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ChemicalBook >> CAS DataBase List >>(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid

(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid

CAS No.
85977-52-2
Chemical Name:
(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid
Synonyms
Afobazole Impurity 3;Palonosetron Intermediate 1;Palonosetron interMediater B;(S)-1,2,3,4-TETRAHYDRO-NAPHTHOIC ACID;(S)-1,2,3,4-tetrahydro-1-naphtoic Acid;(S)-1,2,3,4-tetrahydro-1-naphthoic acid;(S)-1,2,3,4-TETRAHUDRO-1-NAPHTHOIC ACID;(S)-(-)-1,2,3,4-TETRAHYDRONAPHTHOIC ACID;D-(-)-1,2,3,4-Tetrahydro-1-naphthoic Acid;(s)-(-)-1,2,3,4-tetrahedro-naphthoic acid
CBNumber:
CB4259099
Molecular Formula:
C11H12O2
Molecular Weight:
176.21
MDL Number:
MFCD07368365
MOL File:
85977-52-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 03:08:37
Product description Number Pack Size Price
S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 289866 250mg $372
S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 289866 500mg $516
S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 289866 1g $711
S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 289866 2g $974
S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 289866 5g $1351
More product size

(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid Properties

Melting point 54-56°C
Boiling point 54-56°C
Density 1.186±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform
form Solid
pka 4.28±0.20(Predicted)
color White
InChI InChI=1S/C11H12O2/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-2,4,6,10H,3,5,7H2,(H,12,13)/t10-/m0/s1
InChIKey VDLWTJCSPSUGOA-JTQLQIEISA-N
SMILES [C@@H]1(C(O)=O)C2=C(C=CC=C2)CCC1
CAS DataBase Reference 85977-52-2(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi,Xn
Risk Statements  22-36-51
Safety Statements  26-24/25
HS Code  29163990
NFPA 704
0
2 0

(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid price More Price(77)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Usbiological 289866 S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 85977-52-2 250mg $372 2026-06-03 Buy
Usbiological 289866 S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 85977-52-2 500mg $516 2026-06-03 Buy
Usbiological 289866 S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 85977-52-2 1g $711 2026-06-03 Buy
Usbiological 289866 S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 85977-52-2 2g $974 2026-06-03 Buy
Usbiological 289866 S-(-)-1,2,3,4-Tetrahedro-naphthoic acid Asreported 85977-52-2 5g $1351 2026-06-03 Buy
Product number Packaging Price Buy
289866 250mg $372 Buy
289866 500mg $516 Buy
289866 1g $711 Buy
289866 2g $974 Buy
289866 5g $1351 Buy

(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid Chemical Properties,Uses,Production

Chemical Properties

White Solid

Uses

Intermediate in the preparation of Dipeptidyl Boronate Proteasome Inhibitors.

Synthesis

1,2,3,4-Tetrahydro-1-naphthoic acid

1914-65-4

(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid

85977-52-2

General procedure for the synthesis of (S)-tetrahydronaphthalenecarboxylic acid from 1,2,3,4-tetrahydro-1-naphthalenecarboxylic acid: 15.6 g (0.1 mol) of 1,2,3,4-tetrahydronaphthalenecarboxylic acid and 29.8 g (0.1 mol) of quinine were added to 158 mL of a 50% (v/v) aqueous ethanol solution, and stirred for 30 min at 50 °C until complete dissolution. The progress of the reaction was monitored by thin layer chromatography (TLC) with the unfolding agent ratio of petroleum ether (PE):ethyl acetate (EA) = 1:2. Upon completion of the reaction, the reaction solution was cooled to below 0 °C overnight to promote crystallization. Subsequent to filtration, the solid was collected and dried. The dried solid was recrystallized with 90 mL of ethanol, crystallized again at 0 °C, diafiltrated and dried. The resulting product was dissolved in a mixture of 55 mL of 1 mol/L hydrochloric acid and 100 mL of ethyl acetate in a partitioning operation. The organic phase was dried and filtered and concentrated to obtain the crude product. Finally, the crude product was recrystallized from hexane to give 7.21 g of (S)-1,2,3,4-tetrahydronaphthalenecarboxylic acid in the form of white solid in 43.6% yield.

References

[1] Patent: CN108084176, 2018, A. Location in patent: Paragraph 0093; 0102; 0103; 0104
[2] Arkiv foer Kemi, 1958, vol. 12, p. 161,165
[3] Patent: CN107382697, 2017, A

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View Lastest Price from (S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-1,2,3,4-tetrahedro-naphthoic acid pictures 2026-05-28 (S)-1,2,3,4-tetrahedro-naphthoic acid
85977-52-2
 $2.00-5.00 1g 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid pictures 2026-03-20 (S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid
85977-52-2
 $10.00 1KG 99% 10 mt Hebei Chuanghai Biotechnology Co., Ltd
(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid pictures 2025-06-27 (S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid
85977-52-2
 1KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd

(S)-(-)-1,2,3,4-Tetrahedro-naphthoic acid Spectrum

(1S)-1,2,3,4-Tetrahydro-1-naphthalenecarboxylic Acid D-(-)-1,2,3,4-Tetrahydro-1-naphthoic Acid (S)-(-)-1,2,3,4-Tetrahydro-1-naphthoic acid(W.S) (1S)-1-Carboxy-1,2,3,4-tetrahydronaphthalene, (1S)-1,2,3,4-Tetrahydro-1-naphthoic acid Palonosetron interMediater B 1-Naphthalenecarboxylic acid, 1,2,3,4-tetrahydro-,(1S)- (S)-1, 2, 3, 4-Tetrahydronaphthoic acidCAS (S)-1,2,3,4-Tetrahydro-1-naphthoic Acid,99%e.e. (S)-1,2,3,4-TETRAHYDRO-NAPHTHALENE-1-CARBOXYLIC ACID (S)-(-)-1,2,3,4-TETRAHYDRONAPHTHOIC ACID (S)-1,2,3,4-TETRAHYDRO-NAPHTHOIC ACID (s)-(-)-1,2,3,4-tetrahedro-naphthoic acid (S)-1,2,3,4-tetrahydro-1-naphthoic acid (S)-(-)-1,2,3,4-Tetrahedro-1-NaphthoicAcid (S)-1,2,3,4-TETRAHUDRO-1-NAPHTHOIC ACID (S)-1,2,3,4-tetrahydro-1-naphtoic Acid (1S)-1-Carboxy-1,2,3,4-tetrahydronaphthalene (1S)-1,2,3,4-Tetrahydronaphthalene-1-carboxylic acid Palonosetron Intermediate 1 (S)-1,2,3,4-Tetrahydro-1-naphthoic acid, 98%, (SH-(-)-1,2,3,4-Tetrahedro-naphthoic acid (S)-1,2,3,4-Tetrahydro-1-naphthalenecarboxylic acid Afobazole Impurity 3 85977-52-2 Carboxylic Acids & Deriv. CHIRAL CHEMICALS INTERMEDIATESOFPALONOSETRONHYDROCHLORIDE Aromatics Chiral Reagents Intermediates
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