3,3'-[5'-[3-(3-Pyridinyl)phenyl][1,1':3',1''-terphenyl]-3,3''-diyl]bispyridine
3,3'-[5'-[3-(3-Pyridinyl)phenyl][1,1':3',1''-terphenyl]-3,3''-diyl]bispyridine ??? ???
?? ??:
921205-03-0
???:
3,3'-[5'-[3-(3-Pyridinyl)phenyl][1,1':3',1''-terphenyl]-3,3''-diyl]bispyridine
???(??):
TmPyPB;DK7355;TM3PyPB;TMPYPB 1G;TmPyPB, 99.5%;TmPyPB 99% (HPLC);3,3'-(5'-(3-(pyridin-3-yl)p;3,3'-5'-3-(3-Pyridinyl)phenyl1,1';3',1''-terphenyl-3,3''-diylbispyridine;1,3,5-Tris[3-(3-pyridyl)phenyl]benzene
CBNumber:
CB02484745
???:
C39H27N3
??? ??:
537.65
MOL ??:
921205-03-0.mol
MSDS ??:
SDS
3,3'-[5'-[3-(3-Pyridinyl)phenyl][1,1':3',1''-terphenyl]-3,3''-diyl]bispyridine ??
???
195-200°C
?? ?
748.9±55.0 °C(Predicted)
??
1.166
?? ??
2-8°C
???
chloroform: soluble dichloromethane: soluble
??? ??
powder
?? ?? (pKa)
5.02±0.11(Predicted)
InChI
1S/C39H27N3/c1-7-28(34-13-4-16-40-25-34)19-31(10-1)37-22-38(32-11-2-8-29(20-32)35-14-5-17-41-26-35)24-39(23-37)33-12-3-9-30(21-33)36-15-6-18-42-27-36/h1-27H
InChIKey
CINYXYWQPZSTOT-UHFFFAOYSA-N
SMILES
C1(C2=CC(C3=CC=CC(C4=CC=CN=C4)=C3)=CC(C3=CC=CC(C4=CC=CN=C4)=C3)=C2)=CC=CC(C2=CC=CN=C2)=C1
??
?? ??/??
Absorption
λmax254 nm in DCM
??
?? ? ?? ??
?? ? ???? ?? (GHS)
WGK ??
3
HS ??
2933399990
???? ???
11 - Combustible Solids
????(GHS):
?? ?:
Warning
??·?? ??:
??
??·?? ??
?? ??
??
?? ?
?? ??
P- ??
H302
??? ???
?? ?? ?? - ??
?? 4
??
P264, P270, P301+P312, P330, P501
H315
??? ??? ???
????? ?? ?????
?? 2
??
P264, P280, P302+P352, P321,P332+P313, P362
H320
?? ??? ???
?? ? ?? ?? ??? ??
?? 2B
??
P264, P305+P351+P338,P337+P313
H335
?? ???? ??? ? ??
?? ???? ?? - 1? ??;???? ??
?? 3
??
??????:
P261
??·?·??·???·??·...·????? ??? ????.
P280
????/???/???/?????? ?????.
P301+P312
??? ???? ??? ????(??)? ??? ????.
P302+P352
??? ??? ??? ?? ????.
P305+P351+P338
?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
3,3'-[5'-[3-(3-Pyridinyl)phenyl][1,1':3',1''-terphenyl]-3,3''-diyl]bispyridine C??? ??, ??, ??
??
With a low-lying HOMO, high triplet energy level, and electron-deficient pyridine groups, TmPyPB is widely used as an electron-transport layer and hole-blocking layer material in organic electronic devices (such as OLEDs, OPV and perovskite solar cells).
??
Electron-transport and hole/exciton-blocking materail with high electron mobility (10
-4 -10
-3 cm
2 V
-1 s
-1 ) and high triplet energy level (2.75 eV) for highly efficient phosphorescent OLEDs application.
3,3'-[5'-[3-(3-Pyridinyl)phenyl][1,1':3',1''-terphenyl]-3,3''-diyl]bispyridine ?? ?? ? ???
???
?? ??
3,3'-[5'-[3-(3-Pyridinyl)phenyl][1,1':3',1''-terphenyl]-3,3''-diyl]bispyridine ?? ??
???( 144)?? ??
China 139
United Kingdom 1
United States 4
Global 144
3,3'-[5'-[3-(3-Pyridinyl)phenyl][1,1':3',1''-terphenyl]-3,3''-diyl]bispyridine ?? ??: