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Nonafluorohexyltriethoxysilane

Nonafluorohexyltriethoxysilane ??? ???
?? ??:
102390-98-7
???:
Nonafluorohexyltriethoxysilane
???(??):
NONAFLUOROHEXYLTRIETHOXYSILANE;1H,1H,2H,2H-PERFLUOROHEXYLTRIETHOXYSILANE;1H,1H,2H,2H-Nonafluorohexyltriethoxysilane;Triethoxy(1H,1H,2H,2H-perfluorohexyl)silane;Triethoxy(1H,1H,2H,2H-nonafluorohexyl)silane;Silane,triethoxy(3,3,4,4,5,5,6,6,6-nonafluorohexyl)-;Triethoxy(1H,1H,2H,2H-nonafluorohexyl)silane;1H,1H,2H,2H-Nonafluorohexyltriethoxysilane Triethoxy(1H,1H,2H,2H-perfluorohexyl)silane
CBNumber:
CB11856935
???:
C12H19F9O3Si
??? ??:
410.35
MOL ??:
102390-98-7.mol

Nonafluorohexyltriethoxysilane ??

?? ?
241.5±40.0 °C(Predicted)
??
1.240±0.06 g/cm3(Predicted)
???
1.3470 to 1.3510
?? ??
Inert atmosphere,Room Temperature
??? ??
??? ??
??
?? ?? ?? ??
Specific Gravity
1.201
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
InChI
InChI=1S/C12H19F9O3Si/c1-4-22-25(23-5-2,24-6-3)8-7-9(13,14)10(15,16)11(17,18)12(19,20)21/h4-8H2,1-3H3
InChIKey
NYIKUOULKCEZDO-UHFFFAOYSA-N
SMILES
[Si](OCC)(OCC)(OCC)CCC(F)(F)C(F)(F)C(F)(F)C(F)(F)F
EPA
Triethoxy(1,1,2,2,3,3,6,6,6-nonafluorohexyl)silane (102390-98-7)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
TSCA Yes
HS ?? 2931.90.9010
????(GHS): Exclamation Mark (GHS07)
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ??
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P321 (…) ??? ???.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P362 ??? ??? ?? ?? ?? ?????
NFPA 704
0
2 0

Nonafluorohexyltriethoxysilane C??? ??, ??, ??

??? ??

Colorless transparent liquid.

??

Nonafluorohexyltriethoxysilane is an organic silane, which can be used as an organic reagent.

?? ??

Main applications of Nonafluorohexyltriethoxysilane(1H,1H,2H,2H-Perfluorohexyltriethoxysilane)  
1) Used as a coupling agent to increase the bonding strength of the fluorine-containing resin and the substrate.
2) Used to prepare water-proof, oil-proof and anti-fouling treatment agents, and it can be used in the protection of water-proof, anti-fouling and weathering of cultural relics, masonry, metal, wood, etc.
3) Used as a finishing agent to reduce the water holding capacity of natural fiber (wool, cotton, leather, etc.) products, and to improve surface water repellency and stain resistance.
4) Used as a water-repellent and antifouling treatment on the surface of glass.

?? ??

Nonafluorobutyl iodide (NFBI) and triethoxyvinylsilane (TEOVS) were fed into a three-necked flask equipped with a reflux condenser at a molar ratio of 1: 1.1 and then heated to 60 ℃ with stirring. When the internal temperature of the flask was sufficiently heated, azobisbutylnitrile (AIBN), a thermal decomposition radical initiator, was dissolved in an ether-based solvent. Then 0.5 ml/sec was dropped slowly into the stirred flask. After that, when the dropwise addition was completed, the external heating temperature was again set to 60 ℃ and stirred for 6 hours. After that, the internal temperature of the flask was lowered to room temperature (25 ℃), and tributyltin hydride (TBTH) was added to the flask at a rate of 1 ml/sec. After further stirring for 4 hours, distillation under reduced pressure at 1 Torr and 40 ° C yielded Nonafluorohexyltriethoxysilane (1H,1H,2H,2H-Perfluorohexyltriethoxysilane) in 75% yield.Nonafluorohexyltriethoxysilane

Nonafluorohexyltriethoxysilane ?? ?? ? ???

???

?? ??


Nonafluorohexyltriethoxysilane ?? ??

???( 108)?? ??
??? ?? ??? ?? ?? ? ??
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Nonafluorohexyltriethoxysilane ?? ??:

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