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ChemicalBook >> CAS DataBase List >>2-(tert-butyldiMethylsilyloxy)ethanaMine

2-(tert-butyldiMethylsilyloxy)ethanaMine

CAS No.
101711-55-1
Chemical Name:
2-(tert-butyldiMethylsilyloxy)ethanaMine
Synonyms
(2-Aminoethoxy)(tert-butyl)dimethylsilane;2-(tert-ButyldiMethylsilyloxy)ethylaMine;DK445;DK026;DKFELEX0095;Ethanamine, mono-TMS;2-(t-Butyldimethylsilyloxy)Ethanamine;2-amino-tert-butyldimethylsilyloxyethane;2-(tert-butyldiMethylsilyloxy)ethanaMine;Ethanolamine tert-butyldimethylsilyl ether
CBNumber:
CB32565625
Molecular Formula:
C8H21NOSi
Molecular Weight:
175.34
MDL Number:
MFCD18206132
MOL File:
101711-55-1.mol
MSDS File:
SDS
Last updated:2026-05-28 01:08:25
Product description Number Pack Size Price
2-[[tert-Butyl(dimethyl)silyl]oxy]ethylamine B5874 1ML $49
2-[[tert-Butyl(dimethyl)silyl]oxy]ethylamine B5874 5ML $156
2-(tert-Butyldimethylsilyloxy)ethanamine BEA71155 25g $189
2-(tert-Butyldimethylsilyloxy)ethanamine BEA71155 50g $302.5
2-(tert-Butyldimethylsilyloxy)ethanamine BEA71155 100g $454
More product size

2-(tert-butyldiMethylsilyloxy)ethanaMine Properties

Boiling point 178.4±13.0 °C(Predicted)
Density 0.849±0.06 g/cm3(Predicted)
refractive index 1.43
storage temp. 2-8°C(protect from light)
form Light Brown Liquid
pka 8.78±0.10(Predicted)
color Colorless to Almost colorless
InChI InChI=1S/C8H21NOSi/c1-8(2,3)11(4,5)10-7-6-9/h6-7,9H2,1-5H3
InChIKey XDXFUMZONWWODJ-UHFFFAOYSA-N
SMILES C(N)CO[Si](C(C)(C)C)(C)C

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
HS Code  2931900090
NFPA 704
2
2 0

2-(tert-butyldiMethylsilyloxy)ethanaMine price More Price(71)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B5874 2-[[tert-Butyl(dimethyl)silyl]oxy]ethylamine 101711-55-1 1ML $49 2026-04-30 Buy
TCI Chemical B5874 2-[[tert-Butyl(dimethyl)silyl]oxy]ethylamine 101711-55-1 5ML $156 2026-04-30 Buy
Biosynth BEA71155 2-(tert-Butyldimethylsilyloxy)ethanamine 101711-55-1 25g $189 2026-06-04 Buy
Biosynth BEA71155 2-(tert-Butyldimethylsilyloxy)ethanamine 101711-55-1 50g $302.5 2026-06-04 Buy
Biosynth BEA71155 2-(tert-Butyldimethylsilyloxy)ethanamine 101711-55-1 100g $454 2026-06-04 Buy
Product number Packaging Price Buy
B5874 1ML $49 Buy
B5874 5ML $156 Buy
BEA71155 25g $189 Buy
BEA71155 50g $302.5 Buy
BEA71155 100g $454 Buy

2-(tert-butyldiMethylsilyloxy)ethanaMine Chemical Properties,Uses,Production

Chemical Properties

2-(tert-butyldiMethylsilyloxy)ethanaMine is Light Brown Liquid

Uses

2-(tert-butyldiMethylsilyloxy)ethanaMine is used in the preparation of 3-substituted androsterone derivatives.

Synthesis

Monoethanolamine

141-43-5

tert-Butyldimethylsilyl chloride

18162-48-6

2-(tert-butyldiMethylsilyloxy)ethanaMine

101711-55-1

The general procedure for the synthesis of 2-((tert-butyldimethylsilyloxy)ethylamine from 2-aminoethanol and tert-butyldimethylsilyl chloride was as follows: a solution of tert-butyldimethylsilyl chloride (3.6 g, 24 mmol) dissolved in dichloromethane (10 mL) was added slowly and dropwise over a period of 3 minutes to a stirring mixture of 2-aminoethanol (1.22 g, 20 mmol) and imidazole (2.04 g, 30 mmol) in a mixed solution. The reaction mixture was continued to be stirred at room temperature for 1 hour. Subsequently, water (20 mL) was added for quenching and the organic and aqueous phases were separated. The aqueous phase was extracted with dichloromethane (2 x 20 mL), all organic phases were combined, dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to give the light yellow oily product 2-((tert-butyldimethylsilyloxy)ethylamine (3.50 g, 100% yield). The product was confirmed by NMR hydrogen spectrum (400 MHz, CDCl3): δ 3.64 (t, J = 5.0 Hz, 2H), 3.05 (br s, 2H), 2.80 (t, J = 5.0 Hz, 2H), 0.90 (s, 9H), 0.06 (s, 6H); NMR carbon spectrum (100 MHz, CDCl3): δ 64.7, 44.1, 25.9, 18.3, -3.4; mass spectrum (APCI+) showing the molecular ion peak [M + H]+ = 176.6.

References

[1] Journal of Organic Chemistry, 2010, vol. 75, # 17, p. 6023 - 6026
[2] Patent: WO2015/100363, 2015, A1. Location in patent: Page/Page column 43
[3] Patent: US2014/194431, 2014, A1. Location in patent: Paragraph 1044-1045
[4] Angewandte Chemie - International Edition, 2014, vol. 53, # 42, p. 11356 - 11360
[5] Angew. Chem., 2014, vol. 126, # 42, p. 11538 - 11542,5

141-43-5
18162-48-6
101711-55-1
Synthesis of 2-(tert-butyldiMethylsilyloxy)ethanaMine from Monoethanolamine and tert-Butyldimethylsilyl chloride

2-(tert-butyldiMethylsilyloxy)ethanaMine Preparation Products And Raw materials

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View Lastest Price from 2-(tert-butyldiMethylsilyloxy)ethanaMine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-(t-Butyldimethylsilyloxy)Ethanamine pictures 2026-04-17 2-(t-Butyldimethylsilyloxy)Ethanamine
101711-55-1
$1.10-9.90 1kg 99%min 100kg ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
2-(tert-butyldiMethylsilyloxy)ethanaMine pictures 2019-07-12 2-(tert-butyldiMethylsilyloxy)ethanaMine
101711-55-1
$1.00 1KG 99% 25kg Career Henan Chemical Co

2-(tert-butyldiMethylsilyloxy)ethanaMine Spectrum

101711-55-1(2-(tert-butyldiMethylsilyloxy)ethanaMine)Related Search:

2-(tert-butyldiMethylsilyloxy)ethanaMine EthanaMine, 2-[[(1,1-diMethylethyl)diMethylsilyl]oxy]- 2-(t-Butyldimethylsilyloxy)Ethanamine Ethanolamine tert-butyldimethylsilyl ether [2-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]ethyl]amine 2-(tert-butyl-dimethylsilanyloxy)ethylamine 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]ethanamine Ethanamine, mono-TMS 2-amino-tert-butyldimethylsilyloxyethane DK026 DK445 2-(Tert-butyl dimethyl sulyloxy)ethanamine DKFELEX0095 (2-Aminoethoxy)(tert-butyl)dimethylsilane 2-(tert-ButyldiMethylsilyloxy)ethylaMine 101711-55-1 C8H21NOSi Miscellaneous Reagents
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