???(2-OXO-2-????)?????
???(2-OXO-2-????)????? ??
- ?? ?
- 192-193 °C/11 mmHg (lit.)
- ??
- 1.179 g/mL at 25 °C (lit.)
- ???
- n20/D 1.513(lit.)
- ???
- >230 °F
- ??? ??
- ??? ??
- ??
- White to Yellow to Green
- InChI
- 1S/C12H17O4P/c1-3-15-17(14,16-4-2)10-12(13)11-8-6-5-7-9-11/h5-9H,3-4,10H2,1-2H3
- InChIKey
- HPEVTTNSIPGLEL-UHFFFAOYSA-N
- SMILES
- CCOP(=O)(CC(=O)c1ccccc1)OCC
- CAS ??????
- 3453-00-7
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| WGK ?? |
3 |
|
|
| HS ?? |
2931499090 |
|
|
| ???? ??? |
10 - Combustible liquids |
|
|
| ????(GHS): |
|
| ?? ?: |
Warning |
| ??·?? ??: |
| ?? |
??·?? ?? |
?? ?? |
?? |
?? ? |
?? ?? |
P- ?? |
| H302 |
??? ??? |
?? ?? ?? - ?? |
?? 4 |
?? |
|
P264, P270, P301+P312, P330, P501 |
| H315 |
??? ??? ??? |
????? ?? ????? |
?? 2 |
?? |
|
P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
?? ?? ??? ??? |
?? ? ?? ?? ??? ?? |
?? 2A |
?? |
|
P264, P280, P305+P351+P338,P337+P313P |
| H335 |
?? ???? ??? ? ?? |
?? ???? ?? - 1? ??;???? ?? |
?? 3 |
?? |
|
|
|
| ??????: |
| P261 |
??·?·??·???·??·...·????? ??? ????. |
| P301+P312 |
??? ???? ??? ????(??)? ??? ????. |
| P302+P352 |
??? ??? ??? ?? ????. |
| P304+P340 |
???? ??? ??? ?? ??? ??? ???? ?? ??? ??? ????. |
| P305+P351+P338 |
?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????. |
|
| NFPA 704 |
|
|
|
???(2-OXO-2-????)????? C??? ??, ??, ??
??
Reactant involved in:
- Asymmetric Michael addition of β-oxo phosphonates to nitro olefins
- Gem-chlorofluorination of keto phosphonates with subsequent functionalization of the products
- Cyclocondensation reactions to produce arylphosphonates
- Diazo transfer reactions for synthesis of diazo-phosphonyl compounds
- Horner-Wadsworth-Emmons reactions
- Inverse-electron-demand Diels-Alder reactions
Synthesis Reference(s)
Synthetic Communications, 26, p. 2561, 1996
DOI: 10.1080/00397919608004568
???(2-OXO-2-????)????? ?? ?? ? ???
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???(2-OXO-2-????)????? ?? ??
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???(2-OXO-2-????)????? ?? ??:
