ChemicalBook >> CAS DataBase List >>(-)-IPC2B(ALLYL), 1M IN PENTANE
(-)-IPC2B(ALLYL), 1M IN PENTANE
- CAS No.
- 85116-38-7
- Chemical Name:
- (-)-IPC2B(ALLYL), 1M IN PENTANE
- Synonyms
- (-) - Ipc2B (allyl) borane;(-)-IPC2B(ALLYL), 1M IN PENTANE;(-)-Ipc2B(allyl)borane solution;(?)-Ipc2B(allyl)borane solution;(-)-Ipc2B(allyl)borane solution;(?)-Ipc2B(allyl)borane solution;(-)-B-Allyldiisopinocampheylborane solution;(-)-Ipc2B(allyl)borane solution 1 M in pentane;(-)-B-ALLYLDIISOPINOCAMPHEYLBORANE 1 M IN DIOXANE;Allylbis((1r,2s,3r,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane
- CBNumber:
- CB6972336
- Molecular Formula:
- C23H39B
- Molecular Weight:
- 326.37
- MDL Number:
- MFCD09038448
- MOL File:
- 85116-38-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-05-28 02:06:38
| Product description | Number | Pack Size | Price |
| (?)-Ipc2B(allyl)borane solution 1 M in pentane | 678538 | 25ml | $359 |
| (?)-Ipc2B(allyl)borane solution 1 M in pentane | 678538 | 5ml | $100 |
| (-)-BETA-ALLYLDIISOPINOCAMPHEYLBORANE 95.00% | BOR0005260 | 5MG | $501.15 |
| Boiling point | 35-36 °C |
|---|---|
| Density | 0.638 g/mL at 25 °C |
| Flash point | -49 °C |
| storage temp. | -20°C |
| optical activity | [α]20/D 35 to ±5°, c = 1 |
| InChI | 1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m1/s1 |
| InChIKey | ZIXZBDJFGUIKJS-RLEROFIGSA-N |
| SMILES | C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(CC=C)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C |
| UNSPSC Code | 12352002 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS07,GHS08,GHS09 |
|---|---|
| Signal word | Danger |
| Hazard statements | H224-H304-H315-H319-H335+H336-H411 |
| Precautionary statements | P210-P261-P273-P301+P310-P305+P351+P338-P331 |
| target organs | Central nervous system, Respiratory system |
| PPE | Eyeshields, Faceshields, Gloves |
| Hazard Codes | F+,Xn,N,F |
| Risk Statements | 12-51/53-65-66-67-40-36/37-19-11-36/37/38 |
| Safety Statements | 9-16-29-33-61-62-36/37-26 |
| RIDADR | UN 1265 3/PG 2 |
| WGK Germany | 3 |
| Storage Class | 3 - Flammable liquids |
| Hazard Classifications | Aquatic Chronic 2 Asp. Tox. 1 Eye Irrit. 2 Flam. Liq. 1 Skin Irrit. 2 STOT SE 3 |
(-)-IPC2B(ALLYL), 1M IN PENTANE price More Price(3)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 678538 | (?)-Ipc2B(allyl)borane solution 1 M in pentane | 85116-38-7 | 25ml | $359 | 2026-04-30 | Buy |
| Sigma-Aldrich | 678538 | (?)-Ipc2B(allyl)borane solution 1 M in pentane | 85116-38-7 | 5ml | $100 | 2024-03-01 | Buy |
| American Custom Chemicals Corporation | BOR0005260 | (-)-BETA-ALLYLDIISOPINOCAMPHEYLBORANE 95.00% | 85116-38-7 | 5MG | $501.15 | 2021-12-16 | Buy |
(-)-IPC2B(ALLYL), 1M IN PENTANE Chemical Properties,Uses,Production
Uses
This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.
Preparation
(-)-IPC2B(ALLYL), 1M IN PENTANE can be prepared in three steps from either (+)- or (-)-α-pinene (eq 1) .
Reactions
(-)-IPC2B(ALLYL), 1M IN PENTANE is most often used as the crude preparation in Et2O; however, reactions have also been conducted in CS2, CHCl3, CH2Cl2, toluene, and THF.
(-)-IPC2B(ALLYL), 1M IN PENTANE Preparation Products And Raw materials
(-)-IPC2B(ALLYL), 1M IN PENTANE Suppliers
Global( 11)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51395 | 80 |
| Energy Chemical | 021-58432009 400-005-6266 | marketing@energy-chemical.com | China | 44918 | 58 |
| Shanghai Arbor Chemical Co., Ltd. | 021-60451683 15001705751 | market@arborpharmchem.com | China | 2045 | 58 |
| Merck KGaA | 21-20338288 | ordercn@merckgroup.com | China | 6038 | 58 |
| Santa Cruz Biotechnology Inc | 021-60936350 | scbt@scbt.com | China | 6530 | 58 |
| Shanghai Hikem Pharmaceutical Development Co., Ltd. | 13889470786 | info@allychem.com | China | 461 | 58 |
| Supplier | Advantage |
|---|---|
| CONIER CHEM AND PHARMA LIMITED | 58 |
| Sigma-Aldrich | 80 |
| Energy Chemical | 58 |
| Shanghai Arbor Chemical Co., Ltd. | 58 |
| Merck KGaA | 58 |
| Santa Cruz Biotechnology Inc | 58 |
| Shanghai Hikem Pharmaceutical Development Co., Ltd. | 58 |
(-)-B-Allyldiisopinocampheylborane solution
(-)-Ipc2B(allyl)borane solution
(-) - Ipc2B (allyl) borane
(-)-B-ALLYLDIISOPINOCAMPHEYLBORANE 1 M IN DIOXANE
Borane, 2-propenylbis[(1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]-
(-)-Ipc2B(allyl)borane solution 1 M in pentane
(-)-Ipc2B(allyl)borane solution
(-)-IPC2B(ALLYL), 1M IN PENTANE
Allylbis((1r,2s,3r,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)borane
prop-2-enyl-bis[(1R,3R,4S,5R)-4,6,6-trimethyl-3-bicyclo[3.1.1]heptanyl]borane
(?)-Ipc2B(allyl)borane solution
(?)-Ipc2B(allyl)borane solution
85116-38-7
C10H172BCH2CHCH2
C23H39B
