ChemicalBook >> CAS DataBase List >>(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
- CAS No.
- 35193-64-7
- Chemical Name:
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
- Synonyms
- (R)-(-)-BNP ACID;4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(R)-(-)-BNPA;(R)-(-)-BPA;(11bS)-;(S)-(+)-BPA;(S)-(+)-BNPA;(S)-(+)-BNDHP.;(S)-(+)-BNP ACID;(S)-(+)-1,1'-Binapht
- CBNumber:
- CB5107331
- Molecular Formula:
- C20H13O4P
- Molecular Weight:
- 348.29
- MDL Number:
- MFCD00010045
- MOL File:
- 35193-64-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-05-28 01:24:55
| Product description | Number | Pack Size | Price |
| (S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate 97% | 248940 | 1g | $126 |
| (S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate 97% | 248940 | 5g | $274 |
| (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >97.0%(T) | B1144 | 1g | $53 |
| (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >97.0%(T) | B1144 | 100mg | $17 |
| (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98% min.98% | 15-0053 | 1g | $54 |
| More product size | |||
| Melting point | ≥300 °C |
|---|---|
| alpha | 607.5 º (c=1.4,MeOH) |
| Boiling point | 619.5±38.0 °C(Predicted) |
| Density | 1.49±0.1 g/cm3(Predicted) |
| refractive index | 595 ° (C=1, MeOH) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Soluble in DMSO and methanol (hot). |
| form | Powder |
| pka | 1.14±0.20(Predicted) |
| color | white |
| optical activity | [α]22/D +595°, c = 1.35 in methanol |
| BRN | 4787775 |
| InChI | InChI=1S/C20H14O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12,19H,(H,21,22) |
| InChIKey | LOHAVLUFTJNVNC-UHFFFAOYSA-N |
| SMILES | P1(OC2=CC=C3C(=C2C2([H])=C4C(C=CC=C4)=CC=C2O1)C=CC=C3)(O)=O |
| CAS DataBase Reference | 35193-64-7(CAS DataBase Reference) |
| UNSPSC Code | 12352005 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315 | |||||||||
| Precautionary statements | P302+P352 | |||||||||
| PPE | Eyeshields, Gloves, type N95 (US) | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/37/38-20/21/22 | |||||||||
| Safety Statements | 26-36-36/37/39-22 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | RZ2475100 | |||||||||
| F | 10-23 | |||||||||
| HS Code | 29199000 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Skin Irrit. 2 | |||||||||
| NFPA 704 |
|
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate price More Price(79)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 248940 | (S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate 97% | 35193-64-7 | 1g | $126 | 2026-04-30 | Buy |
| Sigma-Aldrich | 248940 | (S)-(+)-1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate 97% | 35193-64-7 | 5g | $274 | 2026-04-30 | Buy |
| TCI Chemical | B1144 | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >97.0%(T) | 35193-64-7 | 1g | $53 | 2026-04-30 | Buy |
| TCI Chemical | B1144 | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >97.0%(T) | 35193-64-7 | 100mg | $17 | 2026-04-30 | Buy |
| Strem Chemicals | 15-0053 | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98% min.98% | 35193-64-7 | 1g | $54 | 2026-04-30 | Buy |
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties,Uses,Production
Reaction
- Asymmetric hetero Diels-Alder reaction catalyzed by chiral lanthanide(III) complex.
- Highly efficient Mannich reaction
- Acidic Resolving agent for certain amine/racemic mixtures.
Chemical Properties
white to light yellow crystal powde
Uses
Used as a chiral Bronsted acid catalyst in the enantoselective Mannich reaction.
Uses
The S enantiomer of binaphthol derivative as chiral quenching agent.
Purification Methods
Recrystallise it from EtOH. Reflux for 3hours in N NaOH is required to hydrolyse the cyclic phosphate. [Jacques et al. Tetrahedron Lett 4617 1971, Arnold et al. Tetrahedron 24, 343 1983.]
