4-Acetylphenylboronic acid
- CAS No.
- 149104-90-5
- Chemical Name:
- 4-Acetylphenylboronic acid
- Synonyms
- AKOS BRN-0001;TIMTEC-BB SBB000146;RARECHEM AH PB 0162;4-Boronoacetophenone;4-Acetylphenylboroni;4-Acetylphenylboronic;Acetylphenylboronic acid;4-Acetylphenylboronicaci;4-ACETYLPHENYLBORONIC ACID;P-ACETYLPHENYLBORONIC ACID
- CBNumber:
- CB8260446
- Molecular Formula:
- C8H9BO3
- Molecular Weight:
- 163.97
- MDL Number:
- MFCD01074667
- MOL File:
- 149104-90-5.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 4-Acetylphenylboronic acid 95% | 470821 | 5g | $70.8 |
| 4-Acetylphenylboronic acid 95% | 470821 | 25g | $331 |
| 4-Acetylphenylboronic Acid (contains varying amounts of Anhydride) | A1907 | 1g | $24 |
| 4-Acetylphenylboronic Acid (contains varying amounts of Anhydride) | A1907 | 5g | $66 |
| 4-Acetylphenylboronic Acid | TRC-A188840-5G | 5g | $76 |
| More product size | |||
| Melting point | 240-244 °C(lit.) |
|---|---|
| Boiling point | 354.2±44.0 °C(Predicted) |
| Density | 1.19±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | DMSO (Slightly), Methanol (Slightly) |
| form | Crystalline Powder |
| pka | 7.58±0.10(Predicted) |
| color | Pale yellow to yellow |
| Water Solubility | 25 g/L |
| BRN | 7869162 |
| InChI | 1S/C8H9BO3/c1-6(10)7-2-4-8(5-3-7)9(11)12/h2-5,11-12H,1H3 |
| InChIKey | OBQRODBYVNIZJU-UHFFFAOYSA-N |
| SMILES | CC(=O)c1ccc(cc1)B(O)O |
| CAS DataBase Reference | 149104-90-5(CAS DataBase Reference) |
| UNSPSC Code | 12352103 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| target organs | Respiratory system | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant/Keep Cold | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29310095 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|||||||||
| NFPA 704 |
|
4-Acetylphenylboronic acid price More Price(99)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 470821 | 4-Acetylphenylboronic acid 95% | 149104-90-5 | 5g | $70.8 | 2026-04-30 | Buy |
| Sigma-Aldrich | 470821 | 4-Acetylphenylboronic acid 95% | 149104-90-5 | 25g | $331 | 2026-04-30 | Buy |
| TCI Chemical | A1907 | 4-Acetylphenylboronic Acid (contains varying amounts of Anhydride) | 149104-90-5 | 1g | $24 | 2026-04-30 | Buy |
| TCI Chemical | A1907 | 4-Acetylphenylboronic Acid (contains varying amounts of Anhydride) | 149104-90-5 | 5g | $66 | 2026-04-30 | Buy |
| TRC | TRC-A188840-5G | 4-Acetylphenylboronic Acid | 149104-90-5 | 5g | $76 | 2026-06-03 | Buy |
4-Acetylphenylboronic acid Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powder
Uses
4-Acetylphenylboronic acid4-Acetylphenylboronic Acid is used in several metal catalyzed cross-coupling reaction studies.
Uses
Reactant involved in:
- Palladium-catalyzed decarboxylative coupling
- Copper-catalyzed hydroxylation
- Palladium-catalyzed Suzuki-Miyaura cross-coupling
- Cross-coupling with α-bromocarbonyl compounds
- Oxidation catalyzed by Baeyer-Villiger monooxygenases
- 1,5-substitution reactions
Uses
suzuki reaction
General Description
4-Acetylphenylboronic acid is a boronate, belongs to a class of synthetic organic compounds. It reacts rapidly with peroxynitrite (ONOO(-)) to form stable hydroxy derivatives. It undergoes Suzuki coupling with 4-bromotriphenylamine catalyzed by dichlorobis(triphenylphosphine)Pd(II), during the synthesis of dendrimers.
Synthesis
1173922-30-9
1351956-00-7
149104-90-5
The general procedure for the synthesis of (R)-1-(4-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)ethan-1-ol and 4-acetylphenylboronic acid from 1-(4-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)ethan-1-ol was carried out in the following manner: under aseptic conditions, the appropriate racemic alcohol ( 0.5 mmol) was dissolved in dimethylformamide (2 mL) and added to a 500 mL conical flask containing 8.2 g of wet cells (resuspended in 100 mL of phosphate buffer, pH 7.0, 100 mmol/L). The reaction was carried out at 20°C and 400 rpm for 120 hours. After completion of the reaction, the reaction mixture was extracted for 24 h using a continuous liquid-liquid extractor and dichloromethane (300 mL). The organic layer was dried with anhydrous magnesium sulfate followed by evaporation of the solvent under reduced pressure. The crude product was purified by column chromatography using hexane/ethyl acetate as eluent.
References
[1] Journal of Molecular Catalysis B: Enzymatic, 2014, vol. 110, p. 117 - 125
4-Acetylphenylboronic acid Preparation Products And Raw materials
Raw materials
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Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29640 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 33024 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29815 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49979 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8828 | 58 |
| Tianjin Xinshengjiahe Science & Technology Development Co,.Ltd | +86-86-22-87899925 +86-8618522618860 | 18522618860@163.com | China | 694 | 58 |
| SIMAGCHEM CORP | +86-5922680277 +86-13806087780 | sale@simagchem.com | China | 17346 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30225 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 8741 | 58 |
View Lastest Price from 4-Acetylphenylboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2021-07-13 | 4-Acetylphenylboronic acid
149104-90-5
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
 |
2021-07-10 | 4-Acetylphenylboronic acid
149104-90-5
|
$10.00-15.00 | 1KG | 99%+ HPLC | Zhuozhou Wenxi import and Export Co., Ltd | ||
 |
2019-07-06 | 4-Acetylphenylboronic acid
149104-90-5
|
$8.00 | 1kg | 99% | 10MT | Career Henan Chemical Co |
-
- 4-Acetylphenylboronic acid
149104-90-5
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- 4-Acetylphenylboronic acid
149104-90-5
- $10.00-15.00
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
-
- 4-Acetylphenylboronic acid
149104-90-5
- $8.00
- 99%
- Career Henan Chemical Co
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