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ChemicalBook >> CAS DataBase List >>Sodium acrylate

Sodium acrylate

CAS No.
7446-81-3
Chemical Name:
Sodium acrylate
Synonyms
ACRYLIC ACID, SODIUM SALT;Sodium 2-propenoate;DK884;Sodium acryL;SODIUM ACRYLATE;Sodium propenoate;SodiuM acrylate 97%;propyleneacidsodium;Sodium acrylate(~white);Sodium acrylate(~yellow)
CBNumber:
CB9343487
Molecular Formula:
C3H3NaO2
Molecular Weight:
94.04
MDL Number:
MFCD00067207
MOL File:
7446-81-3.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 05:25:13
Product description Number Pack Size Price
Sodium acrylate 97% 408220 25g $98
Sodium acrylate 97% 408220 100g $288
Sodium acrylate FS33461 0.025kg $247.37
Sodium acrylate FS33461 0.05kg $412.28
Sodium acrylate FS33461 0.1kg $577.97
More product size

Sodium acrylate Properties

Melting point >300 °C (lit.)
Density 1.528[at 20℃]
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Aqueous Acid (Slightly), Methanol (Slightly), Water (Slightly)
form Solid
color White to Off-White
Water Solubility 479g/L at 20℃
Hydrolytic Sensitivity 0: forms stable aqueous solutions
Stability May be unstable; may spontaneously polymerize. Incompatible with strong oxidizing agents.
InChI InChI=1S/C3H4O2.Na/c1-2-3(4)5;/h2H,1H2,(H,4,5);/q;+1/p-1
InChIKey NNMHYFLPFNGQFZ-UHFFFAOYSA-M
SMILES C([O-])(=O)C=C.[Na+]
LogP 0.46 at 25℃
CAS DataBase Reference 7446-81-3(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 7C98FKB43H
EPA Substance Registry System Sodium acrylate (7446-81-3)
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Environment (GHS09)
GHS09
Signal word  Warning
Hazard statements  H400
Precautionary statements  P273-P391-P501
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
TSCA  TSCA listed
HS Code  29161100
Storage Class 11 - Combustible Solids
Hazard Classifications Aquatic Acute 1
Hazardous Substances Data 7446-81-3(Hazardous Substances Data)
REACH Registrations Active
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)

Sodium acrylate price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 408220 Sodium acrylate 97% 7446-81-3 25g $98 2026-04-30 Buy
Sigma-Aldrich 408220 Sodium acrylate 97% 7446-81-3 100g $288 2026-04-30 Buy
Biosynth FS33461 Sodium acrylate 7446-81-3 0.025kg $247.37 2026-06-04 Buy
Biosynth FS33461 Sodium acrylate 7446-81-3 0.05kg $412.28 2026-06-04 Buy
Biosynth FS33461 Sodium acrylate 7446-81-3 0.1kg $577.97 2026-06-04 Buy
Product number Packaging Price Buy
408220 25g $98 Buy
408220 100g $288 Buy
FS33461 0.025kg $247.37 Buy
FS33461 0.05kg $412.28 Buy
FS33461 0.1kg $577.97 Buy

Sodium acrylate Chemical Properties,Uses,Production

Chemical Properties

Colorless or light yellow viscous liquid, non-toxic, weakly alkaline, insoluble in organic solvents such as ethanol, acetone, etc., easily soluble in water and aqueous sodium hydroxide, but in aqueous solutions such as calcium hydroxide, magnesium hydroxide, etc., with the increase in the number of alkaline-earth metal ions, the first to dissolve and then precipitate.

Uses

Sodium Acrylate (SA) is a sodium salt of acrylic acid with antibacterial properties. Sodium polyacrylate is a sodium salt of a polymer consisting of acrylic acid, methacrylic acid or one of their simple esters. SA can be used in tuning the grain size of iron oxide microparticles for potential applications in biological assaying and in chemical sensors. Additionally, it acts as a reducing and capping agent for gold nanoparticles, beneficial for various biological applications.

benefits

Sodium acrylate is the sodium salt of acrylic acid. In Skincare or personal care products, sodium acrylate is often used as an ingredient with specific properties, such as its ability to act as a thickening agent or stabilizer in formulations, contributing to the overall texture and stability of the product.
Thickening Agent:Sodium acrylate is commonly used as a thickening agent in cosmetic formulations. It helps improve the viscosity and texture of the product, giving it a smooth and luxurious feel. This is particularly important for products like creams, lotions, and gels.
Stabilizer:Sodium acrylate can contribute to the stability of formulations. It helps prevent the separation of ingredients and enhances the overall shelf life of the product. This is important for maintaining the efficacy and quality of skincare products over time.
Enhanced Spreadability:The inclusion of sodium acrylate in formulations can improve the spreadability of skincare products on the skin. This ensures even application and distribution of the product, enhancing the user experience.
Film-Forming Properties:In some formulations, sodium acrylate may have film-forming properties. This can create a thin film on the skin, providing a protective barrier and potentially helping to lock in moisture.

General Description

Sodium acrylate (SA) is a metal salt that can be prepared by an acid-base reaction between sodium hydroxide and acrylic acid. It can be used in the preparation of poly(sodium acrylate) using bulk, solution, emulsion, and suspension polymerization techniques. It results in the formation of a water soluble polymer that can be used in a variety of industries and personal care applications.

Flammability and Explosibility

Non flammable

Synthesis

An aqueous solution of sodium acrylate is prepared from 216.2 g of acrylic acid (100%=3 mol), 262.8 g of NaOH (50%) and 497 g of water. 3.7 g of N-nitrosodiphenylamine and 3.7 g of 4-methoxyphenol are added to stabilize the solution. 12 g of the quaternary ammonium salt used in Example 1 are also added. 1,125 g (9 mol) of 1,4-dichlorobutene are run in at 90° C. 15.9 g of Na2CO3 are added after 1 hour and the mixture is left to react for a further 2 hours at 90° C. After phase separation, the organic layer is distilled under vacuum. 286.0 g (1.78 mol) of 4-chloro-2-butenyl acrylate (59.4% of the theoretical yield) are obtained. 641 g (5.13 mol) of dichlorobutene are recovered.

References

[1] SIMONE MANZINI . Palladium- and Nickel-Catalyzed Synthesis of Sodium Acrylate from Ethylene, CO2, and Phenolate Bases: Optimization of the Catalytic System for a Potential Process[J]. European Journal of Organic Chemistry, 2015, 2015 32: Pages 7122-7130. DOI:10.1002/ejoc.201501113.
[2] KALRA B, GROSS R A. HRP-mediated polymerizations of acrylamide and sodium acrylate[J]. Green Chemistry, 2002, 2: 174-178. DOI:10.1039/B106735B.
[3] https://www.ewg.org/skindeep/ingredients/705976-SODIUM_ACRYLATES_COPOLYMER/

79-10-7
7446-81-3
Synthesis of Sodium acrylate from Acrylic acid
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