2-Bromo-3-methylaniline
- CAS No.
- 54879-20-8
- Chemical Name:
- 2-Bromo-3-methylaniline
- Synonyms
- 3-Amino-2-bromotoluene;2-BROMO-3-METHYLANILIN;2-BROMO-3-METHYLANILINE;2-broMo-3-MethylbenzenaMine;2-BROMO-3-METHYLANILINE 98;2-BroMo-3-Methylaniline, 97+%;BenzenaMine, 2-broMo-3-Methyl-;2-Bromo-3-methylaniline 95%min;methyl 2-((2-aminophenyl)thio)acetate;2-Bromo-3-methylaniline, 98%, for synthesis
- CBNumber:
- CB9498840
- Molecular Formula:
- C7H8BrN
- Molecular Weight:
- 186.05
- MDL Number:
- MFCD06411367
- MOL File:
- 54879-20-8.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Product description | Number | Pack Size | Price |
| 2-Bromo-3-methylaniline 98% | 645621 | 5g | $388 |
| 2-Bromo-3-methylaniline Asreported | 266453 | 500mg | $333 |
| 2-Bromo-3-methylaniline Asreported | 266453 | 1g | $470 |
| 2-Bromo-3-methylaniline Asreported | 266453 | 2g | $632 |
| 2-Bromo-3-methylaniline Asreported | 266453 | 5g | $848 |
| More product size | |||
| Boiling point | 48 °C/0.03 mmHg (lit.) |
|---|---|
| Density | 1.489 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| form | Liquid |
| pka | 2.66±0.10(Predicted) |
| color | Pale brown |
| InChI | InChI=1S/C7H8BrN/c1-5-3-2-4-6(9)7(5)8/h2-4H,9H2,1H3 |
| InChIKey | VJNUZLYTGSGDHR-UHFFFAOYSA-N |
| SMILES | C1(N)=CC=CC(C)=C1Br |
| UNSPSC Code | 12352100 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H317 | |||||||||
| Precautionary statements | P280-P301+P312+P330-P302+P352 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Faceshields, Gloves | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 22-43-36/37/38-20/21/22 | |||||||||
| Safety Statements | 36/37-60-26-23-9 | |||||||||
| RIDADR | 2810 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 6.1 | |||||||||
| HS Code | 29214300 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| Hazard Classifications | Acute Tox. 4 Oral Skin Sens. 1 |
|||||||||
| NFPA 704 |
|
2-Bromo-3-methylaniline price More Price(63)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 645621 | 2-Bromo-3-methylaniline 98% | 54879-20-8 | 5g | $388 | 2023-06-20 | Buy |
| Usbiological | 266453 | 2-Bromo-3-methylaniline Asreported | 54879-20-8 | 500mg | $333 | 2026-06-03 | Buy |
| Usbiological | 266453 | 2-Bromo-3-methylaniline Asreported | 54879-20-8 | 1g | $470 | 2026-06-03 | Buy |
| Usbiological | 266453 | 2-Bromo-3-methylaniline Asreported | 54879-20-8 | 2g | $632 | 2026-06-03 | Buy |
| Usbiological | 266453 | 2-Bromo-3-methylaniline Asreported | 54879-20-8 | 5g | $848 | 2026-06-03 | Buy |
2-Bromo-3-methylaniline Chemical Properties,Uses,Production
Synthesis
Add iron powder (3.86 g, 69 mmol), water (5 mL) and concentrated HCL (0.5 mL) sequentially to a solution of commercially available 2-bromo-3-nitrotoluene (5 g, 23 mmol) in methanol (100 mL) at room temperature and heat the mixture at reflux for 125 h. Remove the solvents under reduced pressure, suspend the residue in water (400 mL) and extract with chloroform (3 x 250 mL). Dry the combined organic extracts over MGS04 and remove the solvents under reduced pressure to afford 2-bromo-3-methylphenylamine as an amber oil (4.45 g, 100percent): 1H NMR (CDC13) 5 2.30 (s, 3H), 4.00 (br s, 2H), 7.60 (m, 2H), 7.00 (t, 1H).
References
[1] Patent: WO2004/63155, 2004, A1. Location in patent: Page 120-121
[2] Journal of Organic Chemistry, 1988, vol. 53, # 6, p. 1170 - 1176
[3] Angewandte Chemie - International Edition, 2018, vol. 57, # 34, p. 11040 - 11044
[4] Angew. Chem., 2018, vol. 130, # 34, p. 11206 - 11210,5
[5] Angewandte Chemie - International Edition, 2010, vol. 49, # 40, p. 7257 - 7260
2-Bromo-3-methylaniline Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29626 | 60 |
| Fluoropharm Co., Ltd. | +86-0571-85586753 +86-13336034509 | sales@fluoropharm.com | China | 1444 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32998 | 60 |
| Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
| Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | 52513593@qq.com | CHINA | 2971 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 +86-18019713315 | info@accelachem.com | United States | 21189 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63645 | 58 |
| CONIER CHEM AND PHARMA LIMITED | sales@conier.com | China | 49906 | 58 | |
| career henan chemical co | +86-0371-86658258 | factory@coreychem.com | China | 29780 | 58 |
| Fuxin Pharmaceutical | +86-021-021-50872116 | contact@fuxinpharm.com | China | 9976 | 58 |
View Lastest Price from 2-Bromo-3-methylaniline manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-11-18 | 2-BROMO-3-METHYLANILINE 98
54879-20-8
|
$1.10 | 1g | 99.00% | 100 Tons Min | Dideu Industries Group Limited | |
 |
2020-01-09 | 2-BROMO-3-METHYLANILINE 98
54879-20-8
|
$1.00 | 1KG | 98% HPLC | 10 tons/month | Career Henan Chemical Co |
-
- 2-BROMO-3-METHYLANILINE 98
54879-20-8
- $1.10
- 99.00%
- Dideu Industries Group Limited
-
- 2-BROMO-3-METHYLANILINE 98
54879-20-8
- $1.00
- 98% HPLC
- Career Henan Chemical Co
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