ChemicalBook >> CAS DataBase List >>((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE structure

CAS No.: 192139-92-7

Chemical Name:: ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

Synonyms: RuCL;TsDPEN;RuCl(p-cymene)[(R,R)-Ts-DPEN];RuCl[(R,R)-Tsdpen](p-cymene);RuCl(R,R)-Tsdpen;Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II);Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene);(R,R)-N-;R)-2-AMINO-1;[(R,R)-Tsdpen](p-cymene)

CBNumber:: CB81564668

Molecular Formula:: C21H21ClN2O2RuS.C10H14

Molecular Weight:: 636.219

MDL Number:: MFCD10567385

MOL File:: 192139-92-7.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 05:02:08

Product description	Number	Pack Size	Price
RuCl(p-cymene)[(R,R)-Ts-DPEN]	930008	250MG	$74.2
RuCl(p-cymene)[(R,R)-Ts-DPEN]	930008	1G	$189
RuCl(p-cymene)[(R,R)-Ts-DPEN]	703907	100mg	$31
RuCl(p-cymene)[(R,R)-Ts-DPEN]	703907	500mg	$112
RuCl[(R,R)-Tsdpen](p-cymene) >90%(HPLC)	R0125	200mg	$44
More product size

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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Properties

Melting point	215 °C
storage temp.	2-8°C
solubility	Deuterated Chloroform, DMF
form	solid
color	yellow to dark brown
optical activity	[α]20/D 116°, c = 0.1 in chloroform
Sensitive	air sensitive
InChIKey	AZFNGPAYDKGCRB-MNPNNRAMNA-M
SMILES	C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C \|&1:6,13,r\|
UNSPSC Code	12352116
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H335

Precautionary statements

P261-P280-P301+P312-P302+P352-P305+P351+P338

PPE

Eyeshields, Gloves, type N95 (US)

WGK Germany

HS Code

28439000

Storage Class

11 - Combustible Solids

NFPA 704

	1
2		0

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE price More Price(61)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	930008	RuCl(p-cymene)[(R,R)-Ts-DPEN]	192139-92-7	250MG	$74.2	2026-04-30	Buy
Sigma-Aldrich	930008	RuCl(p-cymene)[(R,R)-Ts-DPEN]	192139-92-7	1G	$189	2026-04-30	Buy
Sigma-Aldrich	703907	RuCl(p-cymene)[(R,R)-Ts-DPEN]	192139-92-7	100mg	$31	2026-04-30	Buy
Sigma-Aldrich	703907	RuCl(p-cymene)[(R,R)-Ts-DPEN]	192139-92-7	500mg	$112	2026-04-30	Buy
TCI Chemical	R0125	RuCl[(R,R)-Tsdpen](p-cymene) >90%(HPLC)	192139-92-7	200mg	$44	2026-04-30	Buy

Product number	Packaging	Price	Buy
930008	250MG	$74.2	Buy
930008	1G	$189	Buy
703907	100mg	$31	Buy
703907	500mg	$112	Buy
R0125	200mg	$44	Buy

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chemical Properties,Uses,Production

Reaction

This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester. Reactions of 192139-92-7

Chemical Properties

Orange to brown powder

Uses

Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:

Quinolines
N-Alkyl ketimines
Antitumor and antiproliferative derivatives of natural products isolated from bacteria
Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation

Catalyst with improved performance modified via microenvironment engineering of nanocages

General Description

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.

Synthesis

In a dry reactor, ruthenium chloride catalyst ( 167 mg , 0.273 mmol), mono-p-toluenesulfonic acid diamine ( 0.546 mmol), and triethylamine ( 155 L , 1.11 mmol) were dissolved in dry isopropanol ( 5.5 m L ), and then the resulting reaction mixture was heated to 80 C and reacted with stirring at 80 C for 75 minutes. At the end of the reaction the resulting reaction solution was cooled to room temperature. The resulting solution was concentrated to half its volume under reduced pressure, and then 1.5 mL of deionized water was added to the resulting reaction mixture to precipitate the catalyst. The resulting precipitate was collected by filtration and dried under vacuum to afford the target catalyst (R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethane diamine (p-isopropylphenyl)ruthenium chloride.

