ChemicalBook >?? ???? >4-????????????

4-????????????

4-???????????? ??? ???

?? ??:: 3544-25-0

???:: 4-????????????

???(??):: 4-????????????;4-???????????

???:: 4-Aminophenylacetonitrile

???(??):: 4-AMINOBENZYL CYANIDE;2-(4-AMINOPHENYL)ACETONITRILE;aminophenylacetonitrile;AKOS 220-20;TIMTEC-BB SBB004218;4-AMinophenylacetoni;P-AMINOBENZYL CYANIDE;4-(Cyanomethyl)aniline;Paraphenyl acetonitrile;p-aminophenacetonitrile

CBNumber:: CB0778671

???:: C8H8N2

??? ??:: 132.16

MOL ??:: 3544-25-0.mol

MSDS ??:: SDS

MSDS

?? ?? 373

4-???????????? ??

???: 45-48 °C(lit.)

?? ?: 312 °C(lit.)

??: 1.4747 (rough estimate)

???: 1.6231 (estimate)

???: >230 °F

?? ??: Keep in dark place,Inert atmosphere,Room temperature

???: ???? ???

?? ?? (pKa): 4.25±0.10(Predicted)

??? ??: ??? ??, ?? ?? ???

??: ????? ????

???: ?? ???

BRN: 1100108

?? ??: NIOSH: IDLH 25 mg/m3

InChI: 1S/C8H8N2/c9-6-5-7-1-3-8(10)4-2-7/h1-4H,5,10H2

InChIKey: YCWRFIYBUQBHJI-UHFFFAOYSA-N

SMILES: Nc1ccc(CC#N)cc1

CAS ??????: 3544-25-0(CAS DataBase Reference)

NIST: 4-Aminophenylacetic acid nitrile(3544-25-0)

?? ? ?? ??

??? ??	Xn
?? ???? ??	20/21/22
?????	36-36/37
????(UN No.)	3276
WGK ??	3
?? ?? ??	Harmful
?? ??	6.1
????	III
HS ??	29269095
???? ???	11 - Combustible Solids
Hazard Classifications	Acute Tox. 4 Oral
???? ??	KE-01535 KE-01534

????(GHS):

?? ?:

Warning

??·?? ??:

??	??·?? ??	?? ??	??	?? ?	?? ??	P- ??

??????:

P261	??·?·??·???·??·...·????? ??? ????.
P264	?? ??? ?? ??? ????.
P264	?? ??? ?? ??? ????.
P280	????/???/???/?????? ?????.
P301+P312	??? ???? ??? ????(??)? ??? ????.

NFPA 704

	1
2		0

4-???????????? MSDS

4-Aminophenylacetonitrile

4-???????????? C??? ??, ??, ??

??? ??

yellow to brown crystalline powder, crystals

Synthesis Reference(s)

Synthetic Communications, 22, p. 3189, 1992 DOI: 10.1080/00397919208021132

Synthesis

P-Nitrophenylacetonitrile (10 g, 61.67 mmol) was dissolved in methanol (50 mL). Add 10 per cent Pd/C (1.0g), Replace the reaction system four times with H2, and Stir at room temperature overnight in an H2 environment (0.5 MPa).TLC analysis, the reaction was complete, and the reaction solution was filtered through celite. The filtrate was concentrated under reduced pressure to give 8.08g of 4-Aminophenylacetonitrile; the yield was 99.1 per cent.

4-???????????? ?? ?? ? ???

???

p-Nitrophenylacetonitrile ??? ?? ??? ???? ??

?? ??

4-???????????? 4-?????????????? 1-(CHLOROMETHYL)-3,5-BIS(METHYLSULFONYL)BENZENE 6-???????????,2-???-(9CI) Benzyl N-[4-(cyanomethyl)phenyl]carbamate (4-amino-3,5-dichlorophenyl)acetonitrile 4-(1H-????-5-???)??? 2-CHLORO-N-[4-(?????)??]?????? (4-???-3-???-??)-?????? (4-hydrazinophenyl)acetonitrile 4-(N-BOC-AMinophenyl)acetonitrile

4-???????????? ?? ??

???( 373)?? ??

???	??	???	??	?? ?	??
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4-???????????? ?? ??:

3H-??-3-?, 2-(1,3-??????-3-??-2H-??-2-???)-1,2-??????-(??? ??) 4-Aminosalicylic acid p-Aminobenzamide Sodium 4-aminosalicylate 4-Aminophenol 4-Aminobenzoic acid Sulfanilic acid Cupric acetate monohydrate Dichloromethane 1-(CHLOROMETHYL)-3,5-BIS(METHYLSULFONYL)BENZENE Cyclopentane Glucosamine 4-Aminophenylacetic acid 2-(4-Aminophenyl)ethylamine Sulfanilamide 2-PHENYLGLYCINONITRILE HYDROCHLORIDE 2-PHENYLGLYCINONITRILE HYDROCHLORIDE 2-Aminobenzyl cyanide

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