Irritant/Keep Cold |
| HS Code | 2934100090 |
| Storage Class | 11 - Combustible Solids |
METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 price More Price(49)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | SYX00326 | Methyl 5-bromothiazole-4-carboxylate | 913836-22-3 | 1g | $114 | 2026-04-30 | Buy |
| AstaTech | CL2513 | METHYL5-BROMO-4-THIAZOLECARBOXYLATE 97% | 913836-22-3 | 1G | $30 | 2026-04-30 | Buy |
| AstaTech | CL2513 | METHYL5-BROMO-4-THIAZOLECARBOXYLATE 97% | 913836-22-3 | 5G | $95 | 2026-04-30 | Buy |
| AstaTech | CL2513 | METHYL5-BROMO-4-THIAZOLECARBOXYLATE 97% | 913836-22-3 | 25G | $470 | 2026-04-30 | Buy |
| Activate Scientific | AS50522 | Methyl 5-bromothiazole-4-carboxylate 98% | 913836-22-3 | 1g | $27 | 2026-06-04 | Buy |
METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 Chemical Properties,Uses,Production
Synthesis
850429-60-6
913836-22-3
General procedure for the synthesis of methyl 5-bromo-4-thiazolecarboxylate from methyl 2-amino-5-bromothiazole-4-carboxylate: Methyl 2-amino-5-bromothiazole-4-carboxylate (1.0 equiv, 100 mg, 0.42 mmol) was dissolved in anhydrous DMF (0.8 mL). The reaction mixture was heated to 80 °C under nitrogen protection. A solution of tert-butyl nitrite (1.2 eq, 60 μL, 0.50 mmol) in DMF (0.8 mL) was slowly added dropwise to the hot solution. After several minutes of reaction, no gas escaped indicating completion of the reaction. The reaction mixture was cooled to room temperature and then sampled directly onto a preloaded silica gel column. Rapid column chromatographic separation was carried out sequentially using hexane and ethyl acetate/hexane (2:8, v/v) as eluents to afford methyl 5-bromothiazole-4-carboxylate as a yellow solid (49 mg, 53% yield). The product was analyzed by LCMS (ES) showing a purity of 95%, m/z 222 [M]+, 224 [M+2]+.
References
[1] Patent: WO2008/28168, 2008, A2. Location in patent: Page/Page column 157
[2] Patent: US2009/93465, 2009, A1. Location in patent: Page/Page column 49
[3] Patent: US2009/239859, 2009, A1. Location in patent: Page/Page column 138
METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32998 | 60 |
| Accela ChemBio Inc. | +1-858-6993322 +86-18019713315 | info@accelachem.com | United States | 21189 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63645 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10817 | 58 |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49906 | 58 | |
| career henan chemical co | +86-0371-86658258 | factory@coreychem.com | China | 29780 | 58 |
| Finetech Industry Limited | +86-27-8746-5837 +86-18627785180 | info@finetechnology-ind.com | China | 9539 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 17705817739 | info@dycnchem.com | China | 52693 | 58 |
| CD Chemical Group Limited | +86-13651442114 | info@codchem.com | China | 17253 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418684 +86-18949823763 | sales@tnjchem.com | China | 25333 | 58 |
View Lastest Price from METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-06-30 | METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97
913836-22-3
|
1kg | 98% | 1000kg | Shaanxi Dideu New Materials Co. Ltd | ||
 |
2019-12-26 | METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97
913836-22-3
|
$1.00 | 1KG | 99% | 500kg | Career Henan Chemical Co |
-
- METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97
913836-22-3
- $0.00
- 98%
- Shaanxi Dideu New Materials Co. Ltd
-
- METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97
913836-22-3
- $1.00
- 99%
- Career Henan Chemical Co
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