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Suppliers

Global( 191)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hangzhou ICH Biofarm Co., Ltd	+86-0571-28186870; +undefined8613073685410	sales@ichemie.com	China	1006	58
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +86-16627710726	sales@runvmat.com	China	462	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	+86-15225627621 +86-13213167925	jiuyitime@fdachem.com	China	16511	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29640	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-2158073036	info@dakenam.com	China	14026	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21585	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29812	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10403	58
Accela ChemBio Inc.	+1-858-6993322 +86-18019713315	info@accelachem.com	United States	21193	58

Supplier	Advantage
Hangzhou ICH Biofarm Co., Ltd	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Shenzhen Nexconn Pharmatechs Ltd	58
Accela ChemBio Inc.	58

View Lastest Price from ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-07-02	RuCl(p-cymene)[(R,R)-Ts-DPEN] 192139-92-7	$2.00-5.00	1kg	99%	100kg	ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
2026-06-30	((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE 192139-92-7		1kg	99%	10000KGS	Shaanxi Dideu New Materials Co. Ltd
2026-01-04	RuCl[(R,R)-Tsdpen](p-cymene) 192139-92-7		1kg	99.0%min	800kg	Hangzhou ICH Biofarm Co., Ltd

RuCl(p-cymene)[(R,R)-Ts-DPEN]
192139-92-7
$2.00-5.00
99%
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
192139-92-7
$0.00
99%
Shaanxi Dideu New Materials Co. Ltd

RuCl[(R,R)-Tsdpen](p-cymene)
192139-92-7
99.0%min
Hangzhou ICH Biofarm Co., Ltd

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Spectrum

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE(192139-92-7)¹HNMR

192139-92-7(((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE)Related Search:

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl[(S,S)-FsDPEN](p-cymene) Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene) tBuXPhos Pd G1 (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)

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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene) ((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene) RutheniuM,[N-[(1R,2R)-2-(aMino-kN)-1,2-diphenylethyl]-4-MethylbenzenesulfonaMidato-kN]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]- [((R,R)-2-AMino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]aMido](chloro)(η6-p-cyMene)rutheniuM (R,R)-N- ((R,r)-2-amino-1,2-diphenylethy)[(4-tolyl)sulfonyl]amido](pcymene)ruthenium(II)chloride (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro [(1R,2R)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p... R)-2-AMINO-1 2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE (1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide [N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl- [RuCl(η6-p-cymene)(N-tosyl-1,2-diphenylethylenediamine)] RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) Ruthenium,[N-[(1R,2R)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,98% [(R,R)-Tsdpen](p-cymene) Ruthenium, [N-[(1R,2R)-2-(amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]- [(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II) Chloro(p-cymene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II) ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE ISO 9001：2015 REACH RuCl (cymene)[(R,R)-TsDPEN] [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II) 192139-92-7 [(1R,2R)-2-amiNA-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide RuCl[(R,R)-Tsdpen](p-cymene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY RuCl(p-cymene)[(R,R)-Ts-DPEN] [(1R,2R)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide 1-isopropyl-4-methyl-benzene ruthenium(2+) chloride Ru(II)Cl(p-cymene)[(R,R)-TsDPEN] RuCl(p-cymene)[(R,R)-Ts-DPEN]/(R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(p-cyMene)RutheniuM(II)chloride Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) RuCl(R,R)-Tsdpen RuCl(p-cymene)[(R,R)-Ts-DPEN] RuCl[(R,R)-Tsdpen](p-cymene) RuCL TsDPEN 192139-92-7 C31H35ClN2O2RuS Ru organometallic complex

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