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 303)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 462 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-173 9270 1263 | 1057@dideu.com | China | 3958 | 58 |
| Shanghai UCHEM Inc. | +1-7027589231 +1-7027589231 | sales@myuchem.com | China | 8834 | 58 |
| ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | +86-15225627621 +86-13213167925 | jiuyitime@fdachem.com | China | 16511 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14026 | 58 |
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| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29812 | 58 |
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| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 21193 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 9599 | 58 |
View Lastest Price from (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-07-24 | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
|
$65.00-213.00 | 25g | 0.98 | 25kg | Paints customs n glass | |
 |
2026-07-02 | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2026-06-30 | (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
|
1kg | 99% | 10000KGS | Shaanxi Dideu New Materials Co. Ltd |
-
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
- $65.00-213.00
- 0.98
- Paints customs n glass
-
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
35193-64-7
- $0.00
- 99%
- Shaanxi Dideu New Materials Co. Ltd
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Spectrum
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)MS(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)1HNMR(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)IR(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)Raman(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate(35193-64-7)FT-IR
35193-64-7((S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate)Related Search:
(S)-(-)-1,1'-Bi-2-naphthol
Clindamycin phosphate
1,1'-Bi-2-naphthol
SULPHOSUCCINIC ACID ESTER
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
1of3
(S)-(+)-BNP ACID
(S)-(+)-BNPA
(S)-(+)-BPA
(S)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOPHEPIN-4-OXID
(S)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
(S)-(+)-1,1'-BINAPHTHELENE-2,2'-DIYL-PHOSPHATE
(S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
S-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
(S)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
S(+)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
S(+)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE
(S)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
(S)-4-HYDROXYDINAPHTHO[2,1-D:1'',2''-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE: (S)-(+)-BNP ACID
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 98+%
(11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-Oxide
(S)-(+)-1,1μ-Binaphthalene-2,2μ-diyl hydrogen phosphate, (S)-4-Hydroxydinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-oxide
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98%
[aS,(+)]-2,2'-Phosphinicobisoxy-1,1'-binaphthalene
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate,99%
(S)-(+)-1,1'-Binapht
(S)-5,5',6,6',7,7',8,8'-Octahydro-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate
(11bS)-
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate
(S)-(+)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide, (S)-(+)-BNDHP
(11bS)-4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate,(S)-(-)-BNDHP
(R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE
(R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
R(-)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE
(R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
(R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID
(R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE
(+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
(S)-(+)-BNDHP.
S-(+)BNP ACID / S-(-)-1,1''-BINAPHTHYL-2,2''-DIPHEMYL PHOSPHINE
(S)-(+)-1,1-Binaphthyl-2,2'-dihydrogenphosphate
(S)-(+)-1,1'-binaphthyl-2
(S)-(+)-BINAPHTHYL-2,2'-DIYL HYDROGENPHO SPHATE
S-(+)-1,1Binaphthalene-2,2Dihydrogen Phosphate
(S)-(+)-1,1'-Binaphthyl-2,2'-diylhydrogenephosphate
(S)-(+)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE
(S)-(+)-1,1'-Binaphthyl-2,2'-d
(S)-(+)-1,1'-Binaphthyl-2,2'-diylhydrogenphosphate,min.98%
Dinaphtho2,1-d:1,2-f1,3,2dioxaphosphepin, 4-hydroxy-, 4-oxide, (11bS)-
S)-(+)-1,1'-Binaphthyl-2,2'-diyl
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 97%
(S)-(+)-1,1'-Biphthyl-2,2'-diyl hydrogenphosphate
(S)-1,1'-Binaphthalene-2,2'-diyl Hydrogen Phosphate,99%e.e.
(S)-(+)-1,1'-Binaphthalene-2,2'-diyl-phosphate for synthesis
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-, 4-oxide, (S)-
(11bS)-4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(S)-(+)-1,1'-BINAPHTHE
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate >
(R)-(-)-BPA
(R)-(-)-BNP ACID
(+)-1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate
(S)-(+)-1,1'-Binaphthyl-2,2'-diyl Hydrogen Phosphate
