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ChemicalBook >> CAS DataBase List >>Polyisobutylene

Polyisobutylene

CAS No.
9003-27-4
Chemical Name:
Polyisobutylene
Synonyms
POLYISOBUTENE;usb;p20;p118;p200;oppanolb100;PIB=Oppanol(R);POLY(ISOBUTYLENE) 24'000;POLYISOBUTYLENE, AVERAGE MV CA. 1,200,00 0;kp5
CBNumber:
CB8147859
Molecular Formula:
C4H8
Molecular Weight:
56.10632
MDL Number:
MFCD00084436
MOL File:
9003-27-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-07-06 17:03:36
Product description Number Pack Size Price
Polyisobutylene average Mw ~500,000, average Mn ~200,000 by GPC/MALLS, average Mv ~420,000 181455 100g $214
Polyisobutylene United States Pharmacopeia (USP) Reference Standard 1546966 1g $381
Polyisobutylene FP168349 2kg $900
Polyisobutylene FP168349 1kg $900
Polyisobutylene FP168349 0.5kg $900
More product size

Polyisobutylene Properties

Melting point 54-56 °C
Boiling point 300 °C
Density 0.92 g/mL at 25 °C (lit.)
Tg -61
Tg -62
Tg -64
Tg -75
refractive index n20/D 1.51
Flash point >212
Flash point >482
form slab/chunk
color colorlessor white
Viscosity 1.08 - 1.43(Intrinsic viscosity)
Viscosity 2.42 - 3.00(Intrinsic viscosity)
Viscosity 250cp (20C)
Viscosity 3.90 - 5.05(Intrinsic viscosity)
Stability Stability Combustible. Incompatible with strong oxidizing agents.
Cosmetics Ingredients Functions VISCOSITY CONTROLLING
BINDING
FILM FORMING
InChI InChI=1S/C4H8/c1-4(2)3/h1H2,2-3H3
InChIKey VQTUBCCKSQIDNK-UHFFFAOYSA-N
SMILES C=C(C)C
Surface tension 33.6mN/m at 20°C
Substances Added to Food (formerly EAFUS) POLYISOBUTYLENE (MIN M W 37,000)
FDA 21 CFR 175.105; 175.125; 175.300;176.180; 177.1200; 177.1210;177.1390; 177.1420; 177.2800;178.1005; 178.1010; 178.3570;178.3740
EWG's Food Scores 1
FDA UNII POLYISOBUTYLENE (1300 MW) (241BN7J12Y)
POLYISOBUTYLENE (2600000 MW) (4GAS6381TX)
POLYISOBUTYLENE (85000 MW) (7X53O5S2ZY)
POLYISOBUTYLENE (1000 MW) (5XB3A63Y52)
POLYISOBUTYLENE (75000 MW) (596C33NS2J)
EPA Substance Registry System Polyisobutylene (9003-27-4)
UNSPSC Code 41116107
NACRES NA.24

SAFETY

Risk and Safety Statements

PPE Eyeshields, Gloves
Safety Statements  24/25
WGK Germany  3
RTECS  UD1010000
TSCA  TSCA listed
HS Code  39022000
Storage Class 10 - Combustible liquids
Hazardous Substances Data 9003-27-4(Hazardous Substances Data)

Polyisobutylene price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 181455 Polyisobutylene average Mw ~500,000, average Mn ~200,000 by GPC/MALLS, average Mv ~420,000 9003-27-4 100g $214 2026-04-30 Buy
Sigma-Aldrich 1546966 Polyisobutylene United States Pharmacopeia (USP) Reference Standard 9003-27-4 1g $381 2026-04-30 Buy
Biosynth FP168349 Polyisobutylene 9003-27-4 2kg $900 2026-06-04 Buy
Biosynth FP168349 Polyisobutylene 9003-27-4 1kg $900 2026-06-04 Buy
Biosynth FP168349 Polyisobutylene 9003-27-4 0.5kg $900 2026-06-04 Buy
Product number Packaging Price Buy
181455 100g $214 Buy
1546966 1g $381 Buy
FP168349 2kg $900 Buy
FP168349 1kg $900 Buy
FP168349 0.5kg $900 Buy

Polyisobutylene Chemical Properties,Uses,Production

Chemical Properties

Polyisobutylene is composed of long-chain hydrocarbon formed by polymerization of isobutene, and is extremely stable under normal conditions. It is transparent non-noxious high-consistency semi-solid polymer free of impurities.

Chemical Properties

The physical properties of polyisobutene are very dependent on molecular weight. Polymers with average molecular weight (Mw) of about 15 000 are sticky viscous liquids whilst those with molecular weight of 100000-200000 are rubber-like, resembling unmilled crepe rubber.
Polyisobutene is non-crystalline when unstretched and is therefore soluble at room temperature in hydrocarbons and halogenated hydrocarbons. The material is resistant to most acids, alkalis and aqueous solutions, as would be expected from its saturated hydrocarbon structure and absence of tertiary hydrogen atoms. The lack of tertiary hydrogen atoms renders polyisobutene more resistant to oxidation than polypropylene; also, the less numerous and partially shielded methylene groups in polyisobutene are less reactive than those in polyethylene. However, polyisobutene is rather susceptible to thermal degradation since chain scission is favoured by the greater stability of the resultant tertiary free radical:
free radical of PolyisobutylenePolyisobutene may be chlorinated but the reaction is accompanied by severe degradation.
A limitation of polyisobutene is its tendency to cold flow and, as a result, the polymer finds little use in self-supporting form. Applications are restricted mainly to adhesives, fabric and paper coatings, and blends with other polymers. Low molecular weight polyisobutene is also used in caulking compounds.

