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ChemicalBook >> CAS DataBase List >>Ethyl 2-cyano-3,3-diphenylacrylate

Ethyl 2-cyano-3,3-diphenylacrylate

CAS No.
5232-99-5
Chemical Name:
Ethyl 2-cyano-3,3-diphenylacrylate
Synonyms
UV-3035;ETOCRILENE;ETOCRYLENE;ETHYL 2-CYANO-3,3-DIPHENYLACRYLATE;ce2;2-Propenoicacid,2-cyano-3,3-diphenyl-,ethylester;PCE-2;uvinuln35;tocrylene;Etocrylne
CBNumber:
CB3337091
Molecular Formula:
C18H15NO2
Molecular Weight:
277.32
MDL Number:
MFCD00027364
MOL File:
5232-99-5.mol
MSDS File:
SDS
Last updated:2026-05-28 04:59:47
Product description Number Pack Size Price
Ethyl 2-cyano-3,3-diphenylacrylate 98% 415812 50g $119
Ethyl 2-Cyano-3,3-diphenylacrylate >98.0%(GC) C0962 25g $22
Ethyl 2-Cyano-3,3-diphenylacrylate >98.0%(GC) C0962 500g $158
Ethyl 2-cyano-3,3-diphenylacrylate ≥98% AA003H14 10g $10
Ethyl 2-cyano-3,3-diphenylacrylate 98% AA003H14 25g $12
More product size

Ethyl 2-cyano-3,3-diphenylacrylate Properties

Melting point 97-99 °C(lit.)
Boiling point 174 °C0.2 mm Hg(lit.)
Density 1,05 g/cm3
refractive index 1.5100 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility soluble in Methanol
form powder to crystal
color White to Almost white
Cosmetics Ingredients Functions UV ABSORBER
InChI InChI=1S/C18H15NO2/c1-2-21-18(20)16(13-19)17(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h3-12H,2H2,1H3
InChIKey IAJNXBNRYMEYAZ-UHFFFAOYSA-N
SMILES C(OCC)(=O)/C(/C#N)=C(/C1=CC=CC=C1)\C1=CC=CC=C1
LogP 4.520 (est)
CAS DataBase Reference 5232-99-5(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 974109G71I
EPA Substance Registry System Ethyl 2-cyano-3,3-diphenylacrylate (5232-99-5)
UNSPSC Code 12162002
NACRES NA.24

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Environment (GHS09)
GHS07,GHS09
Signal word  Warning
Hazard statements  H315-H319-H335-H410
Precautionary statements  P261-P264-P271-P273-P302+P352-P305+P351+P338
Hazard Codes  Xi,N
Risk Statements  36/37/38-50/53
Safety Statements  26-36-60-61
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  AT6200000
TSCA  TSCA listed
HS Code  29269090
Storage Class 11 - Combustible Solids
Hazardous Substances Data 5232-99-5(Hazardous Substances Data)
REACH Registrations Active
NFPA 704
0
2 0

Ethyl 2-cyano-3,3-diphenylacrylate price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 415812 Ethyl 2-cyano-3,3-diphenylacrylate 98% 5232-99-5 50g $119 2026-04-30 Buy
TCI Chemical C0962 Ethyl 2-Cyano-3,3-diphenylacrylate >98.0%(GC) 5232-99-5 25g $22 2026-04-30 Buy
TCI Chemical C0962 Ethyl 2-Cyano-3,3-diphenylacrylate >98.0%(GC) 5232-99-5 500g $158 2026-04-30 Buy
aablocks AA003H14 Ethyl 2-cyano-3,3-diphenylacrylate ≥98% 5232-99-5 10g $10 2026-05-28 Buy
aablocks AA003H14 Ethyl 2-cyano-3,3-diphenylacrylate 98% 5232-99-5 25g $12 2026-05-28 Buy
Product number Packaging Price Buy
415812 50g $119 Buy
C0962 25g $22 Buy
C0962 500g $158 Buy
AA003H14 10g $10 Buy
AA003H14 25g $12 Buy

Ethyl 2-cyano-3,3-diphenylacrylate Chemical Properties,Uses,Production

Description

Etocrylene (Ethyl 2-cyano-3,3-diphenylacrylate) is an organic ester that appears as an off-white crystalline powder and functions as a UV absorber. When applied to the skin, this product absorbs UV rays. It can also be used to protect cosmetics and personal care products from deterioration. This product can be used in the formulation of sun protection products, as well as bath, skin, cleansing, hair, nail and fragrance products.

Uses

Ethyl 2-Cyano-3,3-diphenylacrylate is a sunscreen ingredient.

Uses

Ultraviolet screen.

