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?? ??:
13517-00-5
???:
??(I)??????
???(??):
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???:
COPPER(I)HYDRIDE
???(??):
(BDP)Cu(H);Copper hydride;COPPER(I)HYDRIDE;Hydridecopper(I);copper monohydride;Cuprous hydride - in toluene;Copper hydride (CuH) solution ;Copper hydride (CuH) solution in toluene
CBNumber:
CB11406035
???:
??? ??:
0
MOL ??:
13517-00-5.mol

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???
decomposes at >60℃ [KIR78]
??
6.38 [CRC10]
???
6℃
?? ??
-20°C
??? ??
??? ??
??
???
???
65°C?? H2O? ??? [CRC10]
InChI
1S/Cu.H
InChIKey
JJFLDSOAQUJVBF-UHFFFAOYSA-N
SMILES
[CuH]
CAS ??????
13517-00-5
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? F,Xn
?? ???? ?? 63-11-38-48/20-65-67
????? 16-36/37-62
????(UN No.) UN1294 - class 3 - PG 2 - Toluene, solution
WGK ?? 3
???? ??? 3 - Flammable liquids
Hazard Classifications Aquatic Chronic 3
Asp. Tox. 1
Flam. Liq. 2
Repr. 2
Skin Irrit. 2
STOT RE 2
STOT SE 3
????(GHS): Flame (GHS02)Exclamation Mark (GHS07)Health Hazard (GHS08)
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H225 ???? ?? ? ?? ??? ?? ?? 2 ?? P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H304 ??? ??? ???? ???? ? ?? ?? ????? ?? 1 ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H336 ?? ?? ???? ??? ? ?? ?????? ?? ??(1? ??);???? ?? 3 ?? P261, P271, P304+P340, P312,P403+P233, P405, P501
H373 ??? ?? ?? ???? ??(??, ??? ?? ??? ?? ??? ??)? ??? ??? ? ?? ?? ???? ?? - ?? ?? ?? 2 ?? P260, P314, P501
??????:
P210 ?·???·??·????? ????? - ?? ???.
P261 ??·?·??·???·??·...·????? ??? ????.
P281 ???? ?? ???? ?????
P301+P310 ???? ?? ????(??)? ??? ????.
P331 ??? ?? ???.

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light reddish brown; composition can vary from Cu0.6 to CuH; can be prepared by precipitation with hypophosphorous acid at 65°C; used as a reducing agent in some organic reactions [KIR78]

??

Reagent for stereoselective synthesis of exocyclic tetra substituted enol ethers and olefins

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