9-BBN DIMER
- CAS No.
- 21205-91-4
- Chemical Name:
- 9-BBN DIMER
- Synonyms
- 9-BORABICYCLO[3.3.1]NONANE DIMER;9-BBN DIMER;9-BBN,Dimmer;9BBN0.5MinTHF;9-BBN dimer, 97%;9-BBN dimer, 97% (Gms);9-BBN CRYSTALLINE DIMER;9-BBN,0.5MsolutioninTHF;9-BBN dimer,98%,crystalline;9-BBN DIMER, CRYSTALLINE, 98%
- CBNumber:
- CB4155805
- Molecular Formula:
- C16H30B2
- Molecular Weight:
- 244.04
- MDL Number:
- MFCD00168069
- MOL File:
- 21205-91-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 9-Borabicyclo[3.3.1]nonane dimer | 178713 | 5g | $126 |
| 9-Borabicyclo[3.3.1]nonane dimer | 178713 | 25g | $403 |
| 9-BBN Dimer | 440354 | 1g | $319 |
| 9-BBN Dimer | 440354 | 2.5g | $418 |
| 9-BBN Dimer (Technical Grade) | TRC-B119150-5G | 5g | $138 |
| More product size | |||
| Melting point | 150-152 °C(lit.) |
|---|---|
| Boiling point | 365.8±48.0 °C(Predicted) |
| storage temp. | 2-8°C |
| solubility | Soluble in tetrahydrofuran, ether, hexane, benzene, toluene, carbon tetrachloride, chloroform, dichloromethane and dimethylsulfide. Slightly soluble in cyclohexane, dimethoxyethane, diglyme and dioxane. |
| form | crystalline |
| Sensitive | Air & Moisture Sensitive |
| BRN | 605509 |
| Stability | Hygroscopic, Moisture Sensitive |
| InChI | InChI=1S/C16H30B2/c1-5-13-7-2-8-14(6-1)17(13)19-18(20-17)15-9-3-10-16(18)12-4-11-15/h13-16H,1-12H2 |
| InChIKey | IYDIZBOKVLHCQZ-GEEKYZPCSA-N |
| SMILES | B12([H]B3(C4CCCC3CCC4)[H]1)C1CCCC2CCC1 |
| UNSPSC Code | 12352005 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H228-H261-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P231+P232-P261-P305+P351+P338-P422 | |||||||||
| PPE | Eyeshields, Gloves, type P3 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | F,Xi | |||||||||
| Risk Statements | 11-14/15-36/37/38 | |||||||||
| Safety Statements | 26-43 | |||||||||
| RIDADR | UN 3396 4.3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-16 | |||||||||
| HazardClass | 4.2 | |||||||||
| PackingGroup | I | |||||||||
| HS Code | 29349990 | |||||||||
| Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | |||||||||
| Hazard Classifications | Eye Irrit. 2 Flam. Sol. 1 Skin Irrit. 2 STOT SE 3 Water-react 2 |
|||||||||
| Limited Quantities | 0.5 Kg (1.1 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml) | |||||||||
| NFPA 704 |
|
9-BBN DIMER price More Price(29)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 178713 | 9-Borabicyclo[3.3.1]nonane dimer | 21205-91-4 | 5g | $126 | 2026-04-30 | Buy |
| Sigma-Aldrich | 178713 | 9-Borabicyclo[3.3.1]nonane dimer | 21205-91-4 | 25g | $403 | 2026-04-30 | Buy |
| Usbiological | 440354 | 9-BBN Dimer | 21205-91-4 | 1g | $319 | 2026-06-03 | Buy |
| Usbiological | 440354 | 9-BBN Dimer | 21205-91-4 | 2.5g | $418 | 2026-06-03 | Buy |
| TRC | TRC-B119150-5G | 9-BBN Dimer (Technical Grade) | 21205-91-4 | 5g | $138 | 2026-06-03 | Buy |
9-BBN DIMER Chemical Properties,Uses,Production
Chemical Properties
white crystals or crystalline powder
Uses
Employed in the hydroboration of alkynes, nitriles, and ketones.
reaction suitability
reagent type: reductant
Purification Methods
It is available as the solid dimer or in tetrahydrofuran solution. The solid is relatively stable and can be purified by distillation in a vacuum (as dimer) and by recrystallisation from tetrahydrofuran (solubility at room temperature is 9.5%, 0.78M), filter off the solid under N2, wash it with dry pentane and dry it in vacuo at ca 100o. The solid is a dimer (IR 1567cm-1), stable in air (for ca 2 months), and can be heated for 24hours at 200o in an inert atmosphere without loss of hydride activity. It is a dimer in tetrahydrofuran solution also (IR 1567cm-1). It is sensitive to H2O and air (O2) in solution. Its concentration in solution can be determined by reaction with MeOH and measuring the volume of H2 liberated, or it can be oxidised to cis-cyclooctane-1,5-diol (m 73.5-74.5o). [IR: Knights & Brown J Am Chem Soc 90 5280 1968, Brown et al. J Am Chem Soc 96 7765 1974, Brown et al. J Org Chem 41 1778 1976, Brown & Chen J Org Chem 46 3978 1981, Fieser & Fieser Reagents for Org Synth 2 31, 3 24, 10 48, 15 43, 17, 49.] Borane pyridine complex [110 -51 -0] M 92.9, m 8-10o, 10-11o, b 86o/7mm, 100-1 0 1o/12mm, d 4 0.785. Dissolve it in Et2O and wash it with H2O in which it is insoluble. Evaporate the Et2O and distil the residual oil to gives better than 99.8% purity. Its vapour pressure is less than 0.1mm at room temperature. [Taylor et al. J Am Chem Soc 77 1506 1955, Beilstein 20 IV 2235.]
9-BBN DIMER Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1803 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29815 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 8741 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52705 | 58 |
| Henan Alfa Chemical Co., Ltd | +8615838112936 | sale03@alfachem.cn | China | 9796 | 58 |
| HANGZHOU LEAP CHEM CO., LTD. | +86-571-87711850 | market18@leapchem.com | China | 24597 | 58 |
| Coresyn Pharmatech Co., Ltd. | +86-571-86626709 +86-18157142896 | cbc@coresyn.com | China | 9984 | 58 |
View Lastest Price from 9-BBN DIMER manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | 9-BBN DIMER
21205-91-4
|
$1.00 | 1kg | 98%min | Career Henan Chemical Co |
-
- 9-BBN DIMER
21205-91-4
- $1.00
- 98%min
- Career Henan Chemical Co
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