Synthesis Reference(s)

Journal of the American Chemical Society, 63, p. 3452, 1941 DOI: 10.1021/ja01857a057
Tetrahedron Letters, 33, p. 7535, 1992 DOI: 10.1016/S0040-4039(00)60817-1

Synthesis

The preparation method of Ethyl 2-cyano-3,3-diphenylacrylate includes the following steps: add cyclohexane and benzophenone to the reaction kettle, wait until the benzophenone is completely dissolved, then raise the temperature to 102-104°C and keep it warm. Then, add sodium bicarbonate as a catalyst, add ethyl cyanoacetate into the dripping storage tank, slowly add ethyl cyanoacetate dropwise into the reaction kettle, and react for 16 to 18 hours. During the reaction, the water generated is separated in time, and the reaction is completed. The product Ethyl 2-cyano-3,3-diphenylacrylate is obtained.

Properties and Applications

Ethyl 2-cyano-3,3-diphenylacrylate, another name Etocrylene, belongs to acrylic acid or the like UV light absorbers and is mainly used in making UV light absorbers in plastics, coating, dyestuff, vehicle glass, makeup, sun-screening agent. Because acrylate-based, two phenyls of this product and carbonyl can form a larger π key; thus, the structure shape of this product has extremely strong ultraviolet absorption ability.

References

[1] Hisashi Matsumoto, Yasuhiko Suzuki, Shinichi Adachi. “[Estrogenic activity of ultraviolet absorbers and the related compounds].” Yakugaku zasshi: Journal of the Pharmaceutical Society of Japan 125 8 (2005): 643–52.
[2] Marlene Vila . “Ultrasound-assisted emulsification microextraction followed by gas chromatography–mass spectrometry and gas chromatography–tandem mass spectrometry for the analysis of UV filters in water.” Microchemical Journal 124 (2016): Pages 530-539.

119-61-9
105-56-6
5232-99-5
Synthesis of Ethyl 2-cyano-3,3-diphenylacrylate from Benzophenone and Ethyl cyanoacetate

Ethyl 2-cyano-3,3-diphenylacrylate Preparation Products And Raw materials

Global( 352)Suppliers
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Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Etocrilene pictures 2026-06-05 Etocrilene
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1kg 99% 10 tons WUHAN FORTUNA CHEMICAL CO., LTD
uv absorber 3035 pictures 2026-06-02 uv absorber 3035
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25ASSAYS 98% 20 tons QINGDAO JADE NEW MATERIAL TECNOLOGY CO.,LTD
UV absorber Etocrilene / UV-3035  pictures 2026-05-28 UV absorber Etocrilene / UV-3035
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$10.70 10KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
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  • Etocrilene
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Ethyl 2-cyano-3,3-diphenylacrylate Spectrum

Relying on the state forest Etocrilene Ethyl 2-cyano-33-diphenylpropenoate Ethyl 2-cyano-3,3-diphenylacrylate 98% UV Absorber 3035 2-cyano-3,3-diphenyl-2-propenoicaciethylester 2-cyano-3,3-diphenyl-acrylicaciethylester uvabsorber-2 uvinuln35 ETHYL DIPHENYLMETHYLENECYANOACETATE ETHYL-2-CYANO-3,3-DIPHENYLPROPENOATE LABOTEST-BB LT00159302 2-CYANO-3,3-DIPHENYLACRYLIC ACID ETHYL ESTER 2-CYANO-3,3-DIPHENYL-2-PROPENOIC ACID ETHYL ESTER Viosorb 910 Etocrilene=2-Cyano-3,3-diphenylacrylicacidethylester tocrylene 2-CYANO-3,3-DIPHENYLACRYLIC ACID ETHYL ESTER 98+% Ethyl 2-cyano-3,3-diphenyl 2-Cyano-3,3-diphenylpropenoic acid ethyl ester Diphenylmethylenecyanoacetic acid ethyl ester ethyl 2-cyano-3,3-di(phenyl)prop-2-enoate 3,3-dicyclopropyl-2-(ethoxycarbonyl)-acrylonitril alpha-carbethoxy-beta,beta-biscyclopropylacrylonitrile beta,beta-biscyclopropyl-alpha-carbethoxy-acrylonitril ethyl2-cyano-3,3-diphenyl-2-propenoate usafa-15972 Ethyl 2-Cyano-3,3-diphenylacrylate > 2-Cyano-3,3-diphenyL Etocrilene ISO 9001:2015 REACH UV ABSORBER TRUELICHT UV 3035 UV absorber Etocrilene / UV-3035 Etocrilene 5232-99-5 2-Propenoicacid,2-cyano-3,3-diphenyl-,ethylester ETHYL 2-CYANO-3,3-DIPHENYLACRYLATE ce2 UV Absorber Etocrylene Etocrilene Ethyl 2-cyano-3,3-diphenylacrylate, 98% Etocrilene UV absorbent Sinosorb? UV-3035 / Etocrilene Ethyl 2-Cyano-3,3-diphenylacrylate, ≥ 98.0% Tinuvin 3035 Etocrylne CHLUMIUV UV-3035 PCE-2 Etocrilene / UV 3035 Ethyl 2-cyano-3,3-diphenylacrylate (UV-3035) ethyl 2-cyano-3 Based on Lulin Relying on Lulin Relying on Lilin ETOCRYLENE ETOCRILENE UV-3035 5232-99-5 C6H52CCCNCO2C2H5 C12 to C63 Carbonyl Compounds Building Blocks
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