1,4-Phenylenebisboronic acid
- CAS No.
- 4612-26-4
- Chemical Name:
- 1,4-Phenylenebisboronic acid
- Synonyms
- 1,4-PHENYLENEDIBORONIC ACID;BENZENE-1,4-DIBORONIC ACID;1,4-BENZENEDIBORONIC ACID;1,4-Phenyldiboronic acid;1,4-PHENYLENEBIS(BORONIC ACID);p-Benzenediboronic acid;(4-Boronophenyl)boronic acid;NSC 25410;AKOS BRN-0002;enebisboronic acid
- CBNumber:
- CB3274806
- Molecular Formula:
- C6H8B2O4
- Molecular Weight:
- 165.75
- MDL Number:
- MFCD00236018
- MOL File:
- 4612-26-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| Benzene-1,4-diboronic acid ≥95.0% | 417130 | 5g | $134 |
| Benzene-1,4-diboronic acid ≥95.0% | 417130 | 25g | $321 |
| 1,4-Phenylenediboronic Acid (contains varying amounts of Anhydride) | P1358 | 1g | $29 |
| 1,4-Phenylenediboronic Acid (contains varying amounts of Anhydride) | P1358 | 5g | $75 |
| 1,4-Phenylenebisboronic acid | FP74696 | 50g | $181 |
| More product size | |||
| Melting point | >350 °C(lit.) |
|---|---|
| Boiling point | 420.1±55.0 °C(Predicted) |
| Density | 1.33±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | soluble in Methanol |
| pka | 8.30±0.17(Predicted) |
| form | liquid |
| color | white to off-white |
| Water Solubility | Soluble in water 2.5%. |
| BRN | 2836921 |
| InChI | InChI=1S/C6H8B2O4/c9-7(10)5-1-2-6(4-3-5)8(11)12/h1-4,9-12H |
| InChIKey | BODYVHJTUHHINQ-UHFFFAOYSA-N |
| SMILES | C1(B(O)O)=CC=C(B(O)O)C=C1 |
| CAS DataBase Reference | 4612-26-4(CAS DataBase Reference) |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302 | |||||||||
| Precautionary statements | P264-P270-P301+P312-P501 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn,C,Xi | |||||||||
| Risk Statements | 22-36/37/38-20/21/22 | |||||||||
| Safety Statements | 36-26 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Corrosive | |||||||||
| TSCA | No | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29310095 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral | |||||||||
| NFPA 704 |
|
1,4-Phenylenebisboronic acid price More Price(88)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 417130 | Benzene-1,4-diboronic acid ≥95.0% | 4612-26-4 | 5g | $134 | 2026-04-30 | Buy |
| Sigma-Aldrich | 417130 | Benzene-1,4-diboronic acid ≥95.0% | 4612-26-4 | 25g | $321 | 2026-04-30 | Buy |
| TCI Chemical | P1358 | 1,4-Phenylenediboronic Acid (contains varying amounts of Anhydride) | 4612-26-4 | 1g | $29 | 2026-04-30 | Buy |
| TCI Chemical | P1358 | 1,4-Phenylenediboronic Acid (contains varying amounts of Anhydride) | 4612-26-4 | 5g | $75 | 2026-04-30 | Buy |
| Biosynth | FP74696 | 1,4-Phenylenebisboronic acid | 4612-26-4 | 50g | $181 | 2026-06-04 | Buy |
1,4-Phenylenebisboronic acid Chemical Properties,Uses,Production
Chemical Properties
1,4-Phenylenebisboronic acid is off-white powder
Uses
Reagent used for . Externally initiated Kumada catalyst-transfer polycondensation . Suzuki-Miyaura cross-coupling reactions . Energy transfer processes in optoelectronic devices . Palladium-catalyzed sequential alkenylation and conjugate addition reactions . Scholl cyclizations
Uses
It is used for palladium-catalyzed sequential alkenylation and conjugate addition reactions, scholl cyclizations, Suzuki-Miyaura cross-coupling reactions. It is also used in the preparation of indolizine derivatives as OLEDs, in organic thin-film transistors, Fluorescence and solution-processable coordination polymers.
Uses
suzuki reaction
Synthesis
121-43-7
106-37-6
4612-26-4
Under the protection of nitrogen atmosphere, 200 mL of tetrahydrofuran (THF) was added to the reaction flask and cooled to 15°C. 0 g (0.62 mmol) of magnesium and 1.0 g (0.004 mol) of iodine were slowly added followed by the dropwise addition of 300 mL of THF solution containing 68.4 g (0.29 mol) of 1,4-dibromobenzene at a controlled titration rate maintaining the reaction temperature at 30°C. The reaction was continued for 3 hours. After completion, the reaction was continued for 3 hours. After completion of the reaction, the reaction mixture was cooled to -70°C and a mixed solution consisting of trimethyl borate (78.5 mL, 0.72 mol) and 300 mL of THF was slowly added dropwise. After the dropwise addition was completed, the reaction was continued at -70°C for 1 hour, then slowly warmed to room temperature and stirred for 12 hours. To the reaction mixture was added 950 mL of 2.5 M hydrochloric acid, stirred rapidly for 15 minutes and the solid product was collected by filtration. The solid was washed 3 times with 300 mL of hexane and finally dried under vacuum to give 40.7 g of white solid 1,4-phenylenediboronic acid in 84.6% yield.
References
[1] Patent: CN103570530, 2016, B. Location in patent: Paragraph 0042; 0043
1,4-Phenylenebisboronic acid Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai UCHEM Inc. | +86-18930848214 +86-021-56762820 | sales@myuchem.com | China | 8834 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20120 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14026 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21585 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29812 | 58 |
| NINGBO INNO PHARMCHEM CO., LTD. | 13867897135 | sales@nbinno.com | CHINA | 923 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10821 | 58 |
View Lastest Price from 1,4-Phenylenebisboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-07-28 | Benzene-1,4-diboronic acid
4612-26-4
|
$27.00-191.00 | 25g | 0.98 | 100kg | Shanghai UCHEM Inc. | |
 |
2026-07-09 | 1,4-Phenylenebisboronic acid
4612-26-4
|
$3.00-8.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd | ||
 |
2025-05-12 | 1,4-Phenylenebisboronic acid
4612-26-4
|
1kg | 98% | 2 MTs | PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD |
-
- Benzene-1,4-diboronic acid
4612-26-4
- $27.00-191.00
- 0.98
- Shanghai UCHEM Inc.
-
- 1,4-Phenylenebisboronic acid
4612-26-4
- $3.00-8.00
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 1,4-Phenylenebisboronic acid
4612-26-4
- $0.00
- 98%
- PUSHAN INDUSTRIAL (SHAANXI) CO.,LTD
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