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ChemicalBook >> CAS DataBase List >>2-(Trifluoromethoxy)bromobenzene

2-(Trifluoromethoxy)bromobenzene

CAS No.
64115-88-4
Chemical Name:
2-(Trifluoromethoxy)bromobenzene
Synonyms
1-BROMO-2-(TRIFLUOROMETHOXY)BENZENE;1-Bromo-2-(trifL;light yellow liquid,bp185;2-(TRIFLUOROMETHOXY)BENZENE;O-TRIFLUOROMETHOXYBROMOBENZENE;2-(Trifluoromethoxy)bromobenze;2-BROMO(TRIFLUOROMETHOXY)BENZENE;2-(TRIFLUOROMETHOXY)BROMOBENZENE;O-BROMO(TRIFLUOROMETHOXY)BENZENE;2-(trifluoromrthoxy)bromobenzene
CBNumber:
CB5299205
Molecular Formula:
C7H4BrF3O
Molecular Weight:
241.01
MDL Number:
MFCD00040942
MOL File:
64115-88-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 02:35:54
Product description Number Pack Size Price
1-Bromo-2-(trifluoromethoxy)benzene 97% 553891 5g $41.6
1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) T2147 5g $17
1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) T2147 25g $27
1-Bromo-2-(trifluoromethoxy)benzene 99% PC7438UY 50g $25
1-Bromo-2-(trifluoromethoxy)benzene 99% PC7438UY 100g $45
More product size

2-(Trifluoromethoxy)bromobenzene Properties

Boiling point 158-160 °C(lit.)
Density 1.62 g/mL at 25 °C(lit.)
refractive index n20/D 1.464(lit.)
Flash point 140 °F
storage temp. Sealed in dry,Room Temperature
form clear liquid
color Colorless to Light yellow
BRN 1947768
InChI 1S/C7H4BrF3O/c8-5-3-1-2-4-6(5)12-7(9,10)11/h1-4H
InChIKey ITYCJCVRPBLODP-UHFFFAOYSA-N
SMILES FC(F)(F)Oc1ccccc1Br
CAS DataBase Reference 64115-88-4(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
PPE Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-37
RIDADR  UN1993
WGK Germany  3
Hazard Note  Irritant
HazardClass  3
PackingGroup  III
HS Code  29093090
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 3
Limited Quantities 5.0 L (1.3 gallons) (liquid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
NFPA 704
2
2 0

2-(Trifluoromethoxy)bromobenzene price More Price(63)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 553891 1-Bromo-2-(trifluoromethoxy)benzene 97% 64115-88-4 5g $41.6 2022-05-15 Buy
TCI Chemical T2147 1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) 64115-88-4 5g $17 2026-04-30 Buy
TCI Chemical T2147 1-Bromo-2-(trifluoromethoxy)benzene >98.0%(GC) 64115-88-4 25g $27 2026-04-30 Buy
Apolloscientific PC7438UY 1-Bromo-2-(trifluoromethoxy)benzene 99% 64115-88-4 50g $25 2026-06-04 Buy
Apolloscientific PC7438UY 1-Bromo-2-(trifluoromethoxy)benzene 99% 64115-88-4 100g $45 2026-06-04 Buy
Product number Packaging Price Buy
553891 5g $41.6 Buy
T2147 5g $17 Buy
T2147 25g $27 Buy
PC7438UY 50g $25 Buy
PC7438UY 100g $45 Buy

2-(Trifluoromethoxy)bromobenzene Chemical Properties,Uses,Production

Uses

1-Bromo-2-(trifluoromethoxy)benzene can be prepared from (trifluoromethoxy)benzene.

General Description

1-Bromo-2-(trifluoromethoxy)benzene can be prepared from (trifluoromethoxy)benzene.

Synthesis

trifluoromethyl benzoate

1035797-66-0

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE

88284-48-4

2-(Trifluoromethoxy)bromobenzene

64115-88-4

In a glove box, KF (78.4 mg, 1.35 mmol, 4.5 eq.) was added to a 20 mL polyethylene (PE) plastic tube. Subsequently, dicyclohexane-18-crown-6 (503 mg, 1.35 mmol, 4.5 eq.) and 6. Next, ethylidene precursor (0.3 mmol, 1.0 eq.), 1-bromophenylacetylene (218 mg, 1.2 mmol, 4.0 eq.) or perfluorohexyl bromide (479 mg, 1.2 mmol, 4.0 eq.) or pentafluorophenyl bromide ( 296 mg, 1.2 mmol, 4.0 equiv) and trifluoromethyl benzoate (171 mg, 0.9 mmol, 3.0 equiv). The reaction tube was sealed and the reaction was carried out at room temperature for 12 hours. At the end of the reaction, the F-spectral yield was first determined by 19F NMR. Finally, the reaction mixture was filtered, dried and purified directly by column chromatography.

References

[1] Patent: CN108516935, 2018, A. Location in patent: Paragraph 0166; 0167; 0168; 0169; 0170; 0171
[2] Journal of the American Chemical Society, 2018, vol. 140, # 22, p. 6801 - 6805

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View Lastest Price from 2-(Trifluoromethoxy)bromobenzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-(Trifluoromethoxy)bromobenzene pictures 2026-07-09 2-(Trifluoromethoxy)bromobenzene
64115-88-4
$1.00-100.00 1KG 99% Henan Fengda Chemical Co., Ltd
2-(Trifluoromethoxy)bromobenzene pictures 2026-02-02 2-(Trifluoromethoxy)bromobenzene
64115-88-4
10mg 99% 2000tons Shaanxi Dideu Medichem Co. Ltd
2-(Trifluoromethoxy)bromobenzene pictures 2023-11-03 2-(Trifluoromethoxy)bromobenzene
64115-88-4
$10.00 1kg 99% 100T Anhui Zhongda Biotechnology Co., Ltd
2-Bromo-6-(trifluoromethyl)anisole 1-BroMo-2-(trifluoroMethoxy)benzen1-BroMo-2-(trifluoroMethoxy)benzen 2-Bromo-alpha,alpha,alpha-trifluoroanisole, 1-Bromo-2-(trifluoromethoxy)benzene, 2-Bromophenyl trifluoromethyl ether light yellow liquid,bp185 1-Bromo-2-(trifluoromethoxy)benzene 99% 2-Bromo-alpha,alpha,alpha-trifluoroanisole, 2-Bromophenyl trifluoromethyl ether 2-BroMo-1-(trifluoroMethoxy)benzene Dibromoethoxychlorophosphonazo Trifluoromethoxybenzene 2-(TRIFLUOROMETHOXY)BENZENE 2-(TRIFLUOROMETHOXY)BROMOBENZENE 2-BROMO(TRIFLUOROMETHOXY)BENZENE 2-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE O-TRIFLUOROMETHOXYBROMOBENZENE O-BROMO(TRIFLUOROMETHOXY)BENZENE 2-(trifluoromrthoxy)bromobenzene 1-Bromo-2-(trifluoromathoxy)Benzene 2-(Trifluoromethoxy)bromobenze 2-(Trifluoromethoxy)bromobenzene 99% 2-(Trifluoromethoxy)bromobenzene99% 1-BROMO-2-(TRIFLUOROMETHOXY)BENZENE / 2-BROMO-TRIFLUOROMETHOXYBENZENE 2-(trifluoromethoxy)bromobenzene,1-bromo-2-(trifluoromethoxy)benzene Adjacent Bromine Trifluoride Mathoxyphenyl TIANFUCHEM--64115-88-4--2-(Trifluoromethoxy)bromobenzene 2-(Trifluoromethoxy)bromobenzene ISO 9001:2015 REACH Benzene, 1-bromo-2-(trifluoromethoxy)- 1-Bromo-2-(trifL Ortho bromotrifluoromethoxybenzene 1-BROMO-2-(TRIFLUOROMETHOXY)BENZENE 64115-88-4 641115-88-4 ARYL HALIDE Ethers Organic Building Blocks Oxygen Compounds Building Blocks Pyridines alkyl bromide Fluorobenzene Aromatic Halides (substituted) Trifluoroanisole series Miscellaneous Ethers Organic Building Blocks Oxygen Compounds
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