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N-METHYL-N-PHENYLCARBAMOYL CHLORIDE

N-METHYL-N-PHENYLCARBAMOYL CHLORIDE ??? ???
?? ??:
4285-42-1
???:
N-METHYL-N-PHENYLCARBAMOYL CHLORIDE
???(??):
Methyl(phenyl)carbamic chloride;NSC-165671;METHYLPHENYLCARBAMICHLORIDE;N-METHYLCARBANILOYL CHLORIDE;methylphenyl-carbamicchlorid;Methylphenylcarbamyl chloride;Methylphenylcarbamoyl chloride;Carbamicchloride,methylphenyl-;Carbaniloyl chloride, N-methyl-;Carbamoyl chloride, methylphenyl-
CBNumber:
CB0418636
???:
C8H8ClNO
??? ??:
169.61
MOL ??:
4285-42-1.mol
MSDS ??:
SDS

N-METHYL-N-PHENYLCARBAMOYL CHLORIDE ??

???
87-90 °C (lit.)
?? ?
280 °C (lit.)
??
1.1885 (rough estimate)
???
1.5430 (estimate)
?? ??
2-8°C
?? ?? (pKa)
0.06±0.50(Predicted)
InChI
1S/C8H8ClNO/c1-10(8(9)11)7-5-3-2-4-6-7/h2-6H,1H3
InChIKey
CPGWSLFYXMRNDV-UHFFFAOYSA-N
SMILES
CN(C(Cl)=O)c1ccccc1
CAS ??????
4285-42-1
EPA
Carbamic chloride, methylphenyl- (4285-42-1)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? C
?? ???? ?? 34-36/37
????? 26-27-28-36/37/39-45
????(UN No.) UN 3261 8/PG 2
WGK ?? 3
TSCA TSCA listed
HS ?? 29242998
???? ??? 8A - Combustible corrosive hazardous materials
Hazard Classifications Eye Dam. 1
Skin Corr. 1B
STOT SE 3
????(GHS): Corrosion (GHS05)Exclamation Mark (GHS07)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P260 ??·?·??·???·??·...·????? ???? ???.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

N-METHYL-N-PHENYLCARBAMOYL CHLORIDE C??? ??, ??, ??

??? ??

light yellow to light green crystalline mass or

?? ??

Solvolyses of N-methyl-N-phenylcarbamoyl chlorides in aqueous binary mixtures of acetone, ethanol, methanol and in water, D2O and 50% D2O-CH3OD were investigated. Iridium-catalyzed annulation of N-methyl-N-phenylcarbamoyl chloride with internal alkyne was reported.

??

A corrosive lachrymator. Store under dry nitrogen. Use in a fume hood.

N-METHYL-N-PHENYLCARBAMOYL CHLORIDE ?? ?? ? ???

???

?? ??


N-METHYL-N-PHENYLCARBAMOYL CHLORIDE ?? ??

???( 67)?? ??
??? ?? ??? ?? ?? ? ??
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N-METHYL-N-PHENYLCARBAMOYL CHLORIDE ?? ??:

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