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1-(Bromomethyl)naphthalene

1-(Bromomethyl)naphthalene structure

CAS No.: 3163-27-7

Chemical Name:: 1-(Bromomethyl)naphthalene

Synonyms: 1-BROMOMETHYL NAPHTHALENE;CL015;1-(Bromomethyl)napht;1-Naphtylmethyl bromide;(1-Naphtyl)bromomethane;1-(Bromomthy)Naphthalene;1-(Bromomethyl)phthalene;1-Naphthylmethyl bromide;1-(Brommethyl)naphthalen;1-broMo Methyl napthalene

CBNumber:: CB3337682

Molecular Formula:: C11H9Br

Molecular Weight:: 221.09

MDL Number:: MFCD00010804

MOL File:: 3163-27-7.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 05:02:13

Product description	Number	Pack Size	Price
1-(Bromomethyl)naphthalene >98.0%(GC)	B4563	5g	$43
1-(Bromomethyl)naphthalene >98.0%(GC)	B4563	25g	$209
1-(Bromomethyl)naphthalene, ≥95% 95%	228545	5g	$193
1-(Bromomethyl)naphthalene, ≥95% 95%	228545	25g	$273
1-(Bromomethyl)naphthalene, ≥95% 95%	228545	100g	$588
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1-(Bromomethyl)naphthalene Properties

Melting point	52-55°C
Boiling point	213°C/100mmHg
Density	1.44
refractive index	1.6600
storage temp.	Inert atmosphere,2-8°C
form	Powder
color	Off-white
Water Solubility	Slightly soluble in water.
λmax	292nm(Cyclohexane)(lit.)
CAS DataBase Reference	3163-27-7(CAS DataBase Reference)
NIST Chemistry Reference	1-(Bromomethyl)naphthalene(3163-27-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05

Signal word

Danger

Hazard statements

H318-H290-H314

Precautionary statements

P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501-P260h-P301+P330+P331-P303+P361+P353-P305+P351+P338-P501a

Hazard Codes

Risk Statements

20/21/22-36/37/38

Safety Statements

26-36

RIDADR

3261

HazardClass

PackingGroup

HS Code

29036990

NFPA 704

	1
3		0

1-(Bromomethyl)naphthalene price More Price(56)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TCI Chemical	B4563	1-(Bromomethyl)naphthalene >98.0%(GC)	3163-27-7	5g	$43	2026-04-30	Buy
TCI Chemical	B4563	1-(Bromomethyl)naphthalene >98.0%(GC)	3163-27-7	25g	$209	2026-04-30	Buy
Usbiological	228545	1-(Bromomethyl)naphthalene, ≥95% 95%	3163-27-7	5g	$193	2026-06-03	Buy
Usbiological	228545	1-(Bromomethyl)naphthalene, ≥95% 95%	3163-27-7	25g	$273	2026-06-03	Buy
Usbiological	228545	1-(Bromomethyl)naphthalene, ≥95% 95%	3163-27-7	100g	$588	2026-06-03	Buy

Product number	Packaging	Price	Buy
B4563	5g	$43	Buy
B4563	25g	$209	Buy
228545	5g	$193	Buy
228545	25g	$273	Buy
228545	100g	$588	Buy

1-(Bromomethyl)naphthalene Chemical Properties,Uses,Production

Chemical Properties

Off-white powder

Uses

It is employed as a intermediate for organic synthesis and pharmaceutical.

Synthesis

4780-79-4

3163-27-7

The general procedure for the synthesis of 1-bromomethylnaphthalene from 1-naphthalenemethanol: Ethyl α,α-diacetoacetate (0.41 mmol, 1.2 eq.), 1-naphthalenemethanol (0.34 mmol, 1.0 eq.), and triphenylphosphine (0.68 mmol, 2.0 eq.) were added to 3 mL of dichloroethane (DCE) at room temperature and the reaction took place in air. The progress of the reaction was monitored by thin layer chromatography (TLC) during the reaction. Upon completion of the reaction, the reaction was quenched by the addition of 3 mL of water, followed by extraction with ethyl acetate (3 x 3 mL). The organic phases were combined, washed with saturated saline, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography, and the eluent was petroleum ether or a mixed solvent of petroleum ether and ethyl acetate, and the target product 1-bromomethyl naphthalene was finally obtained.

