2-(BROMOMETHYL)BENZYL ALCOHOL, 95%
- CAS No.
- 74785-02-7
- Chemical Name:
- 2-(BROMOMETHYL)BENZYL ALCOHOL, 95%
- Synonyms
- (2-(broMoMethyl)phenyl)Methanol;BenzeneMethanol, 2-(broMoMethyl)-;2-(BroMoMethyl)benzyl alcohol 95%;2-(BROMOMETHYL)BENZYL ALCOHOL, 95%;2-(Bromomethyl)benzenemethanol, 2-Hydroxymethylbenzylbromide
- CBNumber:
- CB7972656
- Molecular Formula:
- C8H9BrO
- Molecular Weight:
- 201.06
- MDL Number:
- MFCD08457642
- MOL File:
- 74785-02-7.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 2-(Bromomethyl)benzyl alcohol 95% | 667706 | 1g | $349 |
| (2-(Bromomethyl)phenyl)methanol | FB139993 | 1g | $900 |
| (2-(Bromomethyl)phenyl)methanol | FB139993 | 0.5g | $900 |
| (2-(Bromomethyl)phenyl)methanol | FB139993 | 0.25g | $900 |
| (2-(Bromomethyl)phenyl)methanol | FB139993 | 0.1g | $900 |
| Melting point | 66-68 °C |
|---|---|
| Boiling point | 279.6±20.0 °C(Predicted) |
| Density | 1.514±0.06 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| form | solid |
| pka | 14.18±0.10(Predicted) |
| Appearance | White to off-white Solid |
| InChI | InChI=1S/C8H9BrO/c9-5-7-3-1-2-4-8(7)6-10/h1-4,10H,5-6H2 |
| InChIKey | JDBQNNKIOFSPOA-UHFFFAOYSA-N |
| SMILES | C1(CO)=CC=CC=C1CBr |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS07,GHS09 |
|---|---|
| Signal word | Danger |
| Hazard statements | H302-H314-H317-H400 |
| Precautionary statements | P260-P273-P280-P301+P312+P330-P303+P361+P353-P305+P351+P338+P310 |
| Hazard Codes | C,N |
| Risk Statements | 22-34-43-50 |
| Safety Statements | 26-28-36/37/39-45-61 |
| RIDADR | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| Storage Class | 8A - Combustible corrosive hazardous materials |
| Hazard Classifications | Acute Tox. 4 Oral Aquatic Acute 1 Eye Dam. Eye Dam. 1 Skin Corr. 1B Skin Sens. 1 |
2-(BROMOMETHYL)BENZYL ALCOHOL, 95% price More Price(43)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 667706 | 2-(Bromomethyl)benzyl alcohol 95% | 74785-02-7 | 1g | $349 | 2026-04-30 | Buy |
| Biosynth | FB139993 | (2-(Bromomethyl)phenyl)methanol | 74785-02-7 | 1g | $900 | 2026-06-04 | Buy |
| Biosynth | FB139993 | (2-(Bromomethyl)phenyl)methanol | 74785-02-7 | 0.5g | $900 | 2026-06-04 | Buy |
| Biosynth | FB139993 | (2-(Bromomethyl)phenyl)methanol | 74785-02-7 | 0.25g | $900 | 2026-06-04 | Buy |
| Biosynth | FB139993 | (2-(Bromomethyl)phenyl)methanol | 74785-02-7 | 0.1g | $900 | 2026-06-04 | Buy |
2-(BROMOMETHYL)BENZYL ALCOHOL, 95% Chemical Properties,Uses,Production
Synthesis
612-14-6
74785-02-7
To 48% hydrobromic acid (15.0 mL) was added 1,2-benzenedimethanol (4.0 g, 29.0 mmol), and the reaction mixture was stirred for 2 h at room temperature. After the reaction was completed, 1N NaOH aqueous solution was added to neutralize to pH 7. The reaction mixture was diluted with ethyl acetate (200 mL), washed sequentially with saturated NaHCO3 solution (20 mL) and brine (20 mL), and the organic phase was dried over anhydrous Na2SO4. The solvent was removed by concentration under reduced pressure and the crude product was purified by silica gel column chromatography (Combi Flash Rf apparatus, ethyl acetate/hexane solvent system, 0-30% gradient elution) to afford 2.6 g (45% yield) of the target compound S14 as a white solid.1H NMR (500 MHz, CDCl3) δ: 7.30-7.45 (m, 4H), 4.85 (s, 2H), 4.64 (s, 2H), 1.81 (br s, 1H).
References
[1] Journal of the American Chemical Society, 2010, vol. 132, # 49, p. 17366 - 17369
[2] Journal of the American Chemical Society, 1980, vol. 102, p. 4193
[3] Synthesis, 1982, # 12, p. 1014 - 1015
[4] Patent: WO2015/69932, 2015, A1. Location in patent: Page/Page column 90; 91
[5] Patent: WO2015/188197, 2015, A2. Location in patent: Page/Page column 78
2-(BROMOMETHYL)BENZYL ALCOHOL, 95% Preparation Products And Raw materials
2-(BROMOMETHYL)BENZYL ALCOHOL, 95% Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 9599 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 57505 | 58 | |
| DAYANG CHEM (HANGZHOU) CO.,LTD | +86-88938639 +86-17705817739 | info@dycnchem.com | China | 53803 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131956 | 58 |
| ROSEWA HOLDING GROUP CO.,LIMITED | +86-023-62871537 | sales@rosewachem.com | China | 2812 | 58 |
| Shanghai He-H Chemical Technology Co., Ltd | 18621911604 | 987025641@qq.com | China | 1217 | 58 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44878 | 61 |
| Beijing Ouhe Technology Co., Ltd | 13552068683 13522913783 | 2355560935@qq.com | China | 11780 | 60 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42934 | 64 |
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