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P-?????

P-?????
P-????? ??? ???
?? ??:
137-18-8
???:
P-?????
???(??):
P-?????
???:
P-XYLOQUINONE
???(??):
2,5-DIMETHYLBENZOQUINONE;2,5-Dimethylcyclohexa-2,5-diene-1,4-dione;2,5-dimethyl-4-benzoquinone;2,5-DIMETHYL-1,4-BENZOQUINONE;Floron;PHLORONE;XYLOQUINONE;Metaphlorone;P-XYLOQUINONE;2,5-XYLOQUINONE
CBNumber:
CB0437589
???:
C8H8O2
??? ??:
136.15
MOL ??:
137-18-8.mol
MSDS ??:
SDS

P-????? ??

???
123-125 °C
?? ?
69-80℃
??
1.1150 (rough estimate)
???
1.5090 (estimate)
?? ??
2-8°C
???
???: ???0.5g/10mL, ??~?? ??, ???~??
??? ??
??? ??
??
????? ????
BRN
2041348
InChI
1S/C8H8O2/c1-5-3-8(10)6(2)4-7(5)9/h3-4H,1-2H3
InChIKey
MYKLQMNSFPAPLZ-UHFFFAOYSA-N
SMILES
CC1=CC(=O)C(C)=CC1=O
CAS ??????
137-18-8
EPA
2,5-Cyclohexadiene-1,4-dione, 2,5-dimethyl- (137-18-8)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xn
?? ???? ?? 22-36/37/38
????? 26-37/39
????(UN No.) UN 2811 6.1/PG 3
WGK ?? 3
RTECS ?? DK4800000
TSCA TSCA listed
HS ?? 29146990
???? ??? 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
????(GHS): Skull and Crossbones (GHS06)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H301 ??? ??? ?? ?? ?? - ?? ?? 3 ?? P264, P270, P301+P310, P321, P330,P405, P501
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
3 0

P-????? C??? ??, ??, ??

??? ??

yellow to brown crystalline powder

??

2,5-Dimethyl-1,4-benzoquinone may be used in a key step involved in the total synthesis of ()-cyathin A3.

?? ??

2,5-Dimethyl-1,4-benzoquinone is a quinone derivative. Its reaction with jack bean urease in phosphate buffer, pH 7.8 has been studied. It is present as one of the component of defensive secretion of opilionid Acanthopachylus aculeatus. It has been investigated as inhibitor of jack bean urease in 50mM phosphate buffer, pH 7.0.

Purification Methods

Crystallise the quinone from EtOH. [Beilstein 7 IV 2090.]

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