2-(Trifluoromethoxy)bromobenzene
- CAS No.
- 64115-88-4
- Chemical Name:
- 2-(Trifluoromethoxy)bromobenzene
- Synonyms
- 1-BROMO-2-(TRIFLUOROMETHOXY)BENZENE;1-Bromo-2-(trifL;light yellow liquid,bp185;2-(TRIFLUOROMETHOXY)BENZENE;O-TRIFLUOROMETHOXYBROMOBENZENE;2-(Trifluoromethoxy)bromobenze;2-BROMO(TRIFLUOROMETHOXY)BENZENE;2-(TRIFLUOROMETHOXY)BROMOBENZENE;O-BROMO(TRIFLUOROMETHOXY)BENZENE;2-(trifluoromrthoxy)bromobenzene
- CBNumber:
- CB5299205
- Molecular Formula:
- C7H4BrF3O
- Molecular Weight:
- 241.01
- MDL Number:
- MFCD00040942
- MOL File:
- 64115-88-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 1-Bromo-2-(trifluoromethoxy)benzene 97% | 553891 | 5g | $41.6 |
| 1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) | T2147 | 5g | $17 |
| 1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) | T2147 | 25g | $27 |
| 1-Bromo-2-(trifluoromethoxy)benzene 99% | PC7438UY | 50g | $25 |
| 1-Bromo-2-(trifluoromethoxy)benzene 99% | PC7438UY | 100g | $45 |
| More product size | |||
| Boiling point | 158-160 °C(lit.) |
|---|---|
| Density | 1.62 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 140 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | clear liquid |
| color | Colorless to Light yellow |
| BRN | 1947768 |
| InChI | 1S/C7H4BrF3O/c8-5-3-1-2-4-6(5)12-7(9,10)11/h1-4H |
| InChIKey | ITYCJCVRPBLODP-UHFFFAOYSA-N |
| SMILES | FC(F)(F)Oc1ccccc1Br |
| CAS DataBase Reference | 64115-88-4(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() ![]() GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a | |||||||||
| PPE | Eyeshields, Gloves, multi-purpose combination respirator cartridge (US) | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36/37/39-37 | |||||||||
| RIDADR | UN1993 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29093090 | |||||||||
| Storage Class | 3 - Flammable liquids | |||||||||
| Hazard Classifications | Flam. Liq. 3 | |||||||||
| Limited Quantities | 5.0 L (1.3 gallons) (liquid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
2-(Trifluoromethoxy)bromobenzene price More Price(63)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 553891 | 1-Bromo-2-(trifluoromethoxy)benzene 97% | 64115-88-4 | 5g | $41.6 | 2022-05-15 | Buy |
| TCI Chemical | T2147 | 1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) | 64115-88-4 | 5g | $17 | 2026-04-30 | Buy |
| TCI Chemical | T2147 | 1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) | 64115-88-4 | 25g | $27 | 2026-04-30 | Buy |
| Apolloscientific | PC7438UY | 1-Bromo-2-(trifluoromethoxy)benzene 99% | 64115-88-4 | 50g | $25 | 2026-06-04 | Buy |
| Apolloscientific | PC7438UY | 1-Bromo-2-(trifluoromethoxy)benzene 99% | 64115-88-4 | 100g | $45 | 2026-06-04 | Buy |
2-(Trifluoromethoxy)bromobenzene Chemical Properties,Uses,Production
Uses
1-Bromo-2-(trifluoromethoxy)benzene can be prepared from (trifluoromethoxy)benzene.
General Description
1-Bromo-2-(trifluoromethoxy)benzene can be prepared from (trifluoromethoxy)benzene.
Synthesis
1035797-66-0
88284-48-4
64115-88-4
In a glove box, KF (78.4 mg, 1.35 mmol, 4.5 eq.) was added to a 20 mL polyethylene (PE) plastic tube. Subsequently, dicyclohexane-18-crown-6 (503 mg, 1.35 mmol, 4.5 eq.) and 6. Next, ethylidene precursor (0.3 mmol, 1.0 eq.), 1-bromophenylacetylene (218 mg, 1.2 mmol, 4.0 eq.) or perfluorohexyl bromide (479 mg, 1.2 mmol, 4.0 eq.) or pentafluorophenyl bromide ( 296 mg, 1.2 mmol, 4.0 equiv) and trifluoromethyl benzoate (171 mg, 0.9 mmol, 3.0 equiv). The reaction tube was sealed and the reaction was carried out at room temperature for 12 hours. At the end of the reaction, the F-spectral yield was first determined by 19F NMR. Finally, the reaction mixture was filtered, dried and purified directly by column chromatography.
References
[1] Patent: CN108516935, 2018, A. Location in patent: Paragraph 0166; 0167; 0168; 0169; 0170; 0171
[2] Journal of the American Chemical Society, 2018, vol. 140, # 22, p. 6801 - 6805
2-(Trifluoromethoxy)bromobenzene Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Anhui Zhongda Biotechnology Co., Ltd | +8619956560829 | justine@zhongda-biotech.com | China | 286 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20120 | 58 |
| Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 14026 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21585 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29812 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-29-87569262 +86-15003564040 | 1056@dideu.com | China | 3968 | 58 |
View Lastest Price from 2-(Trifluoromethoxy)bromobenzene manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2026-07-09 | 2-(Trifluoromethoxy)bromobenzene
64115-88-4
|
$1.00-100.00 | 1KG | 99% | Henan Fengda Chemical Co., Ltd | ||
![]() |
2026-02-02 | 2-(Trifluoromethoxy)bromobenzene
64115-88-4
|
10mg | 99% | 2000tons | Shaanxi Dideu Medichem Co. Ltd | ||
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2023-11-03 | 2-(Trifluoromethoxy)bromobenzene
64115-88-4
|
$10.00 | 1kg | 99% | 100T | Anhui Zhongda Biotechnology Co., Ltd |
-

- 2-(Trifluoromethoxy)bromobenzene
64115-88-4
- $1.00-100.00
- 99%
- Henan Fengda Chemical Co., Ltd
-

- 2-(Trifluoromethoxy)bromobenzene
64115-88-4
- 99%
- Shaanxi Dideu Medichem Co. Ltd
-

- 2-(Trifluoromethoxy)bromobenzene
64115-88-4
- $10.00
- 99%
- Anhui Zhongda Biotechnology Co., Ltd
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