Uses

polyisobutene (hydrogenated) is an emollient.
Polyisobutylene, sometimes called butyl rubber, and other times PIB, is a vinyl polymer. It's very similar to polyethylene and polypropylene in structure, except that every other carbon is substituted with two methyl groups. It is made from the monomer isobutylene, by cationic vinyl polymerization.
Polyisobutylene is a synthetic rubber, or elastomer. It's special because it's the only rubber that's gas impermeable. That is, it's the only rubber that can hold air for long periods of time. You may have noticed that balloons will go flat after a few days. This is because they are made of polyisoprene, which is not gas impermeable. Because polyisobutylene will hold air, it is used to make things like the inner tubes, liner layers of tires, and the inner liners of basketballs.

Preparation

Silicone rubbers are prepared as follows:
Preparation of Silicone rubbers
Other groups may replace the methyl groups. Silicone rubbers have excellent ozone and weathering resistance, good electrical properties, and good adhesion to metal.

Definition

ChEBI: A polymer composed of repeating 1,1-dimethylethylene units. 2-methylprop-1-ene (1,1-Dimethylethylene) is an alkene that is prop-1-ene substituted by a methyl group at position 2. It is an alkene and a gas molecular entity.

Application

Polyisobutylene (PIB) is a vinyl polymer with a uniquely low water diffusion rate and low glass transition temperature (Tg) (-75 °C). It is widely available for use in the following ways:
(1) PIB can be used as a common encapsulation material for photovoltaic modules.
(2) Chemically inert elastomers with oxidation and thermal degradation resistance and low gas permeability.
(3) Plasticisers in rubber formulations and sporting goods (e.g. golf clubs, tennis rackets, grips for bicycles and tools).
(4) Adhesive compositions used as wound dressings where PIB acts as a tackifier.
(5) Functionalisation of polyisobutylene with pyrene by photoinduced radical addition of 1-bromomethylpyrene in the presence of Mn2(CO)10 during the preparation of polyisobutylene-based block copolymers.
(6) Highly reactive polyisobutylene (HRPIB) is the most important industrial polymer material used as a lubricant, fuel and polymer additive. In contrast to conventional Polyisobutylene, HRPIB is a polymer using olefins as end groups.

Solubility in organics

non-polar organic solvents (i.e. aliphatic, aromatic, cyclic and halogenated hydrocarbons), THF

Polyisobutylene Preparation Products And Raw materials

Global( 292)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Chuanghai Biotechnology Co., Ltd
+8615350571055 Sibel@chuanghaibio.com China 8738 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3692 58
Hebei Zhuanglai Chemical Trading Co Ltd
+86-16264648883 niki@zlchemi.com China 7245 58
Shijiazhuang Byine Trading Co.,ltd
19350938084 mark@sjzbyine.com China 265 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-86-13131129325 +8613131129325 sales1@chuanghaibio.com China 5220 58
Anhui Ruihan Technology Co., Ltd
+8617756083858 daisy@anhuiruihan.com China 973 58
Hebei Jingbo New Material Technology Co., Ltd
+8619931165850 hbjbtech@163.com China 1000 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20120 58
Yujiang Chemical (Shandong) Co.,Ltd.
+8617736087130 catherine@yjchem.com.cn China 994 58
Hebei Longbang Technology Co., LTD
+86-18633929156 admin@hblongbang.com China 972 58

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View Lastest Price from Polyisobutylene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Polyisobutylene pictures 2026-07-27 Polyisobutylene
9003-27-4
0.99 RongNa Biotechnology Co.,Ltd
Polyisobutylene pictures 2026-07-09 Polyisobutylene
9003-27-4
$1.00-50.00 1KG 99% Henan Fengda Chemical Co., Ltd
Polyisobutylene pictures 2026-07-06 Polyisobutylene
9003-27-4
1kg 98% 1000kg Shaanxi Dideu New Materials Co. Ltd
isobutenehomopolymer isobutenepolymer isobutylenehomopolymer POLYISOBUTYLENE(C12-C20) maxvis2000 napvis30 oktol oppanolb oppanolb15 oppanolb150 oppanolb200 oppanolb3 paratac paxon3204 pb150 pib100 poly(2-methylpropene) polyisobutylenepsg polyvis06sh polyvis150sh polyvis200sh POLY(ISOBUTYLENE) 390 POLY(ISOBUTYLENE) 4'400 POLY(ISOBUTYLENE) 583'000 POLY(ISOBUTYLENE) 680 POLY(ISOBUTYLENE) 73'000 POLY(ISOBUTYLENE) 856'000 POLY(ISOBUTYLENE) 86'000 1-Propene,2-methyl-,homopolymer 2-methyl-1-propenhomopolymer 2-methylpropenepolymer 2-methyl-propenpolymers amoco600 hyvis200 kp5 polyvis30sh psb(aliphaticpolymer) Vistanex (b-100) POLY(ISOBUTYLENE), CA. M.W.400.000 POLY(ISOBUTYLENE), CA. M.W. 840.000 100G Poly(isobutylene), ca. MW. 4.700.000 Poly(isobutylene), ca. MW. 2.800 Poly(isobutylene), ca. MW. 1.700.000 Poly(isobutylene)ca. M.W. 840.000 Poly(isobutylene),ca. M.W. 700.000 Poly(isobutylene),ca. M.W. 85.000 Polyisobutylene (1 g) Polyisobutylene (PIB) Polyisobutylene high viscosity Polyisobutylene medium viscosity Polyisobutylene low viscosity ISO-BUTYLENE RESIN POLYISOBUTYLENE POLY(ISOBUTYLENE) 10'000 POLY(ISOBUTYLENE) 134'000 POLY(ISOBUTYLENE) 2'500 POLY(ISOBUTYLENE) 302'000 POLY(ISOBUTYLENE) 34'000
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