References

[1] Synthetic Communications, 2010, vol. 40, # 11, p. 1646 - 1649
[2] Organic Letters, 2003, vol. 5, # 8, p. 1167 - 1169
[3] Tetrahedron Letters, 2014, vol. 55, # 1, p. 90 - 93
[4] Canadian Journal of Chemistry, 1981, vol. 59, p. 2629 - 2641
[5] Tetrahedron, 2003, vol. 59, # 52, p. 10453 - 10463

1-(Bromomethyl)naphthalene synthesis

Synthesis of 1-(Bromomethyl)naphthalene from 1-Naphthalenemethanol

1-(Bromomethyl)naphthalene Preparation Products And Raw materials

Raw materials

1-(Dimethoxymethyl)naphthalene 1-NAPHTHOIC ACID METHYL ESTER Bromomethyl methyl ether Carbon tetrabromide Formaldehyde

1-Naphthalenemethanol 1-Methylnaphthalene Naphthalene 1-Naphthaldehyde 1-Naphthoic acid

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Preparation Products

1-Methylnaphthalene 1,2-BIS(1-NAPHTHYL)ETHANE 1-BROMO-2-METHYLNAPHTHALENE 1-broMo-4-phthaldehyde 1-(1-naphthylmethyl)-1H-indole-2,3-dione

(1-Naphthyl)methyl Methacrylate

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1-(Bromomethyl)naphthalene Suppliers

Global( 212)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shaanxi Dideu Medichem Co. Ltd	+86-029-81138252 +86-173 9270 1263	1057@dideu.com	China	3957	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29640	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	14026	58
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29812	58
Xiamen AmoyChem Co., Ltd	+86-86-5926051114	sales@amoychem.com	China	6366	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED		sales@conier.com	China	49979	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17346	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +86-189 4982 3763	sales@tnjchem.com	China	34563	58

Supplier	Advantage
Shaanxi Dideu Medichem Co. Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Xiamen AmoyChem Co., Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
SIMAGCHEM CORP	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from 1-(Bromomethyl)naphthalene manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-07-08	1-(Bromomethyl)naphthalene 3163-27-7	$1.00	1Kg	98%	20T	Shaanxi Dideu Medichem Co. Ltd
2021-07-13	1-(Bromomthy)Naphthalene 3163-27-7	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd
2021-07-09	1-(Bromomthy)Naphthalene 3163-27-7	$10.00-15.00	1KG	99%+ HPLC		Zhuozhou Wenxi import and Export Co., Ltd

1-(Bromomethyl)naphthalene
3163-27-7
$1.00
98%
Shaanxi Dideu Medichem Co. Ltd

1-(Bromomthy)Naphthalene
3163-27-7
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

1-(Bromomthy)Naphthalene
3163-27-7
$10.00-15.00
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

1-(Bromomethyl)naphthalene Spectrum

1-(Bromomethyl)naphthalene(3163-27-7)¹HNMR 1-(Bromomethyl)naphthalene(3163-27-7)¹³CNMR

3163-27-7(1-(Bromomethyl)naphthalene)Related Search:

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Dimethylnaphthalene, mixture of isomers 2-(Bromomethyl)naphthalene Methyl bromide 1-BROMO-4-(BROMOMETHYL)NAPHTHALENE 1,4-BIS(BROMOMETHYL)NAPHTHALENE

3-(BROMOMETHYL)PYRENE 1,8-BIS(BROMOMETHYL)NAPHTHALENE 4-(BROMOMETHYL)NAPHTHALENE-1-CARBONITRILE 1-(BROMOMETHYL)-4-NITRONAPHTHALENE 9,10-Bis(bromomethyl)anthracene

ALPHA-BROMO-1-NAPHTHALENEACETIC ACID ETHYL ESTER 4-(BROMOMETHYL)NAPHTHALENE-1-CARBOXYLIC ACID 1-Bromomethyl-7-fluoro-naphthalene

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Naphthalene, 1-(bromomethyl)- 1-BROMOMETHYL NAPHTHALENE 99.73% 1-(Bromomthy)Naphthalene 1-(Bromomethy)naphthalene (1-Naphtyl)bromomethane 1-Naphtylmethyl bromide 1-(Bromomethyl)napht 1-broMo Methyl napthalene 1-Naphthylmethyl bromide 1-(Bromomethyl)phthalene CL015 1-(Bromomethyl)naphthalene, 98% off-white powder 1-(Bromomethyl)naphthalene > 1-(Brommethyl)naphthalen 1-BROMOMETHYL NAPHTHALENE 3163-27-7 3136-27-7 3613-27-7 Naphthalene series

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