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ChemicalBook >> CAS DataBase List >>4,4'-DI-TERT-BUTYLDIPHENYLAMINE

4,4'-DI-TERT-BUTYLDIPHENYLAMINE

CAS No.
4627-22-9
Chemical Name:
4,4'-DI-TERT-BUTYLDIPHENYLAMINE
Synonyms
BIS(4-TERT-BUTYLPHENYL)AMINE;4-tert-butyl-N-(4-tert-butylphenyl)aniline;Stearer STAR;p,p'-Di-tert-butyldip;Di-4-tert-butylphenylamine;-DI-TERT-BUTYLDIPHENYLAMINE;Bis(p-tert-butylphenyl)amine;4,4'-DI-TERT-BUTYLDIPHENYLAMINE;p,p'-Di-tert-butyldiphenylamine;N,N-Bis(4-tert-butylphenyl)amine
CBNumber:
CB6146702
Molecular Formula:
C20H27N
Molecular Weight:
281.44
MDL Number:
MFCD00417391
MOL File:
4627-22-9.mol
MSDS File:
SDS
Last updated:2026-05-28 01:22:31
Product description Number Pack Size Price
Bis(4-tert-butylphenyl)amine >90.0%(GC) B2803 25g $31
Bis(4-tert-butylphenyl)amine >90.0%(GC) B2803 500g $159
DBDPA ≥90% 45197 25g $29
DBDPA ≥90% 45197 50g $55
DBDPA ≥90% 45197 100g $104
More product size

4,4'-DI-TERT-BUTYLDIPHENYLAMINE Properties

Melting point 108 °C
Boiling point 195 °C / 3mmHg
Density 0.974±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Slightly)
form Solid
pka 1.47±0.40(Predicted)
color Off-White to Pale Beige
InChI InChI=1S/C20H27N/c1-19(2,3)15-7-11-17(12-8-15)21-18-13-9-16(10-14-18)20(4,5)6/h7-14,21H,1-6H3
InChIKey OPEKHRGERHDLRK-UHFFFAOYSA-N
SMILES C1(NC2=CC=C(C(C)(C)C)C=C2)=CC=C(C(C)(C)C)C=C1
FDA UNII S25750I14Y

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P330-P332+P313-P337+P313-P362-P403+P233-P405-P501
HS Code  29214990
NFPA 704
1
0 0

4,4'-DI-TERT-BUTYLDIPHENYLAMINE price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical B2803 Bis(4-tert-butylphenyl)amine >90.0%(GC) 4627-22-9 25g $31 2026-04-30 Buy
TCI Chemical B2803 Bis(4-tert-butylphenyl)amine >90.0%(GC) 4627-22-9 500g $159 2026-04-30 Buy
Cayman Chemical 45197 DBDPA ≥90% 4627-22-9 25g $29 2026-04-30 Buy
Cayman Chemical 45197 DBDPA ≥90% 4627-22-9 50g $55 2026-04-30 Buy
Cayman Chemical 45197 DBDPA ≥90% 4627-22-9 100g $104 2026-04-30 Buy
Product number Packaging Price Buy
B2803 25g $31 Buy
B2803 500g $159 Buy
45197 25g $29 Buy
45197 50g $55 Buy
45197 100g $104 Buy

4,4'-DI-TERT-BUTYLDIPHENYLAMINE Chemical Properties,Uses,Production

Chemical Properties

White needle-like crystals

Uses

Bis(4-tert-butylphenyl)amine could be a useful reagent for synthesizing efficient luminogens with AIE features that permit imaging the brain through an intact skull.

Synthesis

1-Bromo-4-tert-butylbenzene

3972-65-4

4-tert-Butylaniline

769-92-6

4,4'-DI-TERT-BUTYLDIPHENYLAMINE

4627-22-9

Bis(dibenzylideneacetone)palladium (1.7 g, 3 mmol) and tri-tert-butylphosphine (1.2 g, 6 mmol) were added to toluene (200 mL) under argon protection using 4-tert-butylaniline (14.9 g, 100 mmol) and 4-tert-butylbromobenzene (21.2 g, 100 mmol). The mixture was heated to 90 °C, followed by the addition of sodium tert-butoxide (0.6 g, 6 mmol) and continued heating to 110 °C. The reaction was carried out under an argon atmosphere. The reaction mixture was stirred under argon atmosphere for 12 hours. After completion of the reaction, it was cooled to room temperature and separated by addition of water. The organic layer was concentrated to give a solid product which was purified by silica gel column chromatography to give the target product di(4-tert-butylphenyl)amine (20.2 g, 72 mmol) in 72% yield.

References

[1] Bulletin of the Chemical Society of Japan, 2000, vol. 73, # 4, p. 1021 - 1027
[2] Patent: CN107286027, 2017, A. Location in patent: Paragraph 0052; 0064; 0065; 0066
[3] Patent: CN107573306, 2018, A. Location in patent: Paragraph 0030; 0038
[4] Patent: CN107573357, 2018, A. Location in patent: Paragraph 0039; 0040
[5] Tetrahedron Letters, 2001, vol. 42, # 27, p. 4421 - 4424

3972-65-4
769-92-6
4627-22-9
Synthesis of 4,4'-DI-TERT-BUTYLDIPHENYLAMINE from 1-Bromo-4-tert-butylbenzene and 4-tert-Butylaniline
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View Lastest Price from 4,4'-DI-TERT-BUTYLDIPHENYLAMINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4,4'-Di-tert-butyldiphenylamine pictures 2026-07-09 4,4'-Di-tert-butyldiphenylamine
4627-22-9
$1.00-200.00 1KG 99%, 99.5% Sublimated Henan Fengda Chemical Co., Ltd
4,4'-DI-TERT-BUTYLDIPHENYLAMINE pictures 2023-04-06 4,4'-DI-TERT-BUTYLDIPHENYLAMINE
4627-22-9
1kg 98.0% min 1000kg LY Global chemicals co.,ltd .
4,4'-DI-TERT-BUTYLDIPHENYLAMINE pictures 2020-01-08 4,4'-DI-TERT-BUTYLDIPHENYLAMINE
4627-22-9
$2.00 1KG 98% 100g , 1kg, 5kg , 50kg Career Henan Chemical Co

4,4'-DI-TERT-BUTYLDIPHENYLAMINE Spectrum

4,4'-DI-TERT-BUTYLDIPHENYLAMINE Bis(p-tert-butylphenyl)amine Di-4-tert-butylphenylamine N,N-Bis(4-tert-butylphenyl)amine p,p'-Di-tert-butyldiphenylamine Stearer STAR BenzenaMine,4-(1,1-diMethylethyl)-N-[4-(1,1-diMethylethyl)phenyl]- Bis(4-tert-butylphenyl)amine p,p'-Di-tert-butyldip Bis(4-tert-butylphenyl)amine > Bis(4-tert-butylphenyl)amine in methanol -DI-TERT-BUTYLDIPHENYLAMINE 4-tert-butyl-N-(4-tert-butylphenyl)aniline BIS(4-TERT-BUTYLPHENYL)AMINE 4627-22-9
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