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ChemicalBook >> CAS DataBase List >>2-AMINO-3-CYANOTOLUENE

2-AMINO-3-CYANOTOLUENE

CAS No.
69797-49-5
Chemical Name:
2-AMINO-3-CYANOTOLUENE
Synonyms
2-AMINO-3-CYANOTOLUENE;2-Cyano-6-methylaniline;3-methyl-2-Amino-benzonitrile;2-AMINO-3-METHYL-BENZONITRILE;Benzonitrile, 2-aMino-3-Methyl-;2-amino-3-methylbenzenemethylnitrile
CBNumber:
CB32452268
Molecular Formula:
C8H8N2
Molecular Weight:
132.16
MDL Number:
MFCD09880087
MOL File:
69797-49-5.mol
MSDS File:
SDS
Last updated:2026-05-28 01:04:41
Product description Number Pack Size Price
2-Amino-3-methylbenzonitrile >98% OR906433 250mg $21
2-Amino-3-methylbenzonitrile >98% OR906433 1g $24
2-Amino-3-methylbenzonitrile >98% OR906433 5g $77
2-Amino-3-methylbenzonitrile >98% OR906433 25g $232
2-Amino-3-methylbenzonitrile >98% OR906433 100g $901
More product size

2-AMINO-3-CYANOTOLUENE Properties

storage temp. Keep in dark place,Inert atmosphere,Room temperature
Appearance Light yellow to brown Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
HS Code  2926907090

2-AMINO-3-CYANOTOLUENE price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 250mg $21 2026-06-04 Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 1g $24 2026-06-04 Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 5g $77 2026-06-04 Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 25g $232 2026-06-04 Buy
Apolloscientific OR906433 2-Amino-3-methylbenzonitrile >98% 69797-49-5 100g $901 2026-06-04 Buy
Product number Packaging Price Buy
OR906433 250mg $21 Buy
OR906433 1g $24 Buy
OR906433 5g $77 Buy
OR906433 25g $232 Buy
OR906433 100g $901 Buy

2-AMINO-3-CYANOTOLUENE Chemical Properties,Uses,Production

Application

3-Amino-2-methylbenzonitrile is an aniline heterocyclic compound mainly used in laboratory organic synthesis processes.

Synthesis

2-BROMO-6-METHYLANILINE

53848-17-2

Copper(I) Cyanide

544-92-3

2-AMINO-3-CYANOTOLUENE

69797-49-5

The general procedure for the synthesis of 2-amino-3-methylbenzonitrile from 2-bromo-6-methylaniline and cuprous cyanide was as follows: cuprous cyanide (CuCN, 197 mg, 2.2 mmol) was added to an anhydrous N-methylpyrrolidone (NMP, 3 mL) solution of 2-bromo-6-methylaniline (126 μL, 1 mmol). The reaction mixture was placed in a microwave reactor and irradiated at 220 °C for 40 min. Upon completion of the reaction, the mixture was cooled to room temperature and poured into a mixture consisting of ammonia (50% w/v, 10 mL) and ice. Subsequently, the mixture was stirred for 30 min and the target product was extracted with dichloromethane (3 x 20 mL). The organic layers were combined, washed sequentially with water and saturated saline, dried with anhydrous magnesium sulfate (MgSO4), and then concentrated. The crude product was purified by silica gel column chromatography (eluent: 50% ethyl acetate/hexane) to give a brown oil, which was crystallized after standing (128 mg, 96% yield). The structure of the product was confirmed by 1H NMR (400 MHz, DMSO-d6) and mass spectrometry (MS): 1H NMR δ 2.08 (s, 3H), 5.68 (bs, 2H), 6.51-6.55 (t, 1H), 7.17-7.19 (d, 1H), 7.22-7.24 (dd, 1H); MS m/z 133 ([M+H ]+).

References

[1] Patent: US2008/306053, 2008, A1. Location in patent: Page/Page column 60

2-AMINO-3-CYANOTOLUENE Preparation Products And Raw materials

Global( 73)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29640 60
Changzhou Ansciep Chemical Co., Ltd.
+86 519 86305871 sales@ansciepchem.com CHINA 4241 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
Fuxin Pharmaceutical
+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10000 58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
+8613580539051 joe@yuhengpharm.com CHINA 21142 58
Career Henan Chemica Co
+86-0371-86658258 +8613203830695 laboratory@coreychem.com China 30224 58
Win-Win chemical CO., Limited
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CR Corporation Limited
+8613062833949 fred.wen@crcorporation.cn China 8645 58
Changzhou Anxuan Chemical Co., Ltd
+86-0519-89882563 +86-18961279162 andy@anxuanchem.com China 4327 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418684 +8618949823763 sales@tnjchem.com China 25356 58

2-AMINO-3-CYANOTOLUENE Spectrum

2-AMINO-3-CYANOTOLUENE 2-AMINO-3-METHYL-BENZONITRILE Benzonitrile, 2-aMino-3-Methyl- 2-Cyano-6-methylaniline 3-methyl-2-Amino-benzonitrile 2-amino-3-methylbenzenemethylnitrile 69797-49-5
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