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ChemicalBook >> CAS DataBase List >>BUTOXYCARBOXIM

BUTOXYCARBOXIM

CAS No.
34681-23-7
Chemical Name:
BUTOXYCARBOXIM
Synonyms
butoxicarboxim;co859;PLANT PIN;BUTOXYCARBOXIM;BUTOXYCARBOXIN;butoxycarboxime;BUTOXICARBOXIME;Butoxycarboxim-sulfone;Butoxycarboxim Solution;Butoxycarboxim in Methanol
CBNumber:
CB4278285
Molecular Formula:
C7H14N2O4S
Molecular Weight:
222.26
MDL Number:
MFCD00055365
MOL File:
34681-23-7.mol
MSDS File:
SDS
Last updated:2026-07-31 15:25:14
Product description Number Pack Size Price
Butoxycarboxim B809485 10mg $85
BUTOXYCARBOXIM 95.00% PST0000604 5MG $496.52
More product size

BUTOXYCARBOXIM Properties

Melting point 83°C
Density 1.3816 (rough estimate)
refractive index 1.5690 (estimate)
pka 13.41±0.46(Predicted)
Henry's Law Constant 3.5×106 mol/(m3Pa) at 25℃, HSDB (2015)
FDA UNII C51715874E
EPA Substance Registry System Butoxycarboxim (34681-23-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P330-P501
Hazard Codes  Xn
Risk Statements  22
RTECS  EL9210000
Hazardous Substances Data 34681-23-7(Hazardous Substances Data)

BUTOXYCARBOXIM price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC B809485 Butoxycarboxim 34681-23-7 10mg $85 2021-12-16 Buy
American Custom Chemicals Corporation PST0000604 BUTOXYCARBOXIM 95.00% 34681-23-7 5MG $496.52 2021-12-16 Buy
Product number Packaging Price Buy
B809485 10mg $85 Buy
PST0000604 5MG $496.52 Buy

BUTOXYCARBOXIM Chemical Properties,Uses,Production

Application

BUTOXYCARBOXIM can be used for: (1) applicable crops, ornamental plants. (2) pests such as aphids and spider mites.

Description

Butoxycarboxim is a carbamate insecticide. It is highly soluble in water and is non-volatile. It can be moderately persistent in soils. Persistence in water will depend on local conditions. Based on its physico-chemical properties there is potential to leach to groundwater. Toxicity to biodiversity tends to be moderate to low. Butoxycarboxin is also moderately toxic to mammals if ingested.

Chemical Properties

Butanone soar contains (E)- and (Z)-isomer (85~90):(15~10), colorless crystals. Melting point 85~89℃, pure (E)-isomer 83℃. Vapor pressure 0.266mPa(20℃). Density 1.21g/cm3(20℃).Henry's constant 2.83×10-7 Pa-m3/mol.Solubility in water 209g/L(20℃);Solubility in other solvents(20℃,g/L):Acetone 172,CTC 5.3,Chloroform 186,Cyclohexane 0.9,Heptane 0.1,Isopropyl Alcohol 101,Toluene 29;Freely soluble in polar Soluble in polar solvents, slightly soluble in non-polar solvents. ≤100℃ thermally stable. Hydrolyzed DT50 in aqueous solution: 501d (pH 5), 18d (pH 7), 16d (pH 9). Stable to UV light.

Definition

ChEBI: Butoxycarboxim is a carbamate ester. It has a role as an EC 3.1.1.7 (acetylcholinesterase) inhibitor, a carbamate insecticide and an agrochemical.

Production Methods

Butoxycarboxim is typically produced through a two-step chemical synthesis process starting from readily available precursors. In the first step, the intermediate butocarboxim is synthesised by nucleophilic substitution of 3-chloro-2-butanone with methyl mercaptan to form 3-(methylthio)-2-butanone, followed by oximation with hydroxylamine hydrochloride to yield the oxime, and subsequent acylation of the oxime hydroxyl group with methyl isocyanate to introduce the N-methylcarbamate moiety, resulting in a mixture of isomeric butocarboxim. This intermediate is then oxidised in the second step using peracetic acid (or a similar oxidant) to convert the thioether sulphur atom to a sulfone, affording butoxycarboxim in high yield. The process is conducted under controlled conditions in industrial reactors to manage exothermic reactions and ensure product purity, with purification typically involving extraction, distillation, or chromatography.

Mechanism of action

Systemic with contact and stomach action. Acetylcholine esterase inhibitor.

Pesticide Type

Insecticide; Acaricide

BUTOXYCARBOXIM Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 48)Suppliers
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Hefei TNJ Chemical Industry Co.,Ltd.
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Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 18080918076 800078821@qq.com China 9717 55
TianJin Alta Scientific Co., Ltd. 022-65378550-8551 contact@altascientific.com China 2773 58
Alta Scientific Co., Ltd. 022-6537-8550 15522853686 sales@altasci.com.cn China 4511 55
Shanghai YuanYe Biotechnology Co., Ltd. 13636370518 shyysw007@163.com China 89686 60
3-METHYLSULFONYLBUTANONE O-METHYL CARBAMOYLOXIME BUTOXYCARBOXIM PLANT PIN 2-Butanone,3-methylsulfonyl-,O-(N-methylcarbamoyl)oxime 2-methylsulfonyl-o-(n-methyl-carbamoyl)-butanon-(3)-oxim 3-(sulfonyl)-o-((methylamino)carbonyl)oxime-2-butanone 3-mesylbutanoneo-methylcarbamoyloxime 3-methylsulfonyl-2-butanono-(n-methylcarbamoyl)oxime 3-methylsulphonylbutanoneo-methylcarbamoyloxime butoxycarboxime co859 BUTOXYCARBOXIM PESTANAL BUTOXYCARBOXIN butoxycarboxim (bsi,iso,jmaf) BUTOXICARBOXIME 3-(Methylsulfonyl)-2-butanone O-(methylcarbamoyl)oxime Butoxycarboxim Solution Butoxycarboxim@100 μg/mL in AcCN 2-Butanone, 3-(methylsulfonyl)-, O-[(methylamino)carbonyl]oxime Butoxycarboxim-sulfone Butoxycarboxim 10.0 μg/ml Acetonitrile Butoxycarboxim in Methanol butoxicarboxim 34681-23-7 A-BAlphabetic Alpha sort B BI - BZPesticides Carbamates Insecticides Pesticides&Metabolites
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