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1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-????

1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-????
1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-???? ??? ???
?? ??:
22767-90-4
???:
1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-????
???(??):
1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-????
???:
1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-HEXANEDIONE
???(??):
AKOS B016259;AKOS MSC-0325;TIMTEC-BB SBB003587;ART-CHEM-BB B016259;PIVALOYLTRIFLUOROACETONE;Pivaloyltrifluoroacetone, PTA;Trifluoroacetylpivaloylmethane;(Trifluoroacetyl)pivaloylmethane;1,1,1-trifluoro-5,5-dimethyl-4-hexanedione;1,1,1-Trifluoro-5,5-dimethyl-2,4-hexadione
CBNumber:
CB0142656
???:
C8H11F3O2
??? ??:
196.17
MOL ??:
22767-90-4.mol
MSDS ??:
SDS

1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-???? ??

?? ?
138-141 °C (lit.)
??
1.129 g/mL at 25 °C (lit.)
???
n20/D 1.407(lit.)
???
105 °F
?? ??
Flammables area
??? ??
??
?? ?? (pKa)
6.78±0.10(Predicted)
Specific Gravity
1.129
??
Clear, colourless
BRN
1708830
InChI
1S/C8H11F3O2/c1-7(2,3)5(12)4-6(13)8(9,10)11/h4H2,1-3H3
InChIKey
BVPKYBMUQDZTJH-UHFFFAOYSA-N
SMILES
CC(C)(C)C(=O)CC(=O)C(F)(F)F
CAS ??????
22767-90-4(CAS DataBase Reference)
EPA
2,4-Hexanedione, 1,1,1-trifluoro-5,5-dimethyl- (22767-90-4)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C,F
?? ???? ?? 10
????? 16
????(UN No.) UN 1224 3/PG 3
WGK ?? 3
?? ?? ?? Flammable
TSCA TSCA listed
?? ?? 3
???? III
HS ?? 29147000
???? ??? 3 - Flammable liquids
Hazard Classifications Flam. Liq. 3
????(GHS): Flame (GHS02)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H226 ??? ?? ? ?? ??? ?? ?? 3 ??
??????:
P210 ?·???·??·????? ????? - ?? ???.
P240 ??? ????? ?? ? ??????.
P241 ?? ??? ??[???/??/??/...]?(?) ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
NFPA 704
3
2 0

1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-???? C??? ??, ??, ??

??? ??

clear colorless to yellow liquid

??

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione (TFDMHD) may be used in the synthesis of series of NNO ketoimines bearing trifluoromethyl substituents, via Schiff base condensation. It may be used in the synthesis of octahedral Werner-type cobalt(II) complexes. It was used in the preparation of D2-TFDMHD, by mixing with D2O.

?? ??

1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione (TFDMHD) is a 1,3-diketone. It forms Er(3+) complexes. These complexes shows thermally activated slow relaxation of magnetization under a zero direct-current (DC) field.

1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-???? ?? ?? ? ???

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1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-???? ?? ??

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1,1,1-TRIFLUORO-5,5-DIMETHYL-2,4-???? ?? ??:

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