METHYL 2-AMINO-3-CARBOXYBENZOATE
- CAS No.
- 253120-47-7
- Chemical Name:
- METHYL 2-AMINO-3-CARBOXYBENZOATE
- Synonyms
- METHYL 2-AMINO-3-CARBOXYBENZOATE;2-Amino-3-(methoxycarbonyl)benzoi;2- aMino-3- carboxyMethyl benzoate;Methyl 2-amino-3-carboxybenzoate 97%;6-Carboxy-2-(methoxycarbonyl)aniline;2-aMino-3-(Methoxycabonyl)benzoic acid;3-(Methoxycarbonyl)-2-aMinobenzoic acid;2-Amino-3-(methoxycarbonyl)benzoic acid;2-AMINO-ISOPHTHALIC ACID MONOMETHYL ESTER;1-Methyl 2-amino-1,3-benzenedicarboxylate
- CBNumber:
- CB7112924
- Molecular Formula:
- C9H9NO4
- Molecular Weight:
- 195.17
- MDL Number:
- MFCD06200897
- MOL File:
- 253120-47-7.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| 2-AMINO-ISOPHTHALIC ACID MONOMETHYL ESTER 95% | 55027 | 0.25G | $48 |
| 2-AMINO-ISOPHTHALIC ACID MONOMETHYL ESTER 95% | 55027 | 1G | $95 |
| 2-AMINO-ISOPHTHALIC ACID MONOMETHYL ESTER 95% | 55027 | 5G | $400 |
| 2-Amino-3-(methoxycarbonyl)benzoic acid ≥95% | OR14348 | 250mg | $37 |
| 2-Amino-3-(methoxycarbonyl)benzoic acid ≥95% | OR14348 | 1g | $134 |
| More product size | |||
| Melting point | 160 °C |
|---|---|
| Boiling point | 370.4±32.0 °C(Predicted) |
| Density | 1.373±0.06 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| pka | 4.57±0.10(Predicted) |
| Appearance | White to off-white Solid |
| InChI | InChI=1S/C9H9NO4/c1-14-9(13)6-4-2-3-5(7(6)10)8(11)12/h2-4H,10H2,1H3,(H,11,12) |
| InChIKey | UXQCFHRNRAGKOY-UHFFFAOYSA-N |
| SMILES | C1(C(OC)=O)=CC=CC(C(O)=O)=C1N |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
| Hazard Codes | Xi,Xn |
| Risk Statements | 22 |
| Hazard Note | Irritant |
| HS Code | 2922500090 |
METHYL 2-AMINO-3-CARBOXYBENZOATE price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| AstaTech | 55027 | 2-AMINO-ISOPHTHALIC ACID MONOMETHYL ESTER 95% | 253120-47-7 | 0.25G | $48 | 2026-04-30 | Buy |
| AstaTech | 55027 | 2-AMINO-ISOPHTHALIC ACID MONOMETHYL ESTER 95% | 253120-47-7 | 1G | $95 | 2026-04-30 | Buy |
| AstaTech | 55027 | 2-AMINO-ISOPHTHALIC ACID MONOMETHYL ESTER 95% | 253120-47-7 | 5G | $400 | 2026-04-30 | Buy |
| Apolloscientific | OR14348 | 2-Amino-3-(methoxycarbonyl)benzoic acid ≥95% | 253120-47-7 | 250mg | $37 | 2026-06-04 | Buy |
| Apolloscientific | OR14348 | 2-Amino-3-(methoxycarbonyl)benzoic acid ≥95% | 253120-47-7 | 1g | $134 | 2026-06-04 | Buy |
METHYL 2-AMINO-3-CARBOXYBENZOATE Chemical Properties,Uses,Production
Synthesis
103030-10-0
253120-47-7
Step 1: Synthesis of 2-amino-3-(methoxycarbonyl)benzoic acid Methyl 2,3-dioxo dihydroindole-7-carboxylate (1 eq.) was dissolved in methanol (0.4 M) and hydrogen chloride gas was passed into the solution at 0 °C with continuous stirring of the reaction mixture for 2 hours. After completion of the reaction, the solvent was removed by evaporation and the resulting residue was diluted with chloroform, washed sequentially with saturated aqueous sodium bicarbonate and brine, and the organic phase was dried over anhydrous sodium sulfate and then concentrated to give the crude product (MS (ES+) m/z 206 (M+H)+). The above crude product was dissolved in 10% aqueous hydrogen peroxide solution, prepared as 0.2 M. An equal volume of 2.5% aqueous sodium hydroxide solution was added and the reaction was stirred for 15 min at room temperature. At the end of the reaction, the reaction mixture was acidified with concentrated hydrochloric acid, the precipitate precipitated was collected by filtration and washed with water to obtain monomethyl 2-aminoisophthalate in 88% yield as a white powder. Product characterization data: 1H NMR (400MHz, DMSO-d6, 300K) δ 3.82 (s, 3H), 6.60 (t, 1H, J=7.4Hz), 8.04 (m, 3H), 12.94 (bs, 1H); MS (ES+) m/z 196 (M+H)+.
References
[1] Synthetic Communications, 1999, vol. 29, # 23, p. 4223 - 4233
[2] Patent: WO2007/28789, 2007, A1. Location in patent: Page/Page column 31
METHYL 2-AMINO-3-CARBOXYBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29626 | 60 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63645 | 58 |
| Wuhan Chemwish Technology Co., Ltd | 027-67849912 | sales@chemwish.com | CHINA | 10817 | 58 |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49906 | 58 | |
| career henan chemical co | +86-0371-86658258 | factory@coreychem.com | China | 29780 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21135 | 58 |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1059@dideu.com | China | 29096 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 17705817739 | info@dycnchem.com | China | 52693 | 58 |
| Changzhou Anxuan Chemical Co., Ltd | +86-0519-89882563 +86-18961279162 | andy@anxuanchem.com | China | 4326 | 58 |
| Labnetwork lnc. | +86-27-50766799 +86-18062016861 | contact@labnetwork.com | China | 19981 | 58 |
View Lastest Price from METHYL 2-AMINO-3-CARBOXYBENZOATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2020-01-09 | METHYL 2-AMINO-3-CARBOXYBENZOATE
253120-47-7
|
$1.00 | 1g | ≥98% | Career Henan Chemical Co |
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- METHYL 2-AMINO-3-CARBOXYBENZOATE
253120-47-7
- $1.00
- ≥98%
- Career Henan Chemical Co
