二過塩素酸マグネシウム 化學特性,用途語,生産方法
外観
白色, 柱狀又は粒狀
溶解性
水に易溶。アルコールに易溶。水に極めて溶けやすく、水を加えると激しく発熱する。
用途
ガスの乾燥剤、市販品は二水塩に相當する水分を含有しているが、三水塩でもガスの乾燥に有効といわれている :(MERCK (14TH, 2006))
用途
分析ガス 乾燥剤
使用上の注意
吸濕性が強い。
説明
Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO4)2. Magnesium perchlorate decomposes at 250°C. The heat of formation is 568.90 kJ/mol. If water is added to magnesium perchlorate, the reaction is highly exothermic and may cause damage to the eyes. Thus, this salt should be added to a sufficient amount of water in order to form a dilute solution.
Mg(ClO4)2·6H2O is composed of white, deliquescent crystals which are soluble in water and alcohol but explosive when in contact with reducing materials. This compound is used as a drying agent for gases. This salt is highly exothermic when added to water and releases steamy HCl gas. It can be dried to form the anhydrate by heating to 250°C under vacuum. The hexahydrate losses two molecules of water at 244°C in air and further decomposes to the dihydrate at 336°C and the anhydrate at 438°C.
The anhydrate has been used as a desiccant to dry gas streams or air samples. However, it is no longer used since perchlorates tend to form explosive compounds with a variety of organic materials as well as other substances.
使用
Magnesium perchlorate is commonly utilized as a potent oxidizing agent. It is used as dehydrating agent in organic synthesis. It is practiced in many domains like pharma industry, pyrotechnics industry,in rechargeable batteries and it is a versatile tool in organic synthesis. It possesses photoelectronic and optical properties. Thus it can be used in photo electronic and optoelectronic devices. It is applied as a strong drying agent for gases.
製造方法
Magnesium perchlorate can be prepared by reacting magnesium carbonate with
a solution of perchloric acid:
MgCO3＋ HClO4→Mg(ClO4)2＋ CO2
This salt can also be prepared by an electrochemical
method in water whereby magnesium perchlorate is formed from magnesium chlorate in which a platinum anode and a rotating stainless steel cathode are employed.
反応性
Magnesium perchlorate is a strong oxidizing agent. In aqueous solutions and in acid medium the most conspicuous reactions are those involving oxidation— characteristic of the oxidizing action of perchlorate ion, ClO4ˉ.
Thermal decomposition in the presence of a catalyst, such as manganese dioxide, yields magnesium chloride and oxygen: Mg (ClO4)2→MgCl2 + 4O2
一般的な説明
A white crystalline solid. Strongly absorbs water from air and dissolves in it. Accordingly, used as a regenerable drying agent. May explode under prolonged exposure to heat or fire.
反応プロフィール
Magnesium perchlorate is a strong oxidizing agent. Decomposes at 185-190°C [Hawley]. Noncombustible but accelerates the burning of combustible materials. If large quantities are involved in the fire or the combustible material is finely divided an explosion may result. Avoid contact with mineral acids because of the danger of explosion. In the preparation of anhydrous dimethyl sulfoxide by vacuum distillation from anhydrous Magnesium perchlorate, an explosion occurred [MCA Case History 1187, 1966]. Drying ethylene oxide with Magnesium perchlorate resulted in an explosion [NSC Newsletter. Chem. Soc. 1959]. Magnesium perchlorate used in drying hydrocarbons exploded when heated to 220°C [Ind. & Eng. News 17:70. 1939]. As soon as trimethyl phosphite contacted a small amount of Magnesium perchlorate in a flask, there was a flash and an explosion that shattered the flask [Allison 1968].
危険性
Dangerous fire and explosion risk in contact
with organic materials.
健康ハザード
Inhalation of dust irritates mucous membranes. Ingestion of large amounts may be fatal; immediate symptoms include adominal pains, nausea and vomiting, diarrhea, pallor, blueness, shortness of breath, unconsciousness. Contact with eyes or skin causes irritation.
火災危険
Behavior in Fire: Can form explosive mixture with combustible material or finely powdered metals. Increases the intensity of fires.
安全性プロファイル
Moderately toxic by intraperitoneal route. Severe slun and eye irritant. A powerful oxidner which has caused many explosions in industry. Potentially explosive reactions with alkenes (above 22OoC), ammonia, aryl hydrazine + ether, dimethyl sulfoxide + heat, ethylene oxide, fluorobutane + water, organic materials, phosphorus, trimethyl phosphate. Reacts to form explosive products with ethanol (forms ethyl perchlorate), cellulose + dinitrogen tetraoxide + oxygen (forms cellulose nitrate). Avoid contact with mineral acids, but$ fluorides, hydrocarbons. A drying agent. When heated to decomposition it emits toxic fumes of MgO and Cl-. See also MAGNESIUM COMPOUNDS and PERCHLORATES
輸送方法
UN1475 Magnesium perchlorate, Hazard Class:
5.1; Labels: 5.1-Oxidizer.
純化方法
Magnesium perchlorate (Anhydrone, Dehydrite) [10034-81-8 (anhydrous)] M 259.2, m >250o, pK2 5
不和合性
A powerful oxidizer. Violent reaction
with reducing agents; alkenes (above 220C), ammonia
gas; organic matter; ethylene oxide, finely divided or powdered metals, combustible materials, phosphorus, dimethylsulfoxide, mineral acids; wet argon; hydrazines, alcohols,
wet fluorobutane; butyl fluorides; organic materials. Forms
explosive material with ethyl alcohol. Incompatible with
many materials. Shock or heat may cause magnesium
perchlorate to explode.
二過塩素酸マグネシウム 上流と下流の製品情報
原材料